Redox-Recyclable Extraction and Recovery of Heavy Metal Ions and Radionuclides from Aqueous Media

Author(s):  
Steven H. Strauss
2018 ◽  
Vol 77 (10) ◽  
pp. 2355-2368 ◽  
Author(s):  
Khalida Naseem ◽  
Zahoor H. Farooqi ◽  
Muhammad Z. Ur Rehman ◽  
Muhammad A. Ur Rehman ◽  
Robina Begum ◽  
...  

Abstract This review is based on the adsorption characteristics of sorghum (Sorghum bicolor) for removal of heavy metals from aqueous media. Different parameters like pH, temperature of the medium, sorghum concentration, sorghum particle size, contact time, stirring speed and heavy metal concentration control the adsorption efficiency of sorghum biomass for heavy metal ions. Sorghum biomass showed maximum efficiency for removal of heavy metal ions in the pH range of 5 to 6. It is an agricultural waste and is regarded as the cheapest biosorbent, having high adsorption capacity for heavy metals as compared to other reported adsorbents, for the treatment of heavy metal polluted wastewater. Adsorption of heavy metal ions onto sorghum biomass follows pseudo second order kinetics. Best fitted adsorption isotherm models for removal of heavy metal ions on sorghum biomass are Langmuir and Freundlich adsorption isotherm models. Thermodynamic aspects of heavy metal ions adsorption onto sorghum biomass have also been elaborated in this review article. How adsorption efficiency of sorghum biomass can be improved by different physical and chemical treatments in future has also been elaborated. This review article will be highly useful for researchers working in the field of water treatment via biosorption processing. The quantitative demonstrated efficiency of sorghum biomass for various heavy metal ions has also been highlighted in different sections of this review article.


Sensors ◽  
2019 ◽  
Vol 19 (3) ◽  
pp. 599 ◽  
Author(s):  
Nerea De Acha ◽  
César Elosúa ◽  
Jesús Corres ◽  
Francisco Arregui

Due to the risks that water contamination implies for human health and environmental protection, monitoring the quality of water is a major concern of the present era. Therefore, in recent years several efforts have been dedicated to the development of fast, sensitive, and selective sensors for the detection of heavy metal ions. In particular, fluorescent sensors have gained in popularity due to their interesting features, such as high specificity, sensitivity, and reversibility. Thus, this review is devoted to the recent advances in fluorescent sensors for the monitoring of these contaminants, and special focus is placed on those devices based on fluorescent aptasensors, quantum dots, and organic dyes.


Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4373
Author(s):  
Danil Kurshanov ◽  
Pavel Khavlyuk ◽  
Mihail Baranov ◽  
Aliaksei Dubavik ◽  
Andrei Rybin ◽  
...  

Heavy metal ions are not subject to biodegradation and could cause the environmental pollution of natural resources and water. Many of the heavy metals are highly toxic and dangerous to human health, even at a minimum amount. This work considered an optical method for detecting heavy metal ions using colloidal luminescent semiconductor quantum dots (QDs). Over the past decade, QDs have been used in the development of sensitive fluorescence sensors for ions of heavy metal. In this work, we combined the fluorescent properties of AgInS2/ZnS ternary QDs and the magnetism of superparamagnetic Fe3O4 nanoparticles embedded in a matrix of porous calcium carbonate microspheres for the detection of toxic ions of heavy metal: Co2+, Ni2+, and Pb2+. We demonstrate a relationship between the level of quenching of the photoluminescence of sensors under exposure to the heavy metal ions and the concentration of these ions, allowing their detection in aqueous solutions at concentrations of Co2+, Ni2+, and Pb2+ as low as ≈0.01 ppm, ≈0.1 ppm, and ≈0.01 ppm, respectively. It also has importance for application of the ability to concentrate and extract the sensor with analytes from the solution using a magnetic field.


2010 ◽  
Vol 83 (7) ◽  
pp. 1176-1181 ◽  
Author(s):  
T. E. Nikiforova ◽  
V. A. Kozlov ◽  
M. V. Rodionova

2014 ◽  
Vol 2 (16) ◽  
pp. 5751-5758 ◽  
Author(s):  
T. Okada ◽  
Y. Takeda ◽  
N. Watanabe ◽  
T. Haeiwa ◽  
T. Sakai ◽  
...  

Magnetically collectable and reusable particles for concentrating heavy metal ions and solid acid catalysis in aqueous media were developed.


2015 ◽  
Vol 73 (5) ◽  
pp. 983-992 ◽  
Author(s):  
Francis Ntumba Muya ◽  
Christopher Edoze Sunday ◽  
Priscilla Baker ◽  
Emmanuel Iwuoha

Heavy metal ions such as Cd2+, Pb2+, Cu2+, Mg2+, and Hg2+ from industrial waste water constitute a major cause of pollution for ground water sources. These ions are toxic to man and aquatic life as well, and should be removed from wastewater before disposal. Various treatment technologies have been reported to remediate the potential toxic elements from aqueous media, such as adsorption, precipitation and coagulation. Most of these technologies are associated with some shortcomings, and challenges in terms of applicability, effectiveness and cost. However, adsorption techniques have the capability of effectively removing heavy metals at very low concentration (1–100 mg/L). Various adsorbents have been reported in the literature for this purpose, including, to a lesser extent, the use of hydrogel adsorbents for heavy metal removal in aqueous phase. Here, we provide an in-depth perspective on the design, application and efficiency of hydrogel systems as adsorbents.


2019 ◽  
Vol 7 (25) ◽  
pp. 15432-15443 ◽  
Author(s):  
Anastasia D. Pournara ◽  
Antigoni Margariti ◽  
Georgios D. Tarlas ◽  
Andreas Kourtelaris ◽  
Valeri Petkov ◽  
...  

The two-dimensional Ca-MOF shows a dual function as a sorbent and an electrochemical sensor for heavy metal ions, which is reported for the first time for a MOF material.


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