scholarly journals Jarosite formation in deep Antarctic ice provides a window into acidic, water-limited weathering on Mars

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Giovanni Baccolo ◽  
Barbara Delmonte ◽  
P. B. Niles ◽  
Giannantonio Cibin ◽  
Elena Di Stefano ◽  
...  
Keyword(s):  
Chemical Reactions ◽  
Atmospheric Aerosols ◽  
Ice Core ◽  
Ice Cores ◽  
Progressive Increase ◽  
East Antarctica ◽  
Acidic Water ◽  
Geochemical Process ◽  
Surficial Sediments ◽  
History Of

AbstractMany interpretations have been proposed to explain the presence of jarosite within Martian surficial sediments, including the possibility that it precipitated within paleo-ice deposits owing to englacial weathering of dust. However, until now a similar geochemical process was not observed on Earth nor in other planetary settings. We report a multi-analytical indication of jarosite formation within deep ice. Below 1000 m depth, jarosite crystals adhering on residual silica-rich particles have been identified in the Talos Dome ice core (East Antarctica) and interpreted as products of weathering involving aeolian dust and acidic atmospheric aerosols. The progressive increase of ice metamorphism and re-crystallization with depth, favours the relocation and concentration of dust and the formation of acidic brines in isolated environments, allowing chemical reactions and mineral neo-formation to occur. This is the first described englacial diagenetic mechanism occurring in deep Antarctic ice and supports the ice-weathering model for jarosite formation on Mars, highlighting the geologic importance of paleo ice-related processes on this planet. Additional implications concern the preservation of dust-related signals in deep ice cores with respect to paleoclimatic reconstructions and the englacial history of meteorites from Antarctic blue ice fields.

scholarly journals Methanesulphonic acid movement in solid ice cores

2004 ◽  
Vol 39 ◽  
pp. 540-544 ◽  
Author(s):  
Barbara T. Smith ◽  
Tas D. Van Ommen ◽  
Mark A. J. Curran
Keyword(s):  
Diffusion Coefficient ◽  
Biological Activity ◽  
Sea Ice ◽  
Diffusion Mechanism ◽  
Ice Core ◽  
Ice Cores ◽  
East Antarctica ◽  
The Core ◽  
Central Value

AbstractMethanesulphonic acid (MSA) is an important trace-ion constituent in ice cores, with connections to biological activity and sea-ice distribution. Post-depositional movement of MSA has been documented in firn, and this study investigates movement in solid ice by measuring variations in MSA distribution across several horizontal sections from an ice core after 14.5 years storage. The core used is from below the bubble close-off depth at Dome Summit South, Law Dome, East Antarctica. MSA concentration was studied at 3 and 0.5 cm resolution across the core widths. Its distribution was uniform through the core centres, but the outer 3 cm showed gradients in concentrations down to less than half of the central value at the core edge. This effect is consistent with diffusion to the surrounding air during its 14.5 year storage. The diffusion coefficient is calculated to be 2 ×10–13 m2 s–1, and the implications for the diffusion mechanism are discussed.

Reconstructing Antarctic snow accumulation using nitrogen isotopes of nitrate

2021 ◽  
Author(s):  
Pete D. Akers ◽  
Joël Savarino ◽  
Nicolas Caillon ◽  
Mark Curran ◽  
Tas Van Ommen
Keyword(s):  
Nitrogen Isotopes ◽  
Full Range ◽  
Ice Core ◽  
Ice Cores ◽  
Snow Accumulation ◽  
East Antarctica ◽  
Accumulation Rates ◽  
Sea Levels ◽  
Antarctic Snow ◽  
Parallel Reconstruction

