Effect of in situ synthesized Fe2O3and Co3O4nanoparticles on electroactive β phase crystallization and dielectric properties of poly(vinylidene fluoride) thin films

2015 ◽  
Vol 17 (2) ◽  
pp. 1368-1378 ◽  
Author(s):  
Pradip Thakur ◽  
Arpan Kool ◽  
Biswajoy Bagchi ◽  
Sukhen Das ◽  
Papiya Nandy
Keyword(s):  
Thin Films ◽  
Dielectric Properties ◽  
Vinylidene Fluoride ◽  
Dielectric Constants ◽  
Β Phase ◽  
Poly Vinylidene Fluoride

In situsynthesis of Fe2O3–Co3O4nanoparticles stabilized electroactive PVDF thin films with colossal dielectric constants.

In situ synthesis of Ni(OH)2nanobelt modified electroactive poly(vinylidene fluoride) thin films: remarkable improvement in dielectric properties

2015 ◽  
Vol 17 (19) ◽  
pp. 13082-13091 ◽  
Author(s):  
Pradip Thakur ◽  
Arpan Kool ◽  
Biswajoy Bagchi ◽  
Nur Amin Hoque ◽  
Sukhen Das ◽  
...  
Keyword(s):  
Thin Films ◽  
Dielectric Properties ◽  
Vinylidene Fluoride ◽  
In Situ Synthesis ◽  
Dielectric Constants ◽  
Remarkable Improvement ◽  
Poly Vinylidene Fluoride

Development of Ni(OH)2nanobelt modified electroactive PVDF thin films with colossal dielectric constantsviaa simplein situprocess.

The role of cerium(iii)/yttrium(iii) nitrate hexahydrate salts on electroactive β phase nucleation and dielectric properties of poly(vinylidene fluoride) thin films

RSC Advances ◽  
2015 ◽  
Vol 5 (36) ◽  
pp. 28487-28496 ◽  
Author(s):  
Pradip Thakur ◽  
Arpan Kool ◽  
Biswajoy Bagchi ◽  
Nur Amin Hoque ◽  
Sukhen Das ◽  
...  
Keyword(s):  
Thin Films ◽  
Dielectric Properties ◽  
Vinylidene Fluoride ◽  
Nitrate Hexahydrate ◽  
Yttrium Nitrate ◽  
Β Phase ◽  
Poly Vinylidene Fluoride ◽  
Phase Nucleation ◽  
Yttrium Nitrate Hexahydrate

Electroactive β phase nucleation in cerium/yttrium nitrate hexahydrate salt modified PVDF thin filmsviaformation of hydrogen bonds.

Improvement of electroactive β phase nucleation and dielectric properties of WO3·H2O nanoparticle loaded poly(vinylidene fluoride) thin films

RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 62819-62827 ◽  
Author(s):  
Pradip Thakur ◽  
Arpan Kool ◽  
Biswajoy Bagchi ◽  
Nur Amin Hoque ◽  
Sukhen Das ◽  
...  
Keyword(s):  
Thin Films ◽  
Dielectric Properties ◽  
Vinylidene Fluoride ◽  
Nucleation Mechanism ◽  
Β Phase ◽  
Poly Vinylidene Fluoride ◽  
Phase Nucleation

Electroactive β phase nucleation mechanism and promising dielectric properties of WO3·H2O nanoparticle loaded PVDF thin films.

scholarly journals Development of In-Situ Poled Nanofiber Based Flexible Piezoelectric Nanogenerators for Self-Powered Motion Monitoring

2020 ◽  
Vol 10 (10) ◽  
pp. 3493
Author(s):  
Minjung Kim ◽  
Vignesh Krishnamoorthi Kaliannagounder ◽  
Afeesh Rajan Unnithan ◽  
Chan Hee Park ◽  
Cheol Sang Kim ◽  
...  
Keyword(s):  
Vinylidene Fluoride ◽  
Implantable Devices ◽  
The Past ◽  
Β Phase ◽  
Poly Vinylidene Fluoride ◽  
High Bias ◽  
Self Powered ◽  
Increasing Demand ◽  
Piezoelectric Nanogenerators

