scholarly journals Global rates of water-column denitrification derived from nitrogen gas measurements

2012 ◽  
Vol 5 (8) ◽  
pp. 547-550 ◽  
Author(s):  
Tim DeVries ◽  
Curtis Deutsch ◽  
François Primeau ◽  
Bonnie Chang ◽  
Allan Devol
Keyword(s):  
Water Column ◽  
Nitrogen Gas ◽  
Gas Measurements

scholarly journals An intercomparison of oceanic methane and nitrous oxide measurements

2018 ◽  
Vol 15 (19) ◽  
pp. 5891-5907 ◽  
Author(s):  
Samuel T. Wilson ◽  
Hermann W. Bange ◽  
Damian L. Arévalo-Martínez ◽  
Jonathan Barnes ◽  
Alberto V. Borges ◽  
...  
Keyword(s):  
Nitrous Oxide ◽  
Water Column ◽  
Large Scale ◽  
Trace Gases ◽  
Climatic Forcing ◽  
Order Of Magnitude ◽  
Analytical Accuracy ◽  
Gas Measurements ◽  
Seawater Samples ◽  
The Baltic

Abstract. Large-scale climatic forcing is impacting oceanic biogeochemical cycles and is expected to influence the water-column distribution of trace gases, including methane and nitrous oxide. Our ability as a scientific community to evaluate changes in the water-column inventories of methane and nitrous oxide depends largely on our capacity to obtain robust and accurate concentration measurements that can be validated across different laboratory groups. This study represents the first formal international intercomparison of oceanic methane and nitrous oxide measurements whereby participating laboratories received batches of seawater samples from the subtropical Pacific Ocean and the Baltic Sea. Additionally, compressed gas standards from the same calibration scale were distributed to the majority of participating laboratories to improve the analytical accuracy of the gas measurements. The computations used by each laboratory to derive the dissolved gas concentrations were also evaluated for inconsistencies (e.g., pressure and temperature corrections, solubility constants). The results from the intercomparison and intercalibration provided invaluable insights into methane and nitrous oxide measurements. It was observed that analyses of seawater samples with the lowest concentrations of methane and nitrous oxide had the lowest precisions. In comparison, while the analytical precision for samples with the highest concentrations of trace gases was better, the variability between the different laboratories was higher: 36 % for methane and 27 % for nitrous oxide. In addition, the comparison of different batches of seawater samples with methane and nitrous oxide concentrations that ranged over an order of magnitude revealed the ramifications of different calibration procedures for each trace gas. Finally, this study builds upon the intercomparison results to develop recommendations for improving oceanic methane and nitrous oxide measurements, with the aim of precluding future analytical discrepancies between laboratories.

scholarly journals An intercomparison of oceanic methane and nitrous oxide measurements

2018 ◽  
Author(s):  
Samuel T. Wilson ◽  
Hermann W. Bange ◽  
Damian L. Arévalo-Martínez ◽  
Jonathan Barnes ◽  
Alberto V. Borges ◽  
...  
Keyword(s):  
Nitrous Oxide ◽  
Water Column ◽  
Large Scale ◽  
Trace Gases ◽  
Climatic Forcing ◽  
Order Of Magnitude ◽  
Analytical Accuracy ◽  
Gas Measurements ◽  
Seawater Samples ◽  
The Baltic

Abstract. Large scale climatic forcing is impacting oceanic biogeochemical cycles and is expected to influence the water-column distribution of trace gases including methane and nitrous oxide. Our ability as a scientific community to evaluate changes in the water-column inventories of methane and nitrous oxide depends largely on our capacity to obtain robust and accurate concentration measurements which can be validated across different laboratory groups. This study represents the first formal, international, intercomparison of oceanic methane and nitrous oxide measurements whereby participating laboratories received batches of seawater samples from the subtropical Pacific and the Baltic Sea. Additionally, compressed gas standards from the same calibration scale were distributed to the majority of participating laboratories to improve the analytical accuracy of the gas measurements. The computations used by each laboratory to derive the dissolved gas concentrations were also evaluated for inconsistencies (e.g. pressure and temperature corrections, solubility constants). The results from the intercomparison and intercalibration exercises provided invaluable insights into methane and nitrous oxide measurements. It was observed that analyses of seawater samples with the lowest concentrations of methane and nitrous oxide had the lowest precisions. In comparison, while the analytical precision for samples with the highest concentrations of trace gases was better, the variability between the different laboratories was higher; 36 % for methane and 27 % for nitrous oxide. In addition, the comparison of different batches of seawater samples with methane and nitrous oxide concentrations that ranged over an order of magnitude revealed the ramifications of different calibration procedures for each trace gas. Overall, this paper builds upon the intercomparison results to develop a framework for improving oceanic methane and nitrous oxide measurements, with the aim of precluding future analytical discrepancies between laboratories.

scholarly journals In Situ CO2 and O2 Measurements on a Profiling Float

2013 ◽  
Vol 30 (1) ◽  
pp. 112-126 ◽  
Author(s):  
Björn Fiedler ◽  
Peer Fietzek ◽  
Nuno Vieira ◽  
Péricles Silva ◽  
Henry C. Bittig ◽  
...  
Keyword(s):  
Water Column ◽  
Time Lag ◽  
Profiling Float ◽  
Co2 Partial Pressure ◽  
Surface Ocean ◽  
Tropical North Atlantic ◽  
First Results ◽  
Ocean Layer ◽  
Surface Measurements ◽  
Gas Measurements

