14N NMR as a General Tool to Characterize the Nitrogen-Containing Species and Monitor the Nitration Process

Author(s):  
Han-Lin Deng ◽  
Xian-Sheng Luo ◽  
Zhihui Lin ◽  
Jiaxin Niu ◽  
Mu-Hua Huang
Keyword(s):  
14N Nmr ◽  
2020 ◽  
Vol 45 (3) ◽  
pp. 1069-1103
Author(s):  
Anton Braverman

This paper studies the steady-state properties of the join-the-shortest-queue model in the Halfin–Whitt regime. We focus on the process tracking the number of idle servers and the number of servers with nonempty buffers. Recently, Eschenfeldt and Gamarnik proved that a scaled version of this process converges, over finite time intervals, to a two-dimensional diffusion limit as the number of servers goes to infinity. In this paper, we prove that the diffusion limit is exponentially ergodic and that the diffusion scaled sequence of the steady-state number of idle servers and nonempty buffers is tight. Combined with the process-level convergence proved by Eschenfeldt and Gamarnik, our results imply convergence of steady-state distributions. The methodology used is the generator expansion framework based on Stein’s method, also referred to as the drift-based fluid limit Lyapunov function approach in Stolyar. One technical contribution to the framework is to show how it can be used as a general tool to establish exponential ergodicity.


Author(s):  
Zachary H. Pugh ◽  
Douglas J. Gillan

A diagramming method called Propositional Constraint (PC) graphing was developed as an aid for tasks involving argumentation, planning, and design. Motivated by several AI models of defeasible (or non- monotonic) reasoning, PC graphs were designed to represent knowledge according to an analogical framework in which constraints (e.g., evidence, goals, system constraints) may elicit or deny possibilities (e.g., explanations, decisions, behaviors). In cases of underspecification, an absence of constraints yields uncertainty and competition among plausible outcomes. In cases of overspecification, no plausible outcome is yielded until one of the constraints is amended or forfeited. This framework shares features with theoretical models of reasoning and argumentation, but despite its intuitiveness and applicability, we know of no modeling language or graphical aid that explicitly depicts this defeasible constraint structure. We describe the syntax and semantics for PC graphing and then illustrate potential uses for it.


2011 ◽  
Vol 115 (31) ◽  
pp. 15257-15265 ◽  
Author(s):  
Alexey A. Popov ◽  
Sandra Schiemenz ◽  
Stanislav M. Avdoshenko ◽  
Shangfeng Yang ◽  
Gianaurelio Cuniberti ◽  
...  

1978 ◽  
Vol 33 (5) ◽  
pp. 515-520 ◽  
Author(s):  
K. Barlos ◽  
H. Nöth ◽  
B. Wrackmeyer

Abstract14N chemical shifts of a series of cyclic and noncyclic aminophosphines are reported. The nuclear shielding of nitrogen decreases with increasing number of halogen substituents at phosphorus as well as with increasing number of phosphinyl groups attached to nitrogen. In addition to the influence of electronegativity PN(π)-interactions may account for the observed shielding. Steric effects are discussed.


2004 ◽  
Author(s):  
Magali Joint ◽  
Pierre-Alain Moellic ◽  
P. Hede ◽  
P. Adam

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