Rational Design and Synthesis of Porous Polymer Networks: Toward High Surface Area

2014 ◽  
Vol 26 (15) ◽  
pp. 4589-4597 ◽  
Author(s):  
Weigang Lu ◽  
Zhangwen Wei ◽  
Daqiang Yuan ◽  
Jian Tian ◽  
Stephen Fordham ◽  
...  
Keyword(s):  
Surface Area ◽  
Rational Design ◽  
High Surface ◽  
Polymer Networks ◽  
High Surface Area ◽  
Porous Polymer ◽  
Design And Synthesis

scholarly journals Developing Eco-Friendly and Cost-Effective Porous Adsorbent for Carbon Dioxide Capture

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 1962
Author(s):  
Mahboubeh Nabavinia ◽  
Baishali Kanjilal ◽  
Noahiro Fujinuma ◽  
Amos Mugweru ◽  
Iman Noshadi
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Co2 Capture ◽  
High Surface ◽  
Scale Up ◽  
Polymer Networks ◽  
High Surface Area ◽  
Excellent Thermal Stability ◽  
Doped Polymers ◽  
Metal Doped

To address the issue of global warming and climate change issues, recent research efforts have highlighted opportunities for capturing and electrochemically converting carbon dioxide (CO2). Despite metal doped polymers receiving widespread attention in this respect, the structures hitherto reported lack in ease of synthesis with scale up feasibility. In this study, a series of mesoporous metal-doped polymers (MRFs) with tunable metal functionality and hierarchical porosity were successfully synthesized using a one-step copolymerization of resorcinol and formaldehyde with Polyethyleneimine (PEI) under solvothermal conditions. The effect of PEI and metal doping concentrations were observed on physical properties and adsorption results. The results confirmed the role of PEI on the mesoporosity of the polymer networks and high surface area in addition to enhanced CO2 capture capacity. The resulting Cobalt doped material shows excellent thermal stability and promising CO2 capture performance, with equilibrium adsorption of 2.3 mmol CO2/g at 0 °C and 1 bar for at a surface area 675.62 m2/g. This mesoporous polymer, with its ease of synthesis is a promising candidate for promising for CO2 capture and possible subsequent electrochemical conversion.

Construction and carbon dioxide capture of microporous polymer networks with high surface area based on cross-linkable linear polyimides

2019 ◽  
Vol 10 (33) ◽  
pp. 4611-4620 ◽  
Author(s):  
Ningning Song ◽  
Tianjiao Wang ◽  
Hongyan Yao ◽  
Tengning Ma ◽  
Kaixiang Shi ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Carbon Dioxide Capture ◽  
High Surface ◽  
Polymer Networks ◽  
High Surface Area ◽  
Crosslinking Reaction ◽  
Adsorption Performance ◽  
Microporous Polymer

Microporous polyimide networks with high surface area and excellent CO2 adsorption performance have been constructed based on cross-linkable linear polyimides through crosslinking reaction.

Transient laser heating induced hierarchical porous structures from block copolymer–directed self-assembly

Science ◽  
2015 ◽  
Vol 349 (6243) ◽  
pp. 54-58 ◽  
Author(s):  
Kwan Wee Tan ◽  
Byungki Jung ◽  
Jörg G. Werner ◽  
Elizabeth R. Rhoades ◽  
Michael O. Thompson ◽  
...  
Keyword(s):  
Pore Size ◽  
Surface Area ◽  
Self Assembly ◽  
Laser Heating ◽  
Shape Control ◽  
High Surface ◽  
Polymer Network ◽  
High Surface Area ◽  
Porous Polymer ◽  
Hierarchical Porous

Development of rapid processes combining hierarchical self-assembly with mesoscopic shape control has remained a challenge. This is particularly true for high-surface-area porous materials essential for applications including separation and detection, catalysis, and energy conversion and storage. We introduce a simple and rapid laser writing method compatible with semiconductor processing technology to control three-dimensionally continuous hierarchically porous polymer network structures and shapes. Combining self-assembly of mixtures of block copolymers and resols with spatially localized transient laser heating enables pore size and pore size distribution control in all-organic and highly conducting inorganic carbon films with variable thickness. The method provides all-laser-controlled pathways to complex high-surface-area structures, including fabrication of microfluidic devices with high-surface-area channels and complex porous crystalline semiconductor nanostructures.

scholarly journals Aromatic, microporous polymer networks with high surface area generated in Friedel–Crafts-type polycondensations

2011 ◽  
Vol 2 (10) ◽  
pp. 2186 ◽  
Author(s):  
Eduard Preis ◽  
Christian Widling ◽  
Ullrich Scherf ◽  
Satish Patil ◽  
Gunther Brunklaus ◽  
...  
Keyword(s):  
Surface Area ◽  
High Surface ◽  
Polymer Networks ◽  
High Surface Area ◽  
Microporous Polymer

Solvent-free synthesis of a porous thiophene polymer by mechanochemical oxidative polymerization