Abstract In recent years, profiling floats, which form the basis of the successful international Argo observatory, are also being considered as platforms for marine biogeochemical research. This study showcases the utility of floats as a novel tool for combined gas measurements of CO2 partial pressure (pCO2) and O2. These float prototypes were equipped with a small-sized and submersible pCO2 sensor and an optode O2 sensor for high-resolution measurements in the surface ocean layer. Four consecutive deployments were carried out during November 2010 and June 2011 near the Cape Verde Ocean Observatory (CVOO) in the eastern tropical North Atlantic. The profiling float performed upcasts every 31 h while measuring pCO2, O2, salinity, temperature, and hydrostatic pressure in the upper 200 m of the water column. To maintain accuracy, regular pCO2 sensor zeroings at depth and surface, as well as optode measurements in air, were performed for each profile. Through the application of data processing procedures (e.g., time-lag correction), accuracies of floatborne pCO2 measurements were greatly improved (10–15 μatm for the water column and 5 μatm for surface measurements). O2 measurements yielded an accuracy of 2 μmol kg−1. First results of this pilot study show the possibility of using profiling floats as a platform for detailed and unattended observations of the marine carbon and oxygen cycle dynamics.

The Structure of Radiation Cross-Linked Poly (ethylene oxide) Gels

1971 ◽  
Vol 29 ◽  
pp. 76-77
Author(s):  
C. E. Cluthe ◽  
G. G. Cocks
Keyword(s):  
Molecular Weight ◽  
Ethylene Oxide ◽  
Parallel Plate ◽  
Average Molecular Weight ◽  
Radical Reaction ◽  
Free Radical Reaction ◽  
Nitrogen Gas ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Initial Viscosity

Aqueous solutions of a 1 weight-per cent poly (ethylene oxide) (PEO) were degassed under vacuum, transferred to a parallel plate viscometer under a nitrogen gas blanket, and exposed to Co60 gamma radiation. The Co60 source was rated at 4000 curies, and the dose ratewas 3.8x105 rads/hr. The poly (ethylene oxide) employed in the irradiations had an initial viscosity average molecular weight of 2.1 x 106.The solutions were gelled by a free radical reaction with dosages ranging from 5x104 rads to 4.8x106 rads.

A conduction-cooled stage for high-resolution Cryo-SEM

1992 ◽  
Vol 50 (2) ◽  
pp. 1282-1283
Author(s):  
John G. Sheehan
Keyword(s):  
High Resolution ◽  
Liquid Nitrogen ◽  
Mechanical Stability ◽  
Cooling System ◽  
Cold Trap ◽  
Nitrogen Gas ◽  
Particulate Suspensions ◽  
Advantages And Disadvantages ◽  
Convection Cooling ◽  
Styrene Butadiene

The goal is to examine with high resolution cryo-SEM aqueous particulate suspensions used in coatings for printable paper. A metal-coating chamber for cryo-preparation of such suspensions was described previously. Here, a new conduction-cooling system for the stage and cold-trap in an SEM specimen chamber is described. Its advantages and disadvantages are compared to a convection-cooling system made by Hexland (model CT1000A) and its mechanical stability is demonstrated by examining a sample of styrene-butadiene latex.In recent high resolution cryo-SEM, some stages are cooled by conduction, others by convection. In the latter, heat is convected from the specimen stage by cold nitrogen gas from a liquid-nitrogen cooled evaporative heat exchanger. The advantage is the fast cooling: the Hexland CT1000A cools the stage from ambient temperature to 88 K in about 20 min. However it consumes huge amounts of liquid-nitrogen and nitrogen gas: about 1 ℓ/h of liquid-nitrogen and 400 gm/h of nitrogen gas. Its liquid-nitrogen vessel must be re-filled at least every 40 min.

Comparison of the performance of oscillating water column devices based on arrangements of water columns

2020 ◽  
Vol 14 (3) ◽  
pp. 7082-7093
Author(s):  
Jahirwan Ut Jasron ◽  
Sudjito Soeparmani ◽  
Lilis Yuliati ◽  
Djarot B. Darmadi
Keyword(s):  
Wave Propagation ◽  
Water Column ◽  
Water Depth ◽  
Graphical Form ◽  
Wave Power ◽  
Oscillating Water Column ◽  
Power Absorption ◽  
Water Columns ◽  
Single Column ◽  
Parallel Arrangement

The hydrodynamic performance of oscillating water column (OWC) depends on the depth of the water, the size of the water column and its arrangement, which affects the oscillation of the water surface in the column. An experimental method was conducted by testing 4 water depths with wave periods of 1-3 s. All data recorded by the sensor is then processed and presented in graphical form. The research focused on analyzing the difference in wave power absorption capabilities of the three geometric types of OWC based on arrangements of water columns. The OWC devices designed as single water column, the double water column in a series arrangement which was perpendicular to the direction of wave propagation, and double water column in which the arrangement of columns was parallel to the direction of wave propagation. This paper discussed several factors affecting the amount of power absorbed by the device. The factors are the ratio of water depth in its relation to wavelength (kh) and the inlet openings ratio (c/h) of the devices. The test results show that if the water depth increases in the range of kh 0.7 to 0.9, then the performance of the double chamber oscillating water column (DCOWC) device is better than the single chamber oscillating water column (SCOWC) device with maximum efficiency for the parallel arrangement 22,4%, series arrangement 20.8% and single column 20.7%. However, when referring to c/h, the maximum energy absorption efficiency for a single column is 27.7%, double column series arrangement is 23.2%, and double column parallel arrangement is 29.5%. Based on the results of the analysis, DCOWC devices in parallel arrangement showed the ability to absorb better wave power in a broader range of wave frequencies. The best wave of power absorption in the three testing models occurred in the wave period T = 1.3 seconds.

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