scholarly journals Solubility of vitamin A in supercritical CO2: experimental study and thermodynamic modeling

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Gowhar Ahmad Naikoo ◽  
Mohammad Saeedi Zadegan ◽  
Mona Zamani Pedram ◽  
Israr Ul Hassan ◽  
Waqar Ahmed ◽  
...  
Keyword(s):  
Experimental Data ◽  
Vitamin A ◽  
Supercritical Co2 ◽  
Pressure Range ◽  
Solubility Data ◽  
Mixing Rules ◽  
Critical Properties ◽  
Body System ◽  
Relative Deviation ◽  
Equation Of States

AbstractOne of the best methods of extracting Vitamin A, as a helper of the immune body system and vision, was measured in supercritical carbon dioxide (SC-CO2); Mole fractions were gained at practical conditions in which the temperature was in the range of 303–323 K and the pressure range was 90–235 bar, respectively. Moreover, four Equation of States [Soave–Redlich–Kwong, Peng–Robinson, Stryjek–Vera and Dashtizadeh–Pazuki–Taghikhani–Ghotbi (DPTG)] were compared with the experimental data. Also, the mixing rules of Van der Waals (vdW1 and vdW2) selected to correlate the solubility data of vitamin A. The outcomes indicate that each of EOSs coupled with vdW2, as a method of estimating the physicochemical and critical properties, were correlated with the solubility data of vitamin A in SC-CO2 with more accuracy, in comparison with vdW1. Among the cubic EOSs, the DPTG model with vdW2 generated the most suitable correlation with the percentage average absolute relative deviation (Average Absolute Relative Deviation%) of 6.

scholarly journals Review of existing and development of a novel mathematical model for supercritical CO2 cycles working fluid

2018 ◽  
Vol 240 ◽  
pp. 01036
Author(s):  
Marcin Wołowicz ◽  
Jarosław Milewski ◽  
Piotr Lis
Keyword(s):  
Experimental Data ◽  
Carbon Dioxide ◽  
Mathematical Model ◽  
Heat Capacity ◽  
Supercritical Co2 ◽  
Pressure Range ◽  
Critical Conditions ◽  
Working Fluid ◽  
Critical Properties ◽  
Area Of Interest

The paper aims to compare the models of working fluids against experimental data for carbon dioxide close to its critical conditions. Fortunately, most of the work is already done and published where the authors compared the models based on the equation of the state (EoS). There are a few other models which were not investigated, thus we would like to add a few new results here and focus only on near-critical properties where the biggest deviation between experimental and calculated properties can be observed. The area of interest was pressure range of 7.39 – 20 MPa and temperature range of 304-340 K just above fluid critical point (7.39 MPa, 304.25 K). Model validation was performed for density and heat capacity as one of the most important parameters in preliminary cycle analysis.

Solubility of methane in octane + ethanol at temperatures from 303.15 K to 333.15 K and pressures up to 12.01 MPa

2012 ◽  
Vol 66 (4) ◽  
Author(s):  
Jun-Qing Cai ◽  
Jin-Zhi Qiao
Keyword(s):  
Experimental Data ◽  
Equation Of State ◽  
Solubility Data ◽  
Mixing Rules ◽  
Average Deviation ◽  
Experimental Solubility Data ◽  
Experimental Solubility

AbstractSolubility of methane in octane + ethanol was measured at temperatures ranging from 303.15 K to 333.15 K and pressures ranging from 2.60 MPa to 12.01 MPa. Experimental data were analyzed using the Soave-Redlich-Kwong equation of state with three types of mixing rules, and the estimated average deviation from the experimental solubility data was less than 3.5 %.

Properties of Refrigerants from Cubic Equations of State

2008 ◽  
Vol 59 (5) ◽  
Author(s):  
Viorel Feroiu ◽  
Dan Geana ◽  
Catinca Secuianu
Keyword(s):  
Experimental Data ◽  
Vapor Pressure ◽  
Equations Of State ◽  
Ternary Mixtures ◽  
Volumetric Properties ◽  
Mixing Rules ◽  
Saturation Curve ◽  
Equilibrium Thermodynamic ◽  
Liquid Equilibrium ◽  
Binary And Ternary Mixtures