<p>Precise Antarctic snow accumulation estimates are needed to understand past and future changes in global sea levels, but standard reconstructions using water isotopes suffer from competing isotopic effects external to accumulation. We present here an alternative accumulation proxy based on the post-depositional photolytic fractionation of nitrogen isotopes (d<sup>15</sup>N) in nitrate. On the high plateau of East Antarctica, sunlight penetrating the uppermost snow layers converts snow-borne nitrate into nitrogen oxide gas that can be lost to the atmosphere. This nitrate loss favors <sup>14</sup>NO<sub>3</sub><sup>-</sup> over <sup>15</sup>NO<sub>3</sub><sup>-</sup>, and thus the d<sup>15</sup>N of nitrate remaining in the snow will steadily increase until the nitrate is eventually buried beneath the reach of light. Because the duration of time until burial is dependent upon the rate of net snow accumulation, sites with lower accumulation rates have a longer burial wait and thus higher d<sup>15</sup>N values. A linear relationship (r<sup>2</sup> = 0.86) between d<sup>15</sup>N and net accumulation<sup>-1</sup> is calculated from over 120 samples representing 105 sites spanning East Antarctica. These sites largely encompass the full range of snow accumulation rates observed in East Antarctica, from 25 kg m-<sup>2</sup> yr<sup>-1</sup> at deep interior sites to >400 kg m-<sup>2</sup> yr<sup>-1</sup> at near coastal sites. We apply this relationship as a transfer function to an Aurora Basin ice core to produce a 700-year record of accumulation changes. Our nitrate-based estimate compares very well with a parallel reconstruction for Aurora Basin that uses volcanic horizons and ice-penetrating radar. Continued improvements to our database may enable precise independent estimates of millennial-scale accumulation changes using deep ice cores such as EPICA Dome C and Beyond EPICA-Oldest Ice.</p>

scholarly journals Climate dependent contrast in surface mass balance in East Antarctica over the past 216 ka

2016 ◽  
Vol 62 (236) ◽  
pp. 1037-1048 ◽  
Author(s):  
F. PARRENIN ◽  
S. FUJITA ◽  
A. ABE-OUCHI ◽  
K. KAWAMURA ◽  
V. MASSON-DELMOTTE ◽  
...  
Keyword(s):  
Mass Balance ◽  
Ice Core ◽  
Ice Cores ◽  
East Antarctica ◽  
Surface Mass Balance ◽  
Last Interglacial ◽  
Surface Mass ◽  
The Past ◽  
Water Stable Isotope ◽  
Global Mean Sea Level

ABSTRACTDocumenting past changes in the East Antarctic surface mass balance is important to improve ice core chronologies and to constrain the ice-sheet contribution to global mean sea-level change. Here we reconstruct past changes in the ratio of surface mass balance (SMB ratio) between the EPICA Dome C (EDC) and Dome Fuji (DF) East Antarctica ice core sites, based on a precise volcanic synchronization of the two ice cores and on corrections for the vertical thinning of layers. During the past 216 000 a, this SMB ratio, denoted SMBEDC/SMBDF, varied between 0.7 and 1.1, being small during cold periods and large during warm periods. Our results therefore reveal larger amplitudes of changes in SMB at EDC compared with DF, consistent with previous results showing larger amplitudes of changes in water stable isotopes and estimated surface temperature at EDC compared with DF. Within the last glacial inception (Marine Isotope Stages, MIS-5c and MIS-5d), the SMB ratio deviates by up to 0.2 from what is expected based on differences in water stable isotope records. Moreover, the SMB ratio is constant throughout the late parts of the current and last interglacial periods, despite contrasting isotopic trends.

scholarly journals History of desert dust deposition recorded in the Elbrus ice core

2019 ◽  
Author(s):  
Stanislav Kutuzov ◽  
Michel Legrand ◽  
Suzanne Preunkert ◽  
Patrick Ginot ◽  
Vladimir Mikhalenko ◽  
...  
Keyword(s):  
North Africa ◽  
Drought Index ◽  
Decadal Variability ◽  
Ice Core ◽  
Ice Cores ◽  
Dust Deposition ◽  
The Past ◽  
Dust Sources ◽  
Increasing Trend ◽  
History Of