Energy harvesting technologies have found significant importance over the past decades due to the increasing demand of energy and self-powered design of electronic and implantable devices. Herein, we demonstrate the design and application of in situ poled highly flexible piezoelectric poly vinylidene fluoride (PVDF) graphene oxide (GO) hybrid nanofibers in aligned mode for multifaceted applications from locomotion sensors to self-powered motion monitoring. Here we exploited the simplest and most versatile method, called electrospinning, to fabricate the in situ poled nanofibers by transforming non-polar α-phase of PVDF to polar β- phase structures for enhanced piezoelectricity under high bias voltage. The flexible piezoelectric device fabricated using the aligned mode generates an improved output voltage of 2.1 V at a uniform force of 12 N. The effective piezoelectric transduction exhibited by the proposed system was tested for its multiple efficacies as a locomotion detector, bio-e-skin, smart chairs and so on.

Enhancement of β phase crystallization and dielectric behavior of kaolinite/halloysite modified poly(vinylidene fluoride) thin films

2014 ◽  
Vol 99 ◽  
pp. 149-159 ◽  
Author(s):  
Pradip Thakur ◽  
Arpan Kool ◽  
Biswajoy Bagchi ◽  
Sukhen Das ◽  
Papiya Nandy
Keyword(s):  
Thin Films ◽  
Vinylidene Fluoride ◽  
Dielectric Behavior ◽  
Β Phase ◽  
Poly Vinylidene Fluoride

Preparation, Morphology and Dielectric Properties of Polyamide-6/Poly(Vinylidene Fluoride) Blends

2012 ◽  
Vol 496 ◽  
pp. 263-267
Author(s):  
Rui Li ◽  
Jian Zhong Pei ◽  
Yan Wei Li ◽  
Xin Shi ◽  
Qun Le Du
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Flexible Electronics ◽  
High Dielectric Constant ◽  
Vinylidene Fluoride ◽  
Volume Fraction ◽  
Polyamide 6 ◽  
Dielectric Constants ◽  
Poly Vinylidene Fluoride ◽  
High Dielectric

A novel all-polymeric material with high dielectric constant (k) has been developed by blending poly (vinylidene fluoride) (PVDF) with polyamide-6 (PA6). The dependence of the dielectric properties on frequency and polymer volume fraction was investigated. When the volume fraction of PA6 is 20%, the dielectric property is better than others. The SEM investigations suggest that the enhanced dielectric behavior originates from significant interfacial interactions of polymer-polymer. The XRD demonstrate that the PA6 and PVDF affect the crystalline behavior of each component. Furthermore, the stable dielectric constants of the blends could be tuned by adjusting the content of the polymers. The created high-k all-polymeric blends represent a novel type of material that are simple technology and easy to process, and is of relatively high dielectric constant, applications as flexible electronics.

scholarly journals Influence of molecular weight on dielectric properties and piezoelectric constant of poly(vinylidene fluoride) membranes obtained by electrospinning

Polimery ◽  
2021 ◽  
Vol 66 (10) ◽  
pp. 532
Author(s):  
Aminatul Sobirah Zahari ◽  
Muhammad Hafiz Mazwir ◽  
Izan Izwan Misnon
Keyword(s):  
Molecular Weight ◽  
Dielectric Properties ◽  
Vinylidene Fluoride ◽  
Electrochemical Impedance ◽  
Piezoelectric Constant ◽  
Phase Content ◽  
X Ray Diffraction ◽  
X Ray ◽  
Β Phase ◽  
Poly Vinylidene Fluoride

A significant influence of the molecular weight on the dielectric properties and piezoelectric constant of poly(vinylidene fluoride) (PVDF) membranes obtained by electrospinning was demonstrated. Electrochemical impedance spectroscopy and d33 meter were used to evaluate dielectric properties and piezoelectric constant respectively. The presence of the β-phase was determined by Fourier transform infrared spectroscopy (FTIR) and X-Ray diffraction (XRD). The membranes with the lowest molecular weight (180,000 g/mol) possessed the best dielectric properties. They also had the highest piezoelectric constant (21 pC/N) and dielectric constant (2.9 at 50 Hz) as well as the highest β-phase content (80.25%).