Vapour � liquid equilibrium, thermodynamic and volumetric properties were predicted for three pure hydrofluorocarbons: difluoromethane (R32), pentafluoroethane (R125) and 1,1,1,2 � tetrafluoroethane (R134a) as well as for binary and ternary mixtures of these refrigerants. Three cubic equations of state GEOS3C, SRK (Soave � Redlich � Kwong) and PR (Peng � Robinson) were used. A wide comparison with literature experimental data was made. For the refrigerant mixtures, classical van der Waals mixing rules without interaction parameters were used. The GEOS3C equation, with three parameters estimated by matching several points on the saturation curve (vapor pressure and corresponding liquid volumes), compares favorably to other equations in literature, being simple enough for applications.

scholarly journals The Addition of N-Butanol in Ethanol-Isooctane Mixture to Reduce Vapor Pressure of Oxygenated-Gasoline Blend

2017 ◽  
Vol 17 (3) ◽  
pp. 500 ◽  
Author(s):  
Rendra Panca Anugraha ◽  
Zul Akbar Andi Picunang ◽  
Annas Wiguno ◽  
Rizky Tetrisyanda ◽  
Kuswandi Kuswandi ◽  
...  
Keyword(s):  
Experimental Data ◽  
Ternary System ◽  
Vapor Pressure ◽  
Binary Systems ◽  
Experimental Results ◽  
Ideal Solution ◽  
Positive Deviation ◽  
Relative Deviation ◽  
Wilson Model ◽  
Binary Parameter

In this work, vapor pressure of binary systems for isooctane + ethanol, isooctane + n-butanol and ethanol + n-butanol and ternary system for isooctane + ethanol + n-butanol were measured in the temperature range from 313.15 to 318.15 K using the inclined ebulliometer. The experimental results showed that the existence of n-butanol in isooctane decreases the vapor pressure of mixture, while increasing n-butanol fraction in ternary isooctane-ethanol-n-butanol mixture decreased vapor pressure of mixture. Experimental data for binary systems studied were correlated with Wilson, NRTL and UNIQUAC models with average relative deviation (ARD) of 3.5%. The optimized binary parameter pairs obtained in this work were used to estimate the ternary system. The Wilson model gave the best performance for estimation of ternary system with ARD of 5.4%. All systems studied showed non-ideal solution with positive deviation from Raoult’s law.

Influence of Equation-of-States on Supercritical CO2 Combustion

2020 ◽  
Author(s):  
K. R. V. (Raghu) Manikantachari ◽  
Scott M. Martin ◽  
Ramees K. Rahman ◽  
Carlos Velez ◽  
Subith S. Vasu
Keyword(s):  
Supercritical Co2 ◽  
Carbon Capture ◽  
Flame Structure ◽  
Compressibility Factor ◽  
Operating Conditions ◽  
Binary Interaction ◽  
Binary Interaction Parameter ◽  
Combustion Modeling ◽  
Equation Of States ◽  
Supercritical Combustion

Abstract Fossil fuel based direct-fired supercritical CO2 (sCO2) cycles are gaining the attention of industry, academia and government due to their remarkable efficiency and carbon capture at high-source temperatures. Modeling plays an important role in the development of sCO2 combustors because experiments are very expensive at the designed operating conditions of these direct-fired cycles. Inaccurate density estimates are detrimental to the simulation output. Hence, this work focuses on comprehensive evaluation of the influence and applicability various equation-of-states (EOS) which are being used in the supercritical combustion modeling literature. A state-of-the-art supercritical combustion modeling methodology is used to simulate counter-flow supercritical CO2 flames by using various equation-of-states. The results show that, using the corresponding state principle to evaluate compressibility factor is not accurate. Also, van der Waal type EOSs predictions can be as accurate as complex Benedict-Webb-Rubin EOSs; hence van der Waal EOSs are more suitable to simulate sCO2 combustor simulations. Non-ideal effects are significant under the operating conditions considered in this work. The choice of EOS significantly influences the flame structure and heat release rate. Also, assuming the binary interaction parameter as zero is reasonable in sCO2 combustion simulations.

scholarly journals Thermodynamic modeling of solid solubility in supercritical carbon dioxide: Comparison between mixing rules

2013 ◽  
Vol 19 (3) ◽  
pp. 389-398 ◽  
Author(s):  
Hadi Baseri ◽  
Ali Haghighi-Asl ◽  
Nader Lotfollahi
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Thermodynamic Modeling ◽  
Pressure Range ◽  
The Other ◽  
Mixing Rules ◽  
Calculation Results ◽  
Temperature And Pressure ◽  
Robinson Equation ◽  
Supercritical Carbon

In this paper, Peng Robinson equation of state is used for thermodynamic modeling of the solubility of various solid components in the supercritical carbon dioxide. Moreover, the effects of three mixing rules of Van der Waals mixing rules, Panagiotopoulos and Reid mixing rules and modified Kwak and Mansoori mixing rules on the accuracy of calculation results were studied. Good correlations between calculated and experimental data were obtained in the wide temperature and pressure range. A comparison between used models shows that modified Kwak and Mansoori mixing rules give better correlations in comparison with the other mixing rules.