Abstract. Ice cores are one of the most valuable paleo-archives. Records from the ice cores can provide information not only about the amount of dust in the atmosphere but also about dust sources and its changes in the past. A 182 m long ice core has been recovered at the western plateau of Mt. Elbrus (5115 m elevation) in 2009. This record was extended with the shallow ice core drilling in 2013. Here we present analysis of the concentrations of Ca2+, a commonly used proxy of dust, recorded in Elbrus ice core over the period 1774–2013. The calcium record reveals a quasi decadal variability with a general increasing trend. Using multiple regression analysis we found a statistically significant spatial correlation of the Elbrus Ca2+ summer concentrations and precipitation and soil moisture content in Levant region (specifically Syria and Iraq). The Ca2+ record also correlates with drought index in North Africa (r = 0.69 p 

scholarly journals 1000 year ice-core records from Berkner Island, Antarctica

2002 ◽  
Vol 35 ◽  
pp. 45-51 ◽  
Author(s):  
Robert Mulvaney ◽  
Hans Oerter ◽  
David A. Peel ◽  
Wolfgang Graf ◽  
Carol Arrowsmith ◽  
...  
Keyword(s):  
Decadal Variability ◽  
Ice Core ◽  
Ice Cores ◽  
Aerosol Deposition ◽  
Climate History ◽  
Joint Project ◽  
The Past ◽  
Annual Layer ◽  
History Of ◽  
Field Season

AbstractTwo medium-depth ice cores were retrieved from Berkner Island by a joint project between the Alfred-Wegener-Institut and the British Antarctic Survey in the 1994/95 field season. A 151m deep core from the northern dome (Reinwarthhöhe) of Berkner Island spans 700 years, while a 181 m deep core from the southern dome (Thyssenhöhe) spans approximately 1200 years. Both cores display clear seasonal cycles in electrical conductivity measurements, allowing dating by annual-layer counting and the calculation of accumulation profiles. Stable-isotope measurements (both δ18O and δD), together with the accumulation data, allow us to estimate changes in climate for most of the past millennium: the data show multi-decadal variability around a generally stable long-termmean. In addition, a full suite of major chemistry measurements is available to define the history of aerosol deposition at these sites: again, there is little evidence that the chemistry of the sites has changed over the past six centuries. Finally, we suggest that the southern dome, with an ice thickness of 950 m, is an ideal site from which to gain a climate history of the late stages of the last glacial and the deglaciation for comparison with the records from the deep Antarctic ice cores, and with other intermediate-depth cores such as Taylor Dome and Siple Dome.

Microfluidic device for continuous-flow analysis of organics in oldest ice

2020 ◽  
Author(s):  
Daniele FIlippi ◽  
Chiara Giorio
Keyword(s):  
Time Resolution ◽  
Ice Core ◽  
Flow Analysis ◽  
Ice Cores ◽  
Core Sample ◽  
High Time ◽  
High Time Resolution ◽  
Continuous Analysis ◽  
Climate History ◽  
History Of

<p>The Beyond EPICA Oldest Ice (BEOI) project will drill an ice core dating back to 1.5 million-years (1.5 Myr) ago. This ice core is of particular interest to the scientific community as it will be the only one covering the climate history of the Mid Pleistocene Transition, when glacial-interglacial cycles changed from a 40 Kyr to 100 Kyr cyclicity, and for which causes are not well understood currently. Obtaining useful climatic information beyond 800 Kyr represents an analytical challenge due to the fact that the deepest section of the ice core is very compact and the amount of sample available is very low.</p><p>Current analytical methods for the determination of organics in ice are characterized by a large number of steps that requires large amounts of sample for a single analysis. This results in the loss of the high time resolution desired from ice cores which is particularly problematic for deeper (i.e. older) records where the ice is more compact.</p><p>This work aims at combining the growing field of microfluidics with improvements to conventional mass spectrometry to allow for continuous analysis of organics in ice cores, melted in continuous on a melting-head. In fact, microfluidic is a powerful technology in which, only a small amount of liquid (10<sup>-9</sup>-10<sup>-18</sup> liters) is manipulated and controlled with an extremely high precision. The method invokes a three-step process: (1) the melted ice core sample is sent to a nebulizer to produce aerosol, then (2) the aerosol is dried to remove water content and concentrate the sample, and (3) the aerosol is sent to a mass spectrometer for continuous analysis through a modified electrospray ionization (ESI) probe.</p><p>This novel system, once operational, can be applied to a range of ice cores but is especially useful for older ice cores given the stratification of deeper segments. It will allow the research community to measure organic compounds with a high time resolution, even in the oldest of ice, to retrieve paleoclimatic information that would otherwise be lost using traditional methods.</p>

scholarly journals Inferring paleo-accumulation records from ice-core data by an adjoint method: application to James Ross Island's ice core

