Ball-Milling Graphite Used for Synthesis of Biocompatible Blue Luminescent Graphene Quantum Dots

2021 ◽  
Vol 6 (2) ◽  
Author(s):  
Zhou J ◽  
◽  
Dong Y ◽  
Ma Y ◽  
Zhang T ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Ball Milling ◽  
Graphene Quantum Dots ◽  
Raw Material ◽  
Hydroxyl Groups ◽  
High Quality ◽  
Widespread Application ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron

Graphene Quantum Dots (GQDs) have been prepared by oxidationhydrothermal reaction, using ball-milling graphite as the starting materials. The prepared GQDs are endowed with excellent luminescence properties, with the optimum emission of 320nm. Blue photoluminescent emitted from the GQDs under ultraviolet light. The GQDs are ~3nm in width and 0.5~2 nm in thickness, revealed by high-resolution transmission electron microscopy and atomic force microscopy. In addition, Fourier transform infrared spectrum evidences the existence of carbonyl and hydroxyl groups, meaning GQDs can be dispersed in water easily and used in cellar imaging, and blue area inside L929 cells were clearly observed under the fluorescence microscope. Both low price of raw material and simple prepared method contribute to the high quality GQDs widespread application in future.

scholarly journals Enzyme-Free Electrochemical Nano-Immunosensor Based on Graphene Quantum Dots and Gold Nanoparticles for Cardiac Biomarker Determination

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 578
Author(s):  
Bhargav D. Mansuriya ◽  
Zeynep Altintas
Keyword(s):  
Electron Microscopy ◽  
Quantum Dots ◽  
Gold Nanoparticles ◽  
Troponin I ◽  
Electrochemical Techniques ◽  
Graphene Quantum Dots ◽  
High Specificity ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron

An ultrasensitive enzyme-free electrochemical nano-immunosensor based on a screen-printed gold electrode (SPGE) modified with graphene quantum dots (GQDs) and gold nanoparticles (AuNPs) was engineered to detect cardiac troponin-I (cTnI) for the early diagnosis of acute myocardial infarction (AMI). The GQDs and in-house synthesized AuNPs were implanted onto the SPGE and allowed for anti-cTnI immobilization prior to quantifying cTnI. The biomarker could be determined in a wide concentration range using square-wave voltammetry (SWV), cyclic voltammetry (CV), electron impedance spectroscopy (EIS) and amperometry. The analyses were performed in buffer, as well as in human serum, in the investigation ranges of 1–1000 and 10–1000 pg mL−1, respectively. The detection time ranged from 10.5–13 min, depending on the electrochemical method employed. The detection limit was calculated as 0.1 and 0.5 pg mL−1 for buffer and serum, respectively. The sensitivity of the immunosensor was found to be 6.81 µA cm−2 pg mL−1, whereas the binding affinity was determined to be <0.89 pM. The sensor showed high specificity for cTnI with slight responses for nonspecific biomolecules. Each step of the sensor fabrication was characterized using CV, SWV, EIS and atomic force microscopy (AFM). Moreover, AuNPs, GQDs and their nanocomposites were characterized by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). This is the first immunosensor that represents the successful determination of an analyte using four different electrochemical techniques. Such a sensor could demonstrate a promising future for on-site detection of AMI with its sensitivity, cost-effectiveness, rapidity and specificity.

Ordering of InGaAs Quantum Dots Grown by Molecular Beam Epitaxy under As2 gas flux

2015 ◽  
Vol 1792 ◽  
Author(s):  
Mourad Benamara ◽  
Yuriy I. Mazur ◽  
Peter Lytvyn ◽  
Morgan E. Ware ◽  
Vitaliy Dorogan ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Quantum Dots ◽  
Atomic Force Microscopy ◽  
Molecular Beam Epitaxy ◽  
Large Scale ◽  
Molecular Beam ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron

ABSTRACTThe influence of the substrate temperature on the morphology and ordering of InGaAs quantum dots (QD), grown on GaAs (001) wafers by Molecular Beam Epitaxy (MBE) under As2 flux has been studied using Transmission Electron Microscopy (TEM), Atomic Force Microscopy (AFM) and Photoluminescence (PL) measurements. The experimental results show that lateral and vertical orderings occur for temperatures greater than 520°C and that QDs self-organize in a 6-fold symmetry network on (001) surface for T=555°C. Vertical orderings of asymmetric QDs, along directions a few degrees off [001], are observed on a large scale and their formation is discussed.

scholarly journals Effect of Nucleation Parameters of Ge Quantum Dots Grown over Silicon Oxide by LPCVD

2007 ◽  
Vol 2 (2) ◽  
pp. 81-84
Author(s):  
S. N. M. Mestanza ◽  
I. Doi ◽  
N. C. Frateschi
Keyword(s):  
Quantum Dots ◽  
Silicon Oxide ◽  
Chemical Vapor ◽  
Force Microscopy ◽  
Nucleation Parameters ◽  
Atomic Force ◽  
Transmission Electron ◽  
Pressure Chemical ◽  
Mean Size ◽  
Germanium Quantum Dots

