Self-assembled three-dimensional graphene-based materials for dye adsorption and catalysis

2015 ◽  
Vol 3 (18) ◽  
pp. 10031-10037 ◽  
Author(s):  
Xueping Zhang ◽  
Dong Liu ◽  
Lu Yang ◽  
Limin Zhou ◽  
Tianyan You
Keyword(s):  
Adsorption Capacity ◽  
Self Assembly ◽  
Three Dimensional ◽  
Dye Adsorption ◽  
Reduction Process ◽  
High Adsorption ◽  
Graphene Aerogel ◽  
High Adsorption Capacity ◽  
Self Assembled

Graphene aerogel (GA) fabricated via a simultaneous self-assembly and reduction process showed high adsorption capacity towards dyes.

A three-dimensional nickel-doped reduced graphene oxide composite for selective separation of hemoglobin with a high adsorption capacity

RSC Advances ◽  
