scholarly journals Low-dimensional non-metal catalysts: principles for regulating p-orbital-dominated reactivity

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Si Zhou ◽  
Wei Pei ◽  
Yanyan Zhao ◽  
Xiaowei Yang ◽  
Nanshu Liu ◽  
...  
Keyword(s):  
Active Sites ◽  
High Efficiency ◽  
Silicon Oxide ◽  
Clean Energy ◽  
Metal Catalysts ◽  
Point Of View ◽  
Theoretical Point ◽  
Energy Applications ◽  
Metal Materials ◽  
Low Dimensional

AbstractActivation of p-block elements to replace the rare and precious transition metals for renewable energy applications is highly desirable. In this review, we go over recent experimental and theoretical progress on the low-dimensional non-metal materials for clean energy production, including carbon, silicon, oxide, boron, and phosphorus-based nanostructures, with the p-block elements serving as active sites. We aim to elucidate the mechanism for triggering activity in different kinds of non-metal systems, and extract general principles for controlling the p-orbital-mediated reactivity from a theoretical point of view. The perspectives and challenges for developing high-efficiency non-metal catalysts are provided in the end.

scholarly journals Optimization of Tubular Microalgal Photobioreactors with Spiral Ribs under Single-Sided and Double-Sided Illuminations

Processes ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 619 ◽  
Author(s):  
Lei ◽  
Wang ◽  
Wu
Keyword(s):  
Relative Position ◽  
High Efficiency ◽  
Raw Materials ◽  
Incident Light ◽  
Clean Energy ◽  
Point Of View ◽  
Utilization Efficiency ◽  
Cycle Frequency ◽  
Algal Suspension ◽  
Rib Structure

Microalgae can be raw materials for the production of clean energy and have great potential for development. The design of the microalgal photobioreactor (PBR) affects the mixing of the algal suspension and the utilization efficiency of the light energy, thereby affecting the high-efficiency cultivation of the microalgae. In this study, a spiral rib structure was introduced into a tubular microalgal PBR to improve the mixing performance and the light utilization efficiency. The number of spiral ribs, the inclination angle, and the velocity of the algal suspension were optimized for single-sided and double-sided parallel light illuminations with the same total incident light intensity. Next, the optimization results under the two illumination modes were compared. The results showed that the double-sided illumination did not increase the average light/dark (L/D) cycle frequency of the microalgae particles, but it reduced the efficiency of the L/D cycle enhancement. This outcome was analyzed from the point of view of the relative position between the L/D boundary and the vortex in the flow field. Finally, a method to increase the average L/D cycle frequency was proposed and validated. In this method, the relative position between the L/D boundary and the vortex was adjusted so that the L/D boundary passed through the central region of the vortex. This method can also be applied to the design of other types of PBRs to increase the average L/D cycle frequency.

2D layered organic–inorganic heterostructures for clean energy applications

2018 ◽  
Vol 6 (9) ◽  
pp. 3824-3849 ◽  
Author(s):  
Jalal Azadmanjiri ◽  
James Wang ◽  
Christopher C. Berndt ◽  
Aimin Yu
Keyword(s):  
High Efficiency ◽  
Clean Energy ◽  
Energy Devices ◽  
Energy Applications

2D layered organic–inorganic heterostructures are some of the most promising materials for a broad range of high-efficiency clean energy devices.

scholarly journals Recent Advances in Layered-Double-Hydroxides Based Noble Metal Nanoparticles Efficient Electrocatalysts

Nanomaterials ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 2644
Author(s):  
Zexuan Zhang ◽  
Peilong Li ◽  
Xin Zhang ◽  
Cun Hu ◽  
Yuwen Li ◽  
...  
Keyword(s):  
Noble Metal ◽  
Layered Double Hydroxides ◽  
Active Sites ◽  
Clean Energy ◽  
Metal Catalysts ◽  
Metal Species ◽  
Energy Crisis ◽  
Noble Metal Catalysts ◽  
Recent Advances ◽  
Double Hydroxides

With the energy crisis and environmental pollution becoming more and more serious, it is urgent to develop renewable and clean energy. Hydrogen production from electrolyzed water is of great significance to solve the energy crisis and environmental problems in the future. Recently, layered double hydroxides (LDHs) materials have been widely studied in the electrocatalysis field, due to their unique layered structure, tunable metal species and highly dispersed active sites. Moreover, the LDHs supporting noble metal catalysts obtained through the topotactic transformation of LDHs precursors significantly reduce the energy barrier of electrolyzing water, showing remarkable catalytic activity, good conductivity and excellent durability. In this review, we give an overview of recent advances on LDHs supporting noble metal catalysts, from a brief introduction, to their preparation and modification methods, to an overview of their application in the electrocatalysis field, as well as the challenges and outlooks in this promising field on the basis of current development.

