A Miniature Permanent Magnet Assembly with Localized and Uniform Field with an Application to Optical Pumping of Helium

Atomic state preparation can benefit from a compact and uniform magnetic field source. Simulations and experimental measurements have been used to design, build, and test such a source and then apply it to the optical pumping of atomic helium. This source is a 9.5 mm (3/8″) OD × 6.7 mm (1/4″) ID × 9.5 mm (3/8″) long, NdFeB-N42 assembly of 1.6 mm (1/16″) thick customized annular magnets. It has octupole decay with a residual dipole far field from imperfect dipole cancelations. Fast B-field decay localizes the field, minimizing the need for shielding in applications. It has a greater than 50% clear aperture with a uniform and collimated magnetic field consistent with the prediction of several models. The device is applied to a high precision 3,4He laser spectroscopy experiment using σ+ or σ− optical pumping currently resulting in a measured 99.3% preparation efficiency and in accordance with a rate equation model.

A Miniature Permanent Magnet Assembly with Localized and Uniform Field with an Application to Optical Pumping of Helium

Atomic state preparation can benefit from a compact and uniform magnetic field source. Simulations and experimental measurements have been used to design, build, and test such a source as shown by optical pumping of atomic Helium. This source is a 9.5 mm (3/8") OD x 6.7 mm (1/4") ID x 9.5 mm (3/8") long, NdFeB-N42 assembly of 1.6 mm (1/16") thick customized annular magnets. It has octopole decay with a residual dipole far field from imperfect dipole cancelations. It has greater than 50% clear aperture with uniform and collimated magnetic field consistent with the prediction of several models. Octopole roll-off localizes the field minimizing the need for shielding in applications. The device is applied to a high precision 3,4He laser spectroscopy experiment using σ+ or σ- optical pumping currently resulting in a measured 99.3% preparation efficiency and in accordance with a rate-equation model.

Laser spectroscopy of the $$^2{\mathrm{S}}_{1/2}{-}^2{\mathrm{P}}_{{1}/2}$$, $$^2{\mathrm{P}}_{3/2}$$ transitions in stored and cooled relativistic C$$^{3+}$$ ions

The $$^2{\mathrm{S}}_{1/2}{-}^2{\mathrm{P}}_{{1}/2}$$ 2 S 1 / 2 - 2 P 1 / 2 and $$^2{\mathrm{S}}_{1/2}{-}^2{\mathrm{P}}_{{3}/2}$$ 2 S 1 / 2 - 2 P 3 / 2 transitions in Li-like carbon ions stored and cooled at a velocity of $$\beta \approx 0.47$$ β ≈ 0.47 in the experimental storage ring (ESR) at the GSI Helmholtz Centre in Darmstadt have been investigated in a laser spectroscopy experiment. Resonance wavelengths were obtained using a new continuous-wave UV laser system and a novel extreme UV (XUV) detection system to detect forward emitted fluorescence photons. The results obtained for the two transitions are compared to existing experimental and theoretical data. A discrepancy found in an earlier laser spectroscopy measurement at the ESR with results from plasma spectroscopy and interferometry has been resolved and agreement between experiment and theory is confirmed.

Scanning Tunneling Spectroscopy

This chapter discusses various aspects of scanning tunneling spectroscopy (STS). It is an extension of the classical tunneling spectroscopy experiment to nanometer-scale or atomic-scale features on the sample surface. First, the electronics for STS is presented. The nature of STS as a convolution of tip DOS and sample DOS is discussed. Special tip treatment for the STS experiment, often different from the atomic-resolution STM, is described. The purpose is to produce tips with flat DOS, instead of special tip orbitals. Experimental methods to determine tip DOS is discussed. A detailed account of the inelastic scanning tunneling spectroscopy, or STM-IETS, is then discussed. It includes the principles, the electronics, and the instrumental broadening of the features. This chapter concludes with the STS study of superconductors, especially High-Tc supercondoctors.

Laser spectroscopy of the 2S1/2 - 2P1/2, 2P3/2 transitions in stored and cooled relativistic C3+ ions

The and 2S1/2 - 2P1/2 and 2S1/2 - 2P3/2 transitions in Li-like carbon ions stored and cooled at a velocity of β ≈ 0.47 in the Experimental Storage Ring (ESR) at the GSI Helmholtz Centre in Darmstadt have been investigated in a laser spectroscopy experiment. Resonance wavelengths have been obtained using a new continuous-wave UV laser system and a novel extreme UV (XUV) detection system used to detect forward emitted fluorescence photons. The results obtained for the two transitions are compared to existing experimental and theoretical data. A discrepancy found in an earlier laser spectroscopy measurement at the ESR with results from plasma spectroscopy and interferometry could be resolved and agreement between experiment and theory is confirmed. Nonetheless, the experimental uncertainty is still smaller than that of state-of-the art theory.

Intensity Enhancement of a Two-Dimensional Asynchronous Spectrum Without Noise Level Fluctuation Escalation Using a One-Dimensional Spectra Sequence Change

Previously, we demonstrated that the intensities of cross-peaks in a two-dimensional asynchronous spectrum could be enhanced using sequence change of the corresponding one-dimensional spectra. This unusual approach becomes useful when the determination of the sequential order of physicochemical events is not essential. However, it was not known whether the level of noise in the two-dimensional asynchronous spectrum was also escalated as the sequence of one-dimensional spectra changed. We first investigated the noise behavior in a two-dimensional asynchronous spectrum upon changing the sequence of the corresponding one-dimensional spectra on a model system. In the model system, bilinear data from a chromatographic–spectroscopic experiment on a mixture containing two components were analyzed using a two-dimensional asynchronous spectrum. The computer simulation results confirm that the cross-peak intensities in the resultant a two-dimensional asynchronous spectrum were indeed enhanced by more than 100 times as the sequence of one-dimensional spectra changed, whereas the fluctuation level of noise, reflected by the standard deviation of the value of a two-dimensional asynchronous spectrum at a given point, was almost invariant. Further analysis on the model system demonstrated that the special mathematical property of the Hilbert–Noda matrix (the modules of all column vectors of the Hilbert–Noda matrix being a near constant) accounts for the moderate variation of the noise level during the changes of the sequence of one-dimensional spectra. Next, a realistic example from a thermogravimetry–Fourier transform infrared spectroscopy experiment with added artificial noise in seven one-dimensional spectra was studied. As we altered the sequence of the seven FT-IR spectra, the variation of the cross-peak intensities covered four orders of magnitude in the two-dimensional asynchronous spectra. In contrast, the fluctuation of noise in the two-dimensional asynchronous spectra was within two times. The above results clearly demonstrate that a change in the sequence of one-dimensional spectra is an effective way to improve the signal-to-noise level of the two-dimensional asynchronous spectra.

Extracting contrast in an X-ray speckle visibility spectroscopy experiment under imperfect conditions

Pump–probe experiments at synchrotrons and free-electron lasers to study ultrafast dynamics in materials far from equilibrium have been well established, but techniques to investigate equilibrium dynamics on the nano- and pico-second timescales remain underdeveloped and experimentally challenging. A promising approach relies on a double-probe X-ray speckle visibility spectroscopy setup at split-and-delay beamlines of X-ray free-electron lasers. However, the logistics in consistently producing two collinear, perfectly overlapping pulses necessary to conduct a faithful experiment is difficult to achieve. In this paper, a method is introduced to extract contrast in the case where an angular misalignment and imperfect overlap exists between the two pulses. Numerical simulations of a dynamical system show that contrast can still be extracted for significant angular misalignments accompanied by partial overlap between the two pulses.