The atmosphere system is ruled by the interaction of many meteorological parameters, causing a dependency between them, i.e., moisture and temperature, both suitable in front of any anomaly, such as storms, hurricanes, El Niño-Southern Oscillation (ENSO) events. So, understanding perturbations of the variation of moistness along the time may provide an indicator of any oceanographic phenomenon. Annual relative humidity data around the Equatorial line of the Pacific Ocean were processed and analyzed to comprehend the time evolution of each dataset, appreciate anomalies, trends, histograms, and propose a way to predict anomalous episodes such ENSO events, observing abnormality of lag correlation coefficients between every pair of buoys. Datasets were taken from the Tropical Atmosphere Ocean / Triangle Trans-Ocean Network (TAO/TRITON) project, array directed by Pacific Environmental Laboratory (PMEL) of the National Oceanic and Atmospheric Administration (NOAA), and the Japan Agency for Marine-Earth Science and Technology (JAMSTEC). All the datasets were processed, and the code was elaborated by the author or adapted from Mathworks Inc. Even occurrences of relative humidity in the east side of the Pacific Ocean seem to oscillate harmonically, while occurrences in the west side, do not, because of the size of their amplitudes of oscillations. This fact can be seen in the histograms that show Peak shapes in the east side of the ocean, and Gaussians in the west; lag correlation functions show that no one pair of buoys synchronize fluctuations, but western buoys are affected in front of ENSO events, especially between 1997-98. Definitely, lag correlations in western buoys are determined to detect ENSO events.