Timber Auctions in the Context of the Modern Auction Theory

2007 ◽  
pp. 86-94
Author(s):  
A. Manakov
Keyword(s):  
Theoretical Analysis ◽  
Auction Theory ◽  
Point Of View ◽  
Theoretical Point ◽  
English Auction ◽  
Analysis And Evaluation

The article provides theoretical analysis and evaluation of the timber auctions reforms in Russia. The author shows that the mechanism of the "combined auctions", which functioned until recently, is more appropriate from the theoretical point of view (and from the point of view of the Russian practice) as compared to the officially approved format of the English auction.

A novel cryptosystem based on abstract automata and Latin cubes

2015 ◽  
Vol 52 (2) ◽  
pp. 221-232
Author(s):  
Pál Dömösi ◽  
Géza Horváth
Keyword(s):  
Block Cipher ◽  
Finite Automata ◽  
Theoretical Background ◽  
Point Of View ◽  
Theoretical Point ◽  
Transition Matrices ◽  
Encryption And Decryption ◽  
Secret Keys ◽  
Automata Network ◽  
Fully Functioning

In this paper we introduce a novel block cipher based on the composition of abstract finite automata and Latin cubes. For information encryption and decryption the apparatus uses the same secret keys, which consist of key-automata based on composition of abstract finite automata such that the transition matrices of the component automata form Latin cubes. The aim of the paper is to show the essence of our algorithms not only for specialists working in compositions of abstract automata but also for all researchers interested in cryptosystems. Therefore, automata theoretical background of our results is not emphasized. The introduced cryptosystem is important also from a theoretical point of view, because it is the first fully functioning block cipher based on automata network.

Graffiti als Version und Subversion–Praxen kultureller Re-Regulierung und die Möglichkeit von Gratiforschung

2010 ◽  
Vol 55 (2) ◽  
pp. 11-25 ◽  
Author(s):  
Bernd Dollinger
Keyword(s):  
Social Life ◽  
Point Of View ◽  
Theoretical Point ◽  
Research Practice ◽  
Wird Eine ◽  
Multiple Perspectives

Der Beitrag geht von Versuchen aus, integrative Perspektiven einer überaus heterogenen Graffitiforschung zu bestimmen. In Auseinandersetzung insbesondere mit Bruno Latours Ansatz des »Iconoclash« wird eine kulturtheoretische Referenz bestimmt, die Graffiti als Version identifiziert, d. h. als semiotisch orientierte Veränderung räumlich situierter Ordnungs- und Regulierungspraxen. Ihnen kann, wenn auch nicht zwingend, eine subversive Qualität zukommen. Durch die Ausrichtung am Konzept einer Version wird beansprucht, Forderungen einer normativ weitgehend abstinenten, nicht-essentialistischen und für komplexe Fragen der Identitäts- und Raumpolitik offenen Forschungspraxis einzulösen.<br><br>The contribution attempts to integrate multiple perspectives of current largely heterogeneous graffiti scholarship. Referring to Bruno Latour’s concept »iconoclash«, we discuss graffiti from a cultural-theoretical point of view as a »version«. It appears as a semiotically oriented modification of spatially situated practices that regulate social life. Often, but not necessarily, these practices involve subversive qualities. The concept of »version« facilitates a non-normative and non-essentialist strategy of research. This enables an explorative research practice in which the complex matters of identity and space politics that are associated with graffiti can be addressed.

Geometric Factor in Skeletal Reactions of 2-Methylpentane on Stepped Surfaces of Platinum Catalyst

1992 ◽  
Vol 57 (10) ◽  
pp. 2012-2020
Author(s):  
Vladimír Hejtmánek
Keyword(s):  
Active Sites ◽  
Platinum Catalyst ◽  
Point Of View ◽  
Geometric Factor ◽  
Published Data ◽  
Stepped Surfaces ◽  
Geometric Conditions ◽  
Surface Intermediates ◽  
Isomerization Mechanism

The role of geometric factor in the course of skeletal reactions (isomerization, hydrogenolysis) of 2-methylpentane on stepped (119), (557) and reconstructed R(557) surfaces of single crystals of platinum was evaluated with computer designed models. These calculations were compared with reported experimental data. It was found by analysis of geometric conditions that there are accessible active ensembles on double step of the reconstructed R(557) surface. In addition, these active sites are unsaturated in their coordination sphere and thus catalytically effective. This finding is consistent with published data, confirming higher catalytic activity of this surface. The various pathways of Bond Shift isomerization mechanism of 2-methylpentane from the point of view of steric demands of surface intermediates on differently located ensembles are discussed, too.