Germanium quantum dots (Ge-QD) were grown by Low Pressure Chemical Vapor Deposition (LPCVD) on Si nucleus previously grown on 3 nm thick SiO2 ultra thin film. Samples were analyzed by atomic force microscopy (AFM) and high resolution transmission electron microscopy (HRTEM). We report the analysis of the influence of the nucleation parameters on size and spatial distribution of Ge-QD. AFM images show a Ge-QD density of around 3.6x1010 cm-2, with an 11 nm mean size and 2.9 nm height. Finally, HRTEM investigation shows that the Ge-QD have a crystalline structure, i.e., they are nanocrystals.

Near Field Optical Spectroscopy of GaN/AlN Quantum Dots

2004 ◽  
Vol 831 ◽  
Author(s):  
A. Neogi ◽  
B. P. Gorman ◽  
H. Morkoç ◽  
T. Kawazoe ◽  
M. Ohtsu ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Near Field ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Spacer Layer Thickness ◽  
Spacer Layer ◽  
Lateral Coupling ◽  
Self Assembled ◽  
Spectrally Resolved

ABSTRACTWe investigate the spatial distribution and emission properties of self-assembled GaN/AlN quantum dots. High-resolution transmission electron microscopy reveals near vertical correlation among the GaN dots due to a sufficiently thin AlN spacer layer thickness, which allows strain induced stacking. Scanning electron and atomic force microscopy show lateral coupling due to a surface roughness of ∼ 50–60 nm. Near-field photoluminescence in the illumination mode (both spatially and spectrally resolved) at 10 K revealed emission from individual dots, which exhibits size distribution of GaN dots from localized sites in the stacked nanostructure. Strong spatial localization of the excitons is observed in GaN quantum dots formed at the tip of self-assembled hexagonal pyramid shapes with six [101 1] facets.

IMPROVED CHEMICAL SYNTHESIS OF GRAPHENE USING A SAFER SOLVOTHERMAL ROUTE

2011 ◽  
Vol 10 (01n02) ◽  
pp. 39-42 ◽  
Author(s):  
DILIP KUMAR SINGH ◽  
P. K. IYER ◽  
P. K. GIRI
Keyword(s):  
Electron Microscopy ◽  
Graphene Sheets ◽  
Pyrolysis Process ◽  
High Quality ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Afm Analysis ◽  
Bulk Production

Graphene has been synthesized using thermal decomposition of ethyl alcohol in a medium pressure autoclave. The synthesis was carried out in the presence of strong alkaline solution at a temperature of ~230°C and pressure of 60 bar. The as-synthesized graphene has been characterized using atomic force microscopy (AFM) and high-resolution transmission electron microscopy (HRTEM). AFM analysis on various graphene sheets shows the presence of monolayer (n = 1) to trilayer (n = 3) graphene sheets with thickness of ~1.168 nm. HRTEM studies confirm the high quality of graphene obtained after purification of as-synthesized product. Use of chemically nonexplosive material for synthesis and reduced reaction time along with the absence of post-pyrolysis process make it a commercially viable process for bulk production of graphene.

scholarly journals Conjugated Quantum Dots Inhibit the Amyloidβ(1–42) Fibrillation Process

2011 ◽  
Vol 2011 ◽  
pp. 1-15 ◽  
Author(s):  
Garima Thakur ◽  
Miodrag Micic ◽  
Yuehai Yang ◽  
Wenzhi Li ◽  
Dania Movia ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Quantum Dots ◽  
Atomic Force Microscopy ◽  
Amyloid Beta ◽  
Dihydrolipoic Acid ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Tht Fluorescence

Nanoparticles have enormous potential in diagnostic and therapeutic studies. We have demonstrated that the amyloid beta mixed with and conjugated to dihydrolipoic acid- (DHLA) capped CdSe/ZnS quantum dots (QDs) of size approximately 2.5 nm can be used to reduce the fibrillation process. Transmission electron microscopy (TEM) and atomic force microscopy (AFM) were used as tools for analysis of fibrillation. There is a significant change in morphology of fibrils when amyloidβ(1–42) (Aβ(1–42)) is mixed or conjugated to the QDs. The length and the width of the fibrils vary under modified conditions. Thioflavin T (ThT) fluorescence supports the decrease in fibril formation in presence of DHLA-capped QDs.

