Electrostatic Correlations and Temperature-Dependent Dielectric Constant Can Model LCST in Polyelectrolyte Complex Coacervation

2021 ◽  
Author(s):  
Andrew S. Ylitalo ◽  
Christopher Balzer ◽  
Pengfei Zhang ◽  
Zhen-Gang Wang
Keyword(s):  
Dielectric Constant ◽  
Polyelectrolyte Complex ◽  
Complex Coacervation ◽  
Temperature Dependent

Atomistic prediction on the configuration- and temperature-dependent dielectric constant of Be0.25Mg0.75O superlattice as a high-κ dielectric layer

2021 ◽  
Author(s):  
Gyuseung Han ◽  
In Won Yeu ◽  
Kun Hee Ye ◽  
Seung-Cheol Lee ◽  
Cheol Seong Hwang ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Dft Calculations ◽  
Bond Length ◽  
Dielectric Layer ◽  
Room Temperature ◽  
High Dielectric Constant ◽  
Temperature Dependent ◽  
High Dielectric

Through DFT calculations, a Be0.25Mg0.75O superlattice having long apical Be–O bond length is proposed to have a high bandgap (>7.3 eV) and high dielectric constant (∼18) at room temperature and above.

Early stage kinetics of polyelectrolyte complex coacervation monitored through stopped-flow light scattering

Soft Matter ◽  
2016 ◽  
Vol 12 (44) ◽  
pp. 9030-9038 ◽  
Author(s):  
Xiaoqing Liu ◽  
Marie Haddou ◽  
Isabelle Grillo ◽  
Zohra Mana ◽  
Jean-Paul Chapel ◽  
...  
Keyword(s):  
Light Scattering ◽  
Polyelectrolyte Complex ◽  
Early Stage ◽  
Stopped Flow ◽  
Complex Coacervation ◽  
Kinetics Of

A Computational Framework for the Inverse Identification of Temperature-Dependent Dielectric Permittivity of Materials at Giga-Hertz Frequencies

2020 ◽  
Author(s):  
A. P. Iliopoulos ◽  
B. D. Graber ◽  
J. G. Michopoulos ◽  
J. C. Steuben ◽  
A. J. Birnbaum ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Dielectric Permittivity ◽  
Microwave Sintering ◽  
Inverse Identification ◽  
Temperature Dependent ◽  
Computational Framework ◽  
The Real ◽  
Inverse Approach ◽  
Solid Objects ◽  
Experimental Apparatus

Abstract The microwave sintering of ceramics and other materials has emerged as an attractive method of manufacturing solid objects though volumetric approaches. The accurate modeling of such processes requires the knowledge of the dielectric constant, and particularly the real and imaginary parts of the permittivity, of these materials as they vary with temperature. This particular measurement becomes very challenging as the temperature rises. In this work, an experimental apparatus and an inverse approach are proposed, based on the coupling of the thermo-mechano-electromagnetic physics that can be used to measure the real and imaginary parts of the dielectric constant at high temperatures.

Frequency and temperature dependent dielectric constant of (Ag)x/CuTl-1223 nanoparticles-superconductor composites

2020 ◽  
Vol 825 ◽  
pp. 154138
Author(s):  
Abrar A. Khan ◽  
M. Sohail ◽  
M. Rahim ◽  
M. Mumtaz ◽  
M. Nasir Khan
Keyword(s):  
Dielectric Constant ◽  
Temperature Dependent

Surface Plasmon Resonance based optical temperature sensor using ZnO:N thin film

2012 ◽  
Vol 1399 ◽  
Author(s):  
Kajal Jindal ◽  
Monika Tomar ◽  
Vinay Gupta
Keyword(s):  
Thin Film ◽  
Dielectric Constant ◽  
Surface Plasmon ◽  
Temperature Sensor ◽  
Low Cost ◽  
Temperature Dependent ◽  
Technique Effect ◽  
Wide Range ◽  
Optical Temperature Sensor ◽  
Promising Application

ABSTRACTTemperature dependent optical properties of RF-sputtered c-axis oriented ZnO:N thin film have been investigated. Surface Plasmon modes are excited at the metal-dielectric interface in the Kretschmann-Reather configuration using prism coupling technique. Effect of ZnO:N thin film deposited over Prism-Au structure on the SPR reflectance is studied over a wide range of temperature from 300–500 K at 633 nm wavelength. The value of dielectric constant of ZnO:N film obtained by fitting the experimentally obtained data with the theoretically generated SPR curve at the optical frequency is found to increase linearly with temperature. The increase in dielectric constant (4.03 to 4.11) with increase in temperature from 300 K to 500 K indicates a promising application of the system as an efficient low-cost temperature sensor.

Dielectric and ac Conductivity Studies on Nanocrystalline Mn Modified Cobalt Ferrite

2018 ◽  
Vol 24 (8) ◽  
pp. 5629-5632 ◽  
Author(s):  
Sweety Supriya ◽  
Sunil Kumar ◽  
Manoranjan Kar
Keyword(s):  
Dielectric Constant ◽  
Frequency Response ◽  
Electrical Transport ◽  
Ac Conductivity ◽  
Cobalt Ferrite ◽  
Electrical Transport Properties ◽  
Arrhenius Behavior ◽  
Temperature Dependent ◽  
Two Layer Model ◽  
Frequency Temperature

The ac conductivity and dielectric properties on CoFe2−xMnxO4 for x = 0.00, 0.10, 0.15 and 0.20 have been studied in detail. All the samples were prepared in nanocrystalline size. These materials are found to be crystallized to Fd <mml:math display="block"> <mml:semantics> <mml:mover accent="true"> <mml:mi>3</mml:mi> <mml:mo>¯</mml:mo> </mml:mover> </mml:semantics> </mml:math> m space group in cubic spinel structure. The dielectric constant and ac conductivity has been discussed as a function of frequency, temperature and composition. The relation between dielectric constant and ac conductivity has been analyzed and the results validate each other. The frequency response of ac conductivity (σac) obeys Johnschers power law and the parameters obtained, explain the sources of ac and dc electrical conductivity in the material. The frequency response of σac follows Maxwell–Wagner two-layer model. The influence of frequency as pumping force on activation energy has been determined. The temperature dependent ac conductivity shows the Arrhenius behavior. The σac observed to be enhanced with increase in frequency as well as temperature. The semiconducting behavior (NTCR) was also evident from temperature dependent electrical transport properties study. The low value of ac conductivity suggests a possible use of this material in dielectric applications.

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