Tuning Intermolecular Interactions of Molecular Crowding Electrolyte for High-Performance Aqueous Batteries

2021 ◽  
pp. 123-130
Author(s):  
Dejian Dong ◽  
Jing Xie ◽  
Zhuojian Liang ◽  
Yi-Chun Lu
Keyword(s):  
Intermolecular Interactions ◽  
High Performance ◽  
Molecular Crowding ◽  
Aqueous Batteries

High rate and stable symmetric potassium ion batteries fabricated with flexible electrodes and solid-state electrolytes

Nanoscale ◽  
2018 ◽  
Vol 10 (44) ◽  
pp. 20754-20760 ◽  
Author(s):  
Ke Lu ◽  
Hong Zhang ◽  
Siyuan Gao ◽  
Yingwen Cheng ◽  
Houyi Ma
Keyword(s):  
Solid State ◽  
Prussian Blue ◽  
High Performance ◽  
Potassium Ion ◽  
High Rate ◽  
Flexible Electrodes ◽  
Bipolar Electrodes ◽  
Solid State Electrolytes ◽  
Aqueous Batteries

Prussian blue particles were deposited on polypyrrole coated wiper clothes and used as bipolar electrodes for fabrication of high performance flexible solid state K-ion aqueous batteries.

Balancing intermolecular interactions by variation of pendent alkyl chains for high performance organic photovoltaics

2017 ◽  
Vol 137 ◽  
pp. 445-455 ◽  
Author(s):  
Joo-weon Ock ◽  
Dongjin Kim ◽  
Hyunjung Kim ◽  
Hyeseung Jung ◽  
Hae Jung Son ◽  
...  
Keyword(s):  
Intermolecular Interactions ◽  
Organic Photovoltaics ◽  
High Performance ◽  
Alkyl Chains

scholarly journals Rheological and Printability Assessments on Biomaterial Inks of Nanocellulose/Photo-Crosslinkable Biopolymer in Light-Aided 3D Printing

2021 ◽  
Vol 3 ◽  
Author(s):  
Qingbo Wang ◽  
Oskar Backman ◽  
Markus Nuopponen ◽  
Chunlin Xu ◽  
Xiaoju Wang
Keyword(s):  
3D Printing ◽  
Shear Flow ◽  
Intermolecular Interactions ◽  
High Performance ◽  
Colloidal Stability ◽  
Cellulose Nanofibers ◽  
3D Bioprinting ◽  
Printing Process ◽  
Rheological Measurements ◽  
Recovery Behavior

Biomaterial inks based on cellulose nanofibers (CNFs) and photo-crosslinkable biopolymers have great potential as a high-performance ink system in light-aided, hydrogel extrusion-based 3D bioprinting. However, the colloidal stability of surface charged nanofibrils is susceptible to mono-cations in physiological buffers, which complexes the application scenarios of these systems in formulating cell-laden bioinks. In this study, biomaterial inks formulated by neutral and negatively surface charged CNFs (GrowInk-N and GrowInk-T) and photo-crosslinkable biopolymers (gelatin methacryloyl (GelMA) and methacrylated galactoglucomannan (GGMMA)) were prepared with Milli-Q water or PBS buffer. Quantitative rheological measurements were performed on the ink formulations to characterize their shear flow recovery behavior and to understand the intermolecular interactions between the CNFs of different kinds with GGMMA or GelMA. Meanwhile, printability assessments, including filament extrudability and shape fidelity of the printed scaffold under varying printing conditions, were carried out to optimize the printing process. Our study provides extensive supporting information for further developing these nanocellulose-based systems into photo-crosslinkable bioinks in the service of cell-laden 3D bioprinting.

High performance polyanthraquinone/Co–Ni(OH)2 aqueous batteries based on hydroxyl and potassium insertion/extraction reactions

2020 ◽  
Vol 4 (1) ◽  
pp. 132-137 ◽  
Author(s):  
Chang Liu ◽  
Ting Ma ◽  
Kexin Xia ◽  
Xuesen Hou ◽  
Qingshun Nian ◽  
...  
Keyword(s):  
Power Density ◽  
High Performance ◽  
Cycling Performance ◽  
High Energy ◽  
Aqueous Batteries

A high performance poly(1,4-anthraquinone)/Ni(OH)2 dual-ion battery is designed with high energy/power density and good cycling performance.