2018 ◽  
Vol 6 (44) ◽  
pp. 21901-21905 ◽  
Author(s):  
S. Grätz ◽  
M. Oltermann ◽  
E. Troschke ◽  
S. Paasch ◽  
S. Krause ◽  
...  
Keyword(s):  
Surface Area ◽  
Ball Mill ◽  
Oxidative Polymerization ◽  
High Surface ◽  
High Surface Area ◽  
Solvent Free ◽  
Porous Polymer ◽  
Polymerization Reaction ◽  
Free Environment ◽  
Solvent Free Synthesis

An oxidative polymerization reaction was brought into the solvent-free environment of a ball mill, yielding a porous polymer with a defined structure and high surface area.

scholarly journals New Porous Silicon-Containing Organic Polymers: Synthesis and Carbon Dioxide Uptake

Processes ◽  
2020 ◽  
Vol 8 (11) ◽  
pp. 1488
Author(s):  
Safaa H. Mohamed ◽  
Ayad S. Hameed ◽  
Emad Yousif ◽  
Mohammad Hayal Alotaibi ◽  
Dina S. Ahmed ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Pore Volume ◽  
High Surface ◽  
High Surface Area ◽  
Organic Polymers ◽  
Average Pore ◽  
Carbon Dioxide Uptake ◽  
Design And Synthesis ◽  
The One

The design and synthesis of new multifunctional organic porous polymers has attracted significant attention over the years due to their favorable properties, which make them suitable for carbon dioxide storage. In this study, 2-, 3-, and 4-hydroxybenzaldehyde reacted with phenyltrichlorosilane in the presence of a base, affording the corresponding organosilicons 1–3, which further reacted with benzidine in the presence of glacial acetic acid, yielding the organic polymers 4–6. The synthesized polymers exhibited microporous structures with a surface area of 8.174–18.012 m2 g−1, while their pore volume and total average pore diameter ranged from 0.015–0.035 cm3 g−1 and 1.947–1.952 nm, respectively. In addition, among the synthesized organic polymers, the one with the meta-arrangement structure 5 showed the highest carbon dioxide adsorption capacity at 323 K and 40 bar due to its relatively high surface area and pore volume.

High surface area hypercrosslinked microporous organic polymer networks based on tetraphenylethylene for CO2 capture

2014 ◽  
Vol 2 (21) ◽  
pp. 8054-8059 ◽  
Author(s):  
Shuwen Yao ◽  
Xiao Yang ◽  
Miao Yu ◽  
Yinghua Zhang ◽  
Jia-Xing Jiang
Keyword(s):  
Surface Area ◽  
Co2 Capture ◽  
High Surface ◽  
Polymer Networks ◽  
High Surface Area ◽  
Organic Polymer

A series of hypercrosslinked microporous organic copolymer networks was synthesized via Friedel–Crafts alkylation of tetraphenylethylene (TPE) and/or 1,1,2,2-tetraphenylethane-1,2-diol (TPD) promoted by anhydrous FeCl3.

scholarly journals Editorial: Special Issue on “Emerging Nanostructured Catalytic Materials for Energy and Environmental Applications”

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 285
Author(s):  
Gopalan Saianand ◽  
Anantha-Iyengar Gopalan ◽  
Kwang-Pill Lee
Keyword(s):  
Surface Area ◽  
Rational Design ◽  
High Surface ◽  
High Surface Area ◽  
Reaction Pathways ◽  
Intrinsic Properties ◽  
Special Issue ◽  
Control Reaction ◽  
Catalytic Materials ◽  
Editorial Special Issue

In recent years, there has been a great demand for the rational design and development of novel catalytic materials at the nanoscale (1–100 nm), with a view to more accurately and efficiently control reaction pathways due to their high surface area and intrinsic properties [...]

Hydrothermal Synthesis and Photocatalytic Activity of Mesoporouse TiO2 with High Surface Area and Different Pore Size

2014 ◽  
Vol 918 ◽  
pp. 17-20
Author(s):  
Feng Jiao Chen ◽  
Zhao Sheng Bu ◽  
Guo Wei Zhou
Keyword(s):  
Photocatalytic Activity ◽  
Hydrothermal Synthesis ◽  
Pore Size ◽  
Hydrothermal Method ◽  
Surface Area ◽  
Cetyltrimethylammonium Bromide ◽  
High Surface ◽  
High Surface Area ◽  
Tetrabutyl Titanate ◽  
Design And Synthesis

Mesoporous TiO2with high surface area (SBET) and different pore size was successfully fabricated via hydrothermal method using cetyltrimethylammonium bromide and PEO-PPO-PEO as the structure-directing agents, and tetrabutyl titanate (TBT) as titanium source.SBETand pore size of the materials were adjusted by using different amount of TBT.SBETwas increased as TBT changing from 0.5 g to 1.0 g, and then dropped as 2.0 g TBT added. Among as-prepared samples (PC), PC-1.0 showed the highestSBETof 92.72 m2g1. With the increase amount of TBT, pore size increased from 10.36 nm to 12.72 nm. The phtocatalysis study showed that PC-1.0 had the highest percent degradation of 99.6 %. We believed that the design and synthesis of mesoporous TiO2with changing mesopores andSBETare important for both fundamental and technological viewpoints.

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