scholarly journals How Digital Inclusion Increase Opportunities for Young People: Case of NEETs from Bulgaria, Romania and Turkey

2021 ◽  
Vol 13 (14) ◽  
pp. 7894
Author(s):  
Gabriela Neagu ◽  
Muhammet Berigel ◽  
Vladislava Lendzhova
Keyword(s):  
Data Analysis ◽  
Rural Areas ◽  
Secondary Data ◽  
Point Of View ◽  
Multidimensional Analysis ◽  
Theoretical Point ◽  
Digital Inclusion ◽  
Virtual Mobility ◽  
Alternative Research ◽  
High Share

This paper examines the perspectives of rural NEETs in the information society. Our analysis focuses on the situation of three European countries—Bulgaria, Romania, and Turkey—characterized by a high share of rural areas and a population of NEETs. From a methodological point of view, we use alternative research methods (secondary data analysis) with statistical methods (simple linear regression). From a theoretical point of view, we will opt for a multidimensional analysis perspective: the theory of digital divide, digital inclusion, virtual mobility, etc. Through data analysis, we expect to obtain a more complete and detailed picture of the ICT situation in rural areas (level of digital skills, level of digital inclusion) to demonstrate the importance of ICT in optimizing virtual mobility for the living conditions of the population, especially the NEET population.

scholarly journals Verbena officinalis Verbenaceae (Lamiales): a new plant model system for phyllotaxis research

2021 ◽  
Author(s):  
Beata Zagórska-Marek ◽  
Magdalena Turzańska ◽  
Klaudia Chmiel
Keyword(s):  
Vascular System ◽  
Cumulative Effect ◽  
Point Of View ◽  
Theoretical Point ◽  
Inflorescence Axis ◽  
Organ Identity ◽  
Lateral Organ ◽  
Complex Relationships ◽  
Secondary Transitions

AbstractPhyllotactic diversity and developmental transitions between phyllotactic patterns are not fully understood. The plants studied so far, such as Magnolia, Torreya or Abies, are not suitable for experimental work, and the most popular model plant, Arabidopsis thaliana, does not show sufficient phyllotactic variability. It has been found that in common verbena (Verbena officinalis L.), a perennial, cosmopolitan plant, phyllotaxis differs not only between growth phases in primary transitions but also along the indeterminate inflorescence axis in a series of multiple secondary transitions. The latter are no longer associated with the change in lateral organ identity, and the sequence of phyllotactic patterns is puzzling from a theoretical point of view. Data from the experiments in silico, confronted with empirical observations, suggest that secondary transitions might be triggered by the cumulative effect of fluctuations in the continuously decreasing bract primordia size. The most important finding is that the changes in the primary vascular system, associated with phyllotactic transitions, precede those taking place at the apical meristem. This raises the question of the role of the vascular system in determining primordia initiation sites, and possibly challenges the autonomy of the apex. The results of this study highlight the complex relationships between various systems that have to coordinate their growth and differentiation in the developing plant shoot. Common verbena emerges from this research as a plant that may become a new model suitable for further studies on the causes of phyllotactic transitions.

scholarly journals Modeling and theoretical description of magnetic hybrid materials—bridging from meso- to macro-scales

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Andreas M. Menzel ◽  
Hartmut Löwen
Keyword(s):  
Colloidal Particles ◽  
Colloidal Particle ◽  
Theoretical Description ◽  
Point Of View ◽  
Material Behavior ◽  
Theoretical Point ◽  
Mechanical Stiffness ◽  
Theoretical Approaches ◽  
Theoretical Predictions ◽  
Particle Level

Abstract Magnetic gels and elastomers consist of magnetic or magnetizable colloidal particles embedded in an elastic polymeric matrix. Outstanding properties of these materials comprise reversible changes in their mechanical stiffness or magnetostrictive distortions under the influence of external magnetic fields. To understand such types of overall material behavior from a theoretical point of view, it is essential to characterize the substances starting from the discrete colloidal particle level. It turns out that the macroscopic material response depends sensitively on the mesoscopic particle arrangement. We have utilized and developed several theoretical approaches to this end, allowing us both to reproduce experimental observations and to make theoretical predictions. Our hope is that both these paths help to further stimulate the interest in these fascinating materials.

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