QSPR-Modeling for the Second Virial Cross-Coefficients of Binary Organic Mixtures

2016 ◽  
Vol 1 (2) ◽  
pp. 72-84 ◽  
Author(s):  
Elena Mokshyna ◽  
Pavel Polishchuk ◽  
Vadim Nedostup ◽  
Victor Kuz'min
Keyword(s):  
Intermolecular Interactions ◽  
High Performance ◽  
Pair Potential ◽  
Statistical Characteristics ◽  
Prediction Errors ◽  
Organic Mixtures ◽  
Different Temperatures ◽  
Qspr Modeling ◽  
Predicted Values ◽  
Heterogeneous Interactions

The second virial cross-coefficient is an important characteristic of the pair intermolecular interactions that describes solely the heterogeneous interactions. In the current study, the authors made the first attempt to develop rigorous QSPR models for analysis and prediction of the second virial cross-coefficient. Novel descriptors to describe pair intermolecular interactions were implemented. Statistical characteristics of the obtained models showed high performance. Prediction errors are comparable to the errors of data. Theoretically predicted values of the second virial cross-coefficient may be used to derive PVT-properties of mixtures at the different temperatures as well as to calculate intermolecular pair potential.

Molecular Crowding Electrolytes for High-Voltage Aqueous Batteries

2020 ◽  
Vol MA2020-02 (4) ◽  
pp. 667-667
Author(s):  
Jing Xie ◽  
Zhuojian Liang ◽  
Yi-Chun Lu
Keyword(s):  
High Voltage ◽  
Molecular Crowding ◽  
Aqueous Batteries

High-Performance Small Molecule via Tailoring Intermolecular Interactions and its Application in Large-Area Organic Photovoltaic Modules

2016 ◽  
Vol 6 (12) ◽  
pp. 1600228 ◽  
Author(s):  
Sachin Badgujar ◽  
Gang-Young Lee ◽  
Taiho Park ◽  
Chang Eun Song ◽  
Sangheon Park ◽  
...  
Keyword(s):  
Intermolecular Interactions ◽  
Small Molecule ◽  
High Performance ◽  
Organic Photovoltaic ◽  
Large Area ◽  
Photovoltaic Modules

scholarly journals Prussian Blue Analogues in Aqueous Batteries and Desalination Batteries

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Chiwei Xu ◽  
Zhengwei Yang ◽  
Xikun Zhang ◽  
Maoting Xia ◽  
Huihui Yan ◽  
...  
Keyword(s):  
Prussian Blue ◽  
High Performance ◽  
Large Scale ◽  
Structural Characteristics ◽  
High Spin State ◽  
Aqueous System ◽  
Aqueous Systems ◽  
Prussian Blue Analogues ◽  
The Relationship ◽  
Aqueous Batteries

AbstractIn the applications of large-scale energy storage, aqueous batteries are considered as rivals for organic batteries due to their environmentally friendly and low-cost nature. However, carrier ions always exhibit huge hydrated radius in aqueous electrolyte, which brings difficulty to find suitable host materials that can achieve highly reversible insertion and extraction of cations. Owing to open three-dimensional rigid framework and facile synthesis, Prussian blue analogues (PBAs) receive the most extensive attention among various host candidates in aqueous system. Herein, a comprehensive review on recent progresses of PBAs in aqueous batteries is presented. Based on the application in different aqueous systems, the relationship between electrochemical behaviors (redox potential, capacity, cycling stability and rate performance) and structural characteristics (preparation method, structure type, particle size, morphology, crystallinity, defect, metal atom in high-spin state and chemical composition) is analyzed and summarized thoroughly. It can be concluded that the required type of PBAs is different for various carrier ions. In particular, the desalination batteries worked with the same mechanism as aqueous batteries are also discussed in detail to introduce the application of PBAs in aqueous systems comprehensively. This report can help the readers to understand the relationship between physical/chemical characteristics and electrochemical properties for PBAs and find a way to fabricate high-performance PBAs in aqueous batteries and desalination batteries.

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