Responsive Polymer Welds via Solution Casting for Stabilized Self-Assembly

2012 ◽  
Vol 4 (12) ◽  
pp. 6911-6916 ◽  
Author(s):  
Benny Chen ◽  
Carson T. Riche ◽  
Marcus Lehmann ◽  
Malancha Gupta

2016 ◽  
Vol 120 (22) ◽  
pp. 11938-11946 ◽  
Author(s):  
Huilin Zhao ◽  
Jianping Gao ◽  
Zeng Pan ◽  
Guanbo Huang ◽  
Xiaoyang Xu ◽  
...  


2020 ◽  
Author(s):  
Ali Shahrokhinia ◽  
Randall Scanga ◽  
Priyanka Biswas ◽  
James Reuther

<p><b>ABSTRACT:</b> Photo-controlled atom transfer radical polymerization (PhotoATRP) was implemented, for the first time, to accomplish polymerization induced self-assembly (PISA) mediated by UV light (λ = 365 nm) using ppm levels (ca. < 20 ppm) of copper catalyst at ambient temperature. Using Cu<sup>II</sup>Br<sub>2</sub>/tris(pyridin-2-ylmethyl)amine (TPMA) catalyst systems, PISA was per-formed all in one-pot starting from synthesis of solvophilic poly(oligo(ethylene oxide) methyl ether methacrylate) (POEGMA) blocks to core-crosslinked nanoparticles (NPs) utilizing poly(glycidyl methacrylate) (PGMA) and N,N-cystamine bismethacrylamide (CBMA) as the solvophobic copolymer and crosslinking agent, respectively. Sequential chain-extensions were performed for PGMA demonstrating capabilities for accessing multi-block copolymers with temporal control via switching the UV light on and off. Further, core-crosslinking of PISA nanoparticles was performed via the slow incorporation of the CBMA enabling one-pot crosslinking during the PISA process. Finally, the disulfide installed in the CBMA core-crosslinks allowed for the stimuli-triggered dissociation of nanoparticles using DL-dithiothreitol at acidic pH.</p>



2003 ◽  
Vol 125 (19) ◽  
pp. 5626-5627 ◽  
Author(s):  
Georg Garnweitner ◽  
Bernd Smarsly ◽  
Roger Assink ◽  
Wilhelm Ruland ◽  
Evelyn Bond ◽  
...  


2017 ◽  
Vol 29 (13) ◽  
pp. 5693-5701 ◽  
Author(s):  
Weizheng Fan ◽  
Xia Tong ◽  
Farhad Farnia ◽  
Bing Yu ◽  
Yue Zhao


2019 ◽  
Vol 40 (2) ◽  
pp. 1970004 ◽  
Author(s):  
Daniel B. Wright ◽  
Matthew P. Thompson ◽  
Mollie A. Touve ◽  
Andrea S. Carlini ◽  
Nathan C. Gianneschi


2019 ◽  
Vol 55 (79) ◽  
pp. 11920-11923 ◽  
Author(s):  
Liangliang Yu ◽  
Yuxuan Zhang ◽  
Xiaocong Dai ◽  
Qin Xu ◽  
Li Zhang ◽  
...  

An open-air strategy via enzyme-assisted photoinitiated polymerization-induced self-assembly (photo-PISA) in water is developed for preparing cross-linked CO2-responsive vesicles at high solids contents.



2014 ◽  
Vol 50 (67) ◽  
pp. 9561-9564 ◽  
Author(s):  
Peter J. Roth ◽  
Jing Yang Quek ◽  
Yicheng Zhu ◽  
Bianca M. Blunden ◽  
Andrew B. Lowe

Shaking solutions of tailored (co)polymers in soda water is shown to induce precipitation, nanoparticle formation, or polymer or nanoparticle dissolution.



2014 ◽  
Vol 2 (40) ◽  
pp. 8501-8506 ◽  
Author(s):  
Li Yu ◽  
Zhangxiang Cheng ◽  
Zhijiao Dong ◽  
Yihe Zhang ◽  
Haifeng Yu

Recyclable, fast and visible-light responsive polymer-dispersed liquid crystal/graphene oxide nanocomposite films were fabricated by solution casting and mechanical stretching.





2016 ◽  
Vol 38 (13) ◽  
pp. 1600508 ◽  
Author(s):  
Jianbo Tan ◽  
Xuechao Zhang ◽  
Dongdong Liu ◽  
Yuhao Bai ◽  
Chundong Huang ◽  
...  


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