Optical And Structural properties of Vertical Aligned Self-Assembled InAs Quantum Dots Multilayers

2001 ◽  
Vol 676 ◽  
Author(s):  
J. C. González ◽  
M. I. N. da Silva ◽  
W. N. Rodrigues ◽  
F. M. Matinaga ◽  
R. Magalhaes-Paniago ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Structural Properties ◽  
Molecular Beam ◽  
X Ray Diffraction ◽  
Inas Quantum Dots ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Self Assembled

ABSTRACTIn this work, we report optical and structural properties of vertical aligned self-assembled InAs quantum dots multilayers. The InAs quantum dots samples were grown by Molecular Beam Epitaxy. Employing Atomic Force Microscopy, Transmission Electron Microscopy, and Gracing Incident X-ray Diffraction we have studied the structural properties of samples with different number of periods of the multiplayer structure, as well as different InAs coverage. The optical properties were studied using Photoluminescence spectroscopy.

InP Self Assembled Quantum Dot Lasers Grown on GaAs Substrates by Metalorganic Chemical Vapor Deposition

2001 ◽  
Vol 692 ◽  
Author(s):  
R. D. Dupuis ◽  
J. H. Ryou ◽  
R. D. Heller ◽  
G. Walter ◽  
D. A. Kellogg ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Quantum Dot ◽  
Chemical Vapor ◽  
Active Regions ◽  
Threshold Current ◽  
Double Quantum ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Inp Quantum Dots

AbstractWe describe the operation of lasers having active regions composed of InP selfassembled quantum dots embedded in In0.5Al0.3Ga0.2P grown on GaAs (100) substrates by MOCVD. InP quantum dots grown on In0.5Al0.3Ga0.2P have a high density on the order of about 1–2×10 cm−2 with a dominant size of about 10–15 nm for 7.5 ML growth.[1] These In0.5Al0.3Ga0.2P/InP quantum dots have previously been characterized by atomic-force microscopy, high-resolution transmission electron microscopy, and photoluminescence.[2] We report here the 300K operation of optically pumped red-emitting quantum dots using both double quantum-dot active regions and quantum-dot coupled with InGaP quantum-well active regions. Optically and electrically pumped 300K lasers have been obtained using this active region design; these lasers show improved operation compared to the lasers having QD-based active regions with threshold current densities as low as Jth ∼ 0.5 KA/cm2.

scholarly journals Dissolution and Interaction of Cellulose Carbamate in NaOH/ZnO Aqueous Solutions

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1092
Author(s):  
Yanhui Kang ◽  
Fangyu Wang ◽  
Zeming Zhang ◽  
Jinping Zhou
Keyword(s):  
Aqueous Solutions ◽  
Strong Interactions ◽  
Hydroxyl Groups ◽  
Scanning Calorimetry ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Cellulose Carbamate ◽  
Lower Temperature ◽  
The Stability

The dissolution and molecular interactions of cellulose carbamate (CC) in NaOH/ZnO aqueous solutions were studied using optical microscopy, differential scanning calorimetry (DSC), 1H NMR, dynamic light scattering (DLS), atomic force microscopy (AFM), transmission electron microscopy (TEM), and molecular dynamic simulation. The dissolution of CC in NaOH/ZnO aqueous solutions using the freezing–thawing method was an exothermic process, and the lower temperature was favorable for the dissolution of CC. ZnO dissolved in NaOH aqueous solutions with the formation of Zn(OH)42−, and no free Zn2+ ions existed in the solvents. NaOH/Na2Zn(OH)4 system formed strong interactions with the hydroxyl groups of CC to improve its solubility and the stability of CC solution. The results indicate that 7 wt% NaOH/1.6 wt% ZnO aqueous solution was the most appropriate solvent for the dissolution of CC. This work revealed the dissolution interaction of CC-NaOH/ZnO solutions, which is beneficial for the industrialization of the CarbaCell process.

scholarly journals Density control of InP/GaInP quantum dots grown by metal-organic vapor-phase epitaxy

2018 ◽  
Vol 52 (4) ◽  
pp. 477
Author(s):  
D.V. Lebedev ◽  
N.A. Kalyuzhnyy ◽  
S.A. Mintairov ◽  
K.G. Belyaev ◽  
M.V. Rakhlin ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Chemical Vapor ◽  
Organic Chemical ◽  
Height Distribution ◽  
Force Microscopy ◽  
Self Organized ◽  
Density Control ◽  
Atomic Force ◽  
Transmission Electron ◽  
Metal Organic

AbstractWe investigated structural and emission properties of self-organized InP/GaInP quantum dots (QD) grown by metal organic chemical vapor deposition using an amount of deposited In from 7 to 2 monolayers (ML). In the uncapped samples, using atomic force microscopy (AFM), we observed lateral sizes of 100–200 nm, together with a bimodal height distribution having maxima at ∼5 and ∼15 nm, which we denoted as QDs of type A and B, respectively; and reduction of the density of the type-B dots from 4.4 to 1.6 μm^–2. The reduction of the density of B-type dots were observed also using transmission electron microscopy of the capped samples. Using single dot low-temperature photoluminescence (PL) spectroscopy we demonstrated effects of Wigner localization for the electrons accumulated in these dots.

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