2014 ◽  
Vol 10 (5) ◽  
pp. 3821-3845 ◽  
Author(s):  
C. Martín ◽  
R. Mulvaney ◽  
G. H. Gudmundsson ◽  
H. Corr
Keyword(s):  
Vertical Velocity ◽  
Adjoint Method ◽  
Ice Core ◽  
Synthetic Data ◽  
Ice Cores ◽  
Snow Accumulation ◽  
Polar Regions ◽  
History Of ◽  
Climatic Record ◽  
Accumulation History

Abstract. Ice cores contain a record of snow precipitation that includes information about past atmospheric circulation and mass imbalance in the polar regions. We present a novel adjoint method to reconstruct a climatic record by both optimally dating an ice-core and deriving from it a detailed accumulation history. The motivation of our work is the recent application of phase sensitive radar which measures the vertical velocity of an ice column. The velocity is dependent on the history of subsequent snow accumulation, compaction and compression; and in our inverse formulation of this problem, measured vertical velocity profiles can be utilized directly thereby reducing the uncertainty introduced by ice flow modelling. We first apply our method to synthetic data in order to study its capability and the effect of noise and gaps in the data on retrieved accumulation history. The method is then applied to the ice core retrieved from James Ross Island, Antarctica. We show that the method is robust and that the results depend on quality of the age-depth observations and the derived flow regime around the core site. The method facilitates the incorporation of increasing detail provided by ice-core analysis together with observed full-depth velocity in order to construct a complete climatic record of the polar regions.

scholarly journals Climate dependent contrast in surface mass balance in East Antarctica over the past 216 kyr

2015 ◽  
Vol 11 (1) ◽  
pp. 377-405 ◽  
Author(s):  
F. Parrenin ◽  
S. Fujita ◽  
A. Abe-Ouchi ◽  
K. Kawamura ◽  
V. Masson-Delmotte ◽  
...  
Keyword(s):  
Mass Balance ◽  
Ice Core ◽  
Ice Sheet ◽  
Ice Cores ◽  
Atmospheric Modeling ◽  
East Antarctica ◽  
Surface Mass Balance ◽  
Last Interglacial ◽  
Surface Mass ◽  
The Past

Abstract. Documenting past changes in the East Antarctic surface mass balance is important to improve ice core chronologies and to constrain the ice sheet contribution to global mean sea level. Here we reconstruct the past changes in the ratio of surface mass balance (SMB ratio) between the EPICA Dome C (EDC) and Dome Fuji (DF) East Antarctica ice core sites, based on a precise volcanic synchronisation of the two ice cores and on corrections for the vertical thinning of layers. During the past 216 000 years, this SMB ratio, denoted SMBEDC/SMBDF, varied between 0.7 and 1.1, decreasing during cold periods and increasing during warm periods. While past climatic changes have been depicted as homogeneous along the East Antarctic Plateau, our results reveal larger amplitudes of changes in SMB at EDC compared to DF, consistent with previous results showing larger amplitudes of changes in water stable isotopes and estimated surface temperature at EDC compared to DF. Within interglacial periods and during the last glacial inception (Marine Isotope Stages, MIS-5c and MIS-5d), the SMB ratio deviates by up to 30% from what is expected based on differences in water stable isotope records. Moreover, the SMB ratio is constant throughout the late parts of the current and last interglacial periods, despite contrasting isotopic trends. These SMB ratio changes not closely related to isotopic changes are one of the possible causes of the observed gaps between the ice core chronologies at DF and EDC. Such changes in SMB ratio may have been caused by (i) climatic processes related to changes in air mass trajectories and local climate, (ii) glaciological processes associated with relative elevation changes, or (iii) a combination of climatic and glaciological processes, such as the interaction between changes in accumulation and in the position of the domes. Our inferred SMB ratio history has important implications for ice sheet modeling (for which SMB is a boundary condition) or atmospheric modeling (our inferred SMB ratio could serve as a test).