Influence of Equation-of-States on Supercritical CO2 Combustion Mixtures

2020 ◽  
Vol 143 (6) ◽  
Author(s):  
K.R.V. (Raghu) Manikantachari ◽  
Ramees K. Rahman ◽  
Scott M. Martin ◽  
Carlos Velez ◽  
Subith S. Vasu
Keyword(s):  
Supercritical Co2 ◽  
Carbon Capture ◽  
Flame Structure ◽  
Compressibility Factor ◽  
Operating Conditions ◽  
Binary Interaction ◽  
Binary Interaction Parameter ◽  
Combustion Modeling ◽  
Equation Of States ◽  
Supercritical Combustion

Abstract Fossil fuel based direct-fired supercritical CO2 (sCO2) cycles are gaining the attention of industry, academia, and government due to their remarkable efficiency and carbon capture at high-source temperatures. Modeling plays an important role in the development of sCO2 combustors because experiments are very expensive at the designed operating conditions of these direct-fired cycles. Inaccurate density estimates are detrimental to the simulation output. Hence, this work focuses on comprehensive evaluation of the influence and applicability of various equation-of-states (EOS) which are being used in the supercritical combustion modeling literature. A state-of-the-art supercritical combustion modeling methodology is used to simulate counter-flow supercritical CO2 flames by using various equation-of-states. The results show that using the corresponding state principle to evaluate compressibility factor is not accurate. Also, van der Waal type EOSs predictions can be as accurate as complex Benedict–Webb–Rubin EOSs; hence van der Waal EOSs are more suitable to simulate sCO2 combustor simulations. Non-ideal effects are significant under the operating conditions considered in this work. The choice of EOS significantly influences the flame structure and heat release rate. Also, assuming the binary interaction parameter as zero is reasonable in sCO2 combustion simulations.

Solubility Data Series Books now Available on Web

2015 ◽  
Vol 37 (5-6) ◽  
Keyword(s):  
Experimental Data ◽  
Practical Interest ◽  
Solubility Data ◽  
Data Series ◽  
Series Books ◽  
Equilibrium Data ◽  
Solid Liquid

In the 1970s, IUPAC’s Solubility Data Commission (now the Subcommittee on Solubility and Equilibrium Data) embarked on a project to compile and critically evaluate experimental data for solubility in systems of scientific and practical interest. The first volume in the IUPAC Solubility Data Series, covering the solubility of helium and neon in liquid solvents, was published in 1979. Subsequent years saw many volumes on gas-liquid, liquid-liquid, and solid-liquid solubilities. These volumes are an invaluable scientific resource.

scholarly journals Designing of a double-cylinder viscometer for high-pressure liquids

2020 ◽  
Vol 53 (7-8) ◽  
pp. 1482-1492
Author(s):  
Shuo Liu ◽  
Chenguang Xu ◽  
Tongqi Liu ◽  
Yong Cai
Keyword(s):  
Experimental Data ◽  
High Pressure ◽  
Atmospheric Pressure ◽  
Pressure Range ◽  
Magnetic Coupling ◽  
Normal Pressure ◽  
Friction Torque ◽  
Viscosity Measurement ◽  
Closed Cavity ◽  
Cylinder Viscometer

In this work, a double-cylinder viscometer is designed to measure dynamic viscosity over a pressure range from atmospheric pressure up to 150 MPa and a temperature range of 278.15–333.15 K. A high-pressure closed cavity is designed innovatively and the magnetic coupling is adopted to transfer the torque to reduce the friction; the inner cylinder with ruby bearing is designed to reduce the friction torque, thus the accuracy of the viscosity measurement is improved. The experiment of measuring the standard viscosity liquid (N10 and N35) under normal pressure and measuring the viscosity of methylbenzene under the pressure of 0.1–150 MPa were carried out, and considering all the experimental data, the uncertainty of the viscosity measurements is approximately ±3%.

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