Immobilized ionic liquid induced electroactive β-phase in poly(vinylidene fluoride) thin films

Polymer ◽  
2019 ◽  
Vol 181 ◽  
pp. 121784 ◽  
Author(s):  
Shumin Yang ◽  
Fang Wang ◽  
Xiaohui Li ◽  
Yangjiang Wu ◽  
Tongxin Chang ◽  
...  
Keyword(s):  
Thin Films ◽  
Ionic Liquid ◽  
Vinylidene Fluoride ◽  
Β Phase ◽  
Poly Vinylidene Fluoride

scholarly journals High Electromechanical Deformation Based on Structural Beta-Phase Content and Electrostrictive Properties of Electrospun Poly(vinylidene fluoride- hexafluoropropylene) Nanofibers

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1817 ◽  
Author(s):  
Nikruesong Tohluebaji ◽  
Chatchai Putson ◽  
Nantakan Muensit
Keyword(s):  
Dielectric Properties ◽  
Smart Materials ◽  
Microelectromechanical Systems ◽  
Vinylidene Fluoride ◽  
Interfacial Polarization ◽  
Surface Charges ◽  
Thermal Compression ◽  
Β Phase ◽  
Interfacial Surface ◽  
Poly Vinylidene Fluoride

The poly(vinylidene fluoride-hexafluoropropylene) (P(VDF-HFP)) polymer based on electrostrictive polymers is essential in smart materials applications such as actuators, transducers, microelectromechanical systems, storage memory devices, energy harvesting, and biomedical sensors. The key factors for increasing the capability of electrostrictive materials are stronger dielectric properties and an increased electroactive β-phase and crystallinity of the material. In this work, the dielectric properties and microstructural β-phase in the P(VDF-HFP) polymer were improved by electrospinning conditions and thermal compression. The P(VDF-HFP) fibers from the single-step electrospinning process had a self-induced orientation and electrical poling which increased both the electroactive β-crystal phase and the spontaneous dipolar orientation simultaneously. Moreover, the P(VDF-HFP) fibers from the combined electrospinning and thermal compression achieved significantly enhanced dielectric properties and microstructural β-phase. Thermal compression clearly induced interfacial polarization by the accumulation of interfacial surface charges among two β-phase regions in the P(VDF-HFP) fibers. The grain boundaries of nanofibers frequently have high interfacial polarization, as they can trap charges migrating in an applied field. This work showed that the combination of electrospinning and thermal compression for electrostrictive P(VDF-HFP) polymers can potentially offer improved electrostriction behavior based on the dielectric permittivity and interfacial surface charge distributions for application in actuator devices, textile sensors, and nanogenerators.

scholarly journals Achieving high performance poly(vinylidene fluoride) dielectric composites via in situ polymerization of polypyrrole nanoparticles on hydroxylated BaTiO3 particles

2019 ◽  
Vol 10 (35) ◽  
pp. 8224-8235 ◽  
Author(s):  
Xu Xie ◽  
Zhen-zhen He ◽  
Xiao-dong Qi ◽  
Jing-hui Yang ◽  
Yan-zhou Lei ◽  
...  
Keyword(s):  
Dielectric Properties ◽  
High Performance ◽  
Vinylidene Fluoride ◽  
In Situ Polymerization ◽  
Composite Particles ◽  
Poly Vinylidene Fluoride ◽  
Polypyrrole Nanoparticles

PPy@BTOH composite particles with a ‘mulberry-like’ structure are fabricated to prepare dielectric composites with excellent comprehensive dielectric properties.

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