scholarly journals A Climatic Record Using An Ice Core from the Transantarctic Mountains, Antarctica (Abstract)

1988 ◽  
Vol 10 ◽  
pp. 211
Author(s):  
Paul A. Mayewski ◽  
W. Berry Lyons ◽  
M.J. Spencer ◽  
Mark S. Twickler ◽  
Pieter M. Grootes ◽  
...  
Keyword(s):  
New Hampshire ◽  
Ice Core ◽  
Ice Cores ◽  
Beta Activity ◽  
Glacial History ◽  
Pilot Studies ◽  
Victoria Land ◽  
History Of ◽  
Transantarctic Mountains ◽  
University Of New Hampshire

The production of climatic-change records using glaciochemical time series has seen minimal application in the Transantarctic Mountains. This is true despite the fact that glacial geologic studies in this area are the primary basis for understanding the glacial history of East Antarctica and thus provide an excellent potential framework for the more detailed records obtainable from glaciochemical studies. Numerous sites within the Transantarctic Mountains fit the requirements necessary for the retrieval of ice cores, and pilot studies have been conducted in both southern Victoria Land (Mayewski and Lyons 1982) and northern Victoria Land (Allen and others 1985). These pilot studies have validated the hypothesis that glaciochemical records retrieved from appropriately chosen ice-core sites in the Transantarctic Mountains can be used for: (1) assessing the current stability of the East Antarctic ice sheet, (2) validating models concerning the recent glacial history of the Transantarctic Mountains, (3) searching for relatively high-frequency (1–100 year) climatic signals, (4) determining changes in the relative geography (ocean – land – ice) of a region, and (5) defining the relative importance of the chemical species source areas (i.e. volcanic, biogenic, anthropogenic, marine, crustal) that provide precipitation to the Transantarctic Mountains. During the 1984–85 austral summer, a combined University of New Hampshire – Polar Ice Coring Office effort resulted in the recovery of a 201 m long core from a 2800 m high snow massif atop the Dominion Range (85°15'S, 166°10'E), close to the confluence of the Mill and Beardmore glaciers. Chemical and physical data sets to be developed from this ice core, which is estimated to span a period of approximately 1000 years, include: a detailed 6 m snow pit, several shallow snow pits, and fresh and aged surface snow, in combination with a radio echo-sounding survey of the general area, which will be used to provide three-dimensional control. Chemical and physical analyses conducted as part of the study include: stratigraphy, density, sulfate, nitrate, fluoride, chloride, phosphate, sodium, reactive silicate, total beta activity and oxygen isotopes. The oxygen-isotope analyses are being provided by P. Grootes and M. Stuiver (University of Washington), and all other analyses are being conducted by the Glacier Research Group (University of New Hampshire).

The past 5000 years history of solar modulation of cosmic radiation from 10 Be and 14 C studies

1990 ◽  
Vol 330 (1615) ◽  
pp. 471-480 ◽  
Keyword(s):  
Cosmic Radiation ◽  
Ice Core ◽  
Ice Cores ◽  
Solar Modulation ◽  
Short Term ◽  
The Past ◽  
History Of ◽  
Long Term Trends ◽  
Terrestrial Biomass

10 Be is produced in a similar way as 14 C by the interaction of cosmic radiation with the nuclei in the atmosphere. Assuming that the 10 Be and 14 C variation are proportional and considering the different behaviour in the Earth system, the 10 Be concentrations in ice cores can be compared with the 14 C variations in tree rings. A high correlation is found for the short-term variations ( 14 C-Suess-wiggles). They reflect with a high probability production rate variations. More problematic is the interpretation of the long-term trends of 14 C and 10 Be. Several explanations are discussed. The reconstructed CO 2 concentrations in ice cores indicate a rather constant value (280 ± 10 p.p.m. by volume) during the past few millenia. Measurements on the ice core from Byrd Station, Antarctica, during the period 9000 to 6000 years BP indicate a decrease that might be explained by the extraction of CO 2 from the atmosphere-ocean system to build the terrestrial biomass pool during the climatic optimum.

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