Preparation of fluorescent graphene quantum dots from humic acid for bioimaging application

2015 ◽  
Vol 39 (9) ◽  
pp. 7054-7059 ◽  
Author(s):  
Weijie Shi ◽  
Hai Fan ◽  
Shiyun Ai ◽  
Lusheng Zhu

Humic acid as a raw material was applied for the preparation of graphene quantum dots by a one-step hydrothermal method.

Author(s):  
Zhou J ◽  
◽  
Dong Y ◽  
Ma Y ◽  
Zhang T ◽  
...  

Graphene Quantum Dots (GQDs) have been prepared by oxidationhydrothermal reaction, using ball-milling graphite as the starting materials. The prepared GQDs are endowed with excellent luminescence properties, with the optimum emission of 320nm. Blue photoluminescent emitted from the GQDs under ultraviolet light. The GQDs are ~3nm in width and 0.5~2 nm in thickness, revealed by high-resolution transmission electron microscopy and atomic force microscopy. In addition, Fourier transform infrared spectrum evidences the existence of carbonyl and hydroxyl groups, meaning GQDs can be dispersed in water easily and used in cellar imaging, and blue area inside L929 cells were clearly observed under the fluorescence microscope. Both low price of raw material and simple prepared method contribute to the high quality GQDs widespread application in future.


Talanta ◽  
2017 ◽  
Vol 173 ◽  
pp. 36-43 ◽  
Author(s):  
Narsingh R. Nirala ◽  
Gaurav Khandelwal ◽  
Brijesh Kumar ◽  
Vinita ◽  
Rajiv Prakash ◽  
...  

Nanomaterials ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 104 ◽  
Author(s):  
Rabeb El-Hnayn ◽  
Laetitia Canabady-Rochelle ◽  
Christophe Desmarets ◽  
Lavinia Balan ◽  
Hervé Rinnert ◽  
...  

2,2’-(Ethylenedioxy)bis(ethylamine)-functionalized graphene quantum dots (GQDs) were prepared under mild conditions from graphene oxide (GO) via oxidative fragmentation. The as-prepared GQDs have an average diameter of ca. 4 nm, possess good colloidal stability, and emit strong green-yellow light with a photoluminescence (PL) quantum yield of 22% upon excitation at 375 nm. We also demonstrated that the GQDs exhibit high photostability and the PL intensity is poorly affected while tuning the pH from 1 to 8. Finally, GQDs can be used to chelate Fe(II) and Cu(II) cations, scavenge radicals, and reduce Fe(III) into Fe(II). These chelating and reducing properties that associate to the low cytotoxicity of GQDs show that these nanoparticles are of high interest as antioxidants for health applications.


2017 ◽  
Vol 19 (33) ◽  
pp. 22395-22400 ◽  
Author(s):  
S. R. M. Santiago ◽  
T. N. Lin ◽  
C. H. Chang ◽  
Y. A. Wong ◽  
C. A. J. Lin ◽  
...  

We report a facile, fast, and one-step approach to prepare N-doped graphene quantum dots (GQDs) using pulsed laser ablation with diethylenetriamine (DETA).


2021 ◽  
Vol 9 ◽  
Author(s):  
Zheng Yanyan ◽  
Jing Lin ◽  
Liuhong Xie ◽  
Hongliang Tang ◽  
Kailong Wang ◽  
...  

Simple and efficient synthesis of graphene quantum dots (GQDs) with anodic electrochemiluminescence (ECL) remains a great challenge. Herein, we present an anodic ECL-sensing platform based on nitrogen-doped GQDs (N-GQDs), which enables sensitive detection of hydrogen peroxide (H2O2) and glucose. N-GQDs are easily prepared using one-step molecular fusion between carbon precursor and a dopant in an alkaline hydrothermal process. The synthesis is simple, green, and has high production yield. The as-prepared N-GQDs exhibit a single graphene-layered structure, uniform size, and good crystalline. In the presence of H2O2, N-GQDs possess high anodic ECL activity owing to the functional hydrazide groups. With N-GQDs being ECL probes, sensitive detection of H2O2 in the range of 0.3–100.0 μM with a limit of detection or LOD of 63 nM is achieved. As the oxidation of glucose catalyzed by glucose oxidase (GOx) produces H2O2, sensitive detection of glucose is also realized in the range of 0.7–90.0 μM (LOD of 96 nM).


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