Determination of Adsorption in Double Layers involving Solid Metals

Nature ◽  
1960 ◽  
Vol 186 (4721) ◽  
pp. 305-307 ◽  
Author(s):  
ERIK A. BLOMGREN ◽  
JOHN O'M. BOCKRIS
Keyword(s):  
2020 ◽  
Vol 24 (11-12) ◽  
pp. 3215-3230 ◽  
Author(s):  
Yuru Ge ◽  
Xuan Xie ◽  
Jessica Roscher ◽  
Rudolf Holze ◽  
Qunting Qu

Abstract Relevant fundamentals of the electrochemical double layer and supercapacitors utilizing the interfacial capacitance as well as superficial redox processes at the electrode/solution interface are briefly reviewed. Experimental methods for the determination of the capacity of electrochemical double layers, of charge storage electrode materials for supercapacitors, and of supercapacitors are discussed and compared. Intrinsic limitations and pitfalls are indicated; popular errors, misconceptions, and mistakes are evaluated. The suitability of available methods is discussed, and practical recommendations are provided.


1905 ◽  
Vol 3 (53) ◽  
pp. 217-228
Author(s):  
Emile Picard

Without restricting ourselves to the historical order, let us resume the development of mathematical physics in the last century, in so far as analysis is concerned. The problems of thermal equilibrium lead to the equation already known to Laplace in the study of attraction. There are few equations which have been the object of so many researches as this celebrated one. The conditions for the limits may assume various forms. The simplest case is that of the thermal equilibrium of a body, the elements of the surface of which are maintained at given temperatures. From the physical point of view, it may be regarded as evident that the temperature, assumed continuous in the interior since there is no source of heat, is determined when it is given at the surface. The more general case is that in which, the condition remaining permanent, there would be a radiation outward with an intensity • varying at the surface according to a given law ; in particular the temperature may be given over one portion, while there is radiation over the remainder. These questions, which are not yet solved in their widest generality, have largely contributed to the direction taken by the theory of partial differential equations. They have called attention to types of determination of the integrals which would never have presented themselves if we had been restricted to a purely abstract point of view. Laplace’s equation has been already met with in hydrodynamics, and in the study of attraction varying inversely as the square of the distance. The latter theory brought to light elements of the most essential nature, such as the potential of single and double layers. Here we meet with analytical combinations of the highest importance, which have since been notably generalised. Green’s formula is a case in point. The fundamental problems of electrostatics are of the same order of ideas, and certainly the celebrated theorem on electrical phenomena in the interior of a hollow conductor, which Faraday rediscovered at a later stage by experimental means, knowing nothing whatever of Green’s memoir, was a notable triumph for theory. This magnificent aggregate has remained the type of the classical theories of mathematical physics, which seem to us to have almost attained perfection, and which have exercised, and still exercise, so happy an influence on the progress of pure analysis by suggesting to it the most beautiful problems. The theory of functions again will afford us a notable comparison. The analytical transformations brought into play are not distinct from those we have met with in the steady movement of heat. Certain fundamental problems in the theory of functions of a complex variable have lost their abstract enunciation and assumed a physical form, as in the case of the distribution of temperature on a closed surface of any connectivity whatever and without radiation, in thermal equilibrium, with two sources of heat which necessarily correspond to equal and opposite flows. Interpreting this, we find a question on Abelian integrals of the third species in the theory of algebraical curves.


By an ellipsoidal body is meant, in the present paper, any homogeneous body which can be arrived at by continuous distortion of an ellipsoid. If ƒ 0 = 0 is the equation of the ellipsoid from which we start, and e is a parameter, the distortion of the ellipsoid may be supposed to proceed by e increasing from the value e = 0 upwards, and the final figure may be taken to be ƒ 0 + e ƒ 1 + e 2 ƒ 2 + e 3 ƒ 3 + ... = 0. For very small distortions the first two terms will adequately represent the distorted figure, and as we pass to higher orders the remaining terms will enter successively. The potential problem, to some extent interesting in itself, derives its chief importance from its application to the determination of the possible figures of equilibrium of a rotating mass of liquid. Poincaré, using his ingenious method of double layers, has shown how the potential of an ellipsoidal body can be carried as far as the second-order terms when the distortion is small, but gives no indication of how it is possible to carry it further, and indeed his method is one which hardly seems susceptible of being developed further than he himself has developed it. It is clear, however, that progress with the problem of rotating liquids can only be made when a method is available for writing down the potential of an ellipsoidal body distorted as far as we please. I believe the method explained in the present paper will be found capable of giving the potential of a body distorted to any extent, although (for reasons which will be explained later) I have not in the present paper carried the calculations further than second-order terms.


1997 ◽  
Vol 3 (S2) ◽  
pp. 1051-1052
Author(s):  
R. Holmestad ◽  
J.-P. Morniroli ◽  
J.M. Zuo ◽  
J.C.H. Spence

Silicon carbide (SiC) is a widely used ceramic material, with many structural and electronic applications. It exists in many polytypes, differing from one another only by the stacking sequence of close packed double layers of Si and C atoms. The polytype called 4H has the hexagonal structure shown in figure 1. The double layers here have a stacking sequence of ABACABAC.. The distance z between the Si and the C layers (shown in figure 1) is an adjustable parameter, which is not exactly known. The aim of this work is to determine the atomic positions in the c-direction by quantitative convergent beam electron diffraction (QCBED). The goal is to develop a general refinement approach for structure determination by electron diffraction. Many newly synthesized materials are available in only very small quantities in the single crystal form and/or mixed with other phases, making X-ray diffraction methods difficult. SiC is often full of stacking faults. For these types of materials, the CBED method is ideal because of the small probe that can be used; areas of less than 100 Å can be studied.


1985 ◽  
Vol 107 ◽  
pp. 113-123
Author(s):  
Robert A. Smith

Limitations of current knowledge of plasma double layers create difficulties in extrapolating double-layer concepts for application to astrophysical models. Some problems of this sort are described, and some central issues in structure and dynamics of double layers are identified, which must be addressed in astrophysical contexts. These include the determination of kinetic boundary conditions, and the relations of time and length scales of local dynamics and structure to those of the global circuit in which the double layer is contained.


1966 ◽  
Vol 25 ◽  
pp. 93-97
Author(s):  
Richard Woolley

It is now possible to determine proper motions of high-velocity objects in such a way as to obtain with some accuracy the velocity vector relevant to the Sun. If a potential field of the Galaxy is assumed, one can compute an actual orbit. A determination of the velocity of the globular clusterωCentauri has recently been completed at Greenwich, and it is found that the orbit is strongly retrograde in the Galaxy. Similar calculations may be made, though with less certainty, in the case of RR Lyrae variable stars.


1999 ◽  
Vol 190 ◽  
pp. 549-554
Author(s):  
Nino Panagia

Using the new reductions of the IUE light curves by Sonneborn et al. (1997) and an extensive set of HST images of SN 1987A we have repeated and improved Panagia et al. (1991) analysis to obtain a better determination of the distance to the supernova. In this way we have derived an absolute size of the ringRabs= (6.23 ± 0.08) x 1017cm and an angular sizeR″ = 808 ± 17 mas, which give a distance to the supernovad(SN1987A) = 51.4 ± 1.2 kpc and a distance modulusm–M(SN1987A) = 18.55 ± 0.05. Allowing for a displacement of SN 1987A position relative to the LMC center, the distance to the barycenter of the Large Magellanic Cloud is also estimated to bed(LMC) = 52.0±1.3 kpc, which corresponds to a distance modulus ofm–M(LMC) = 18.58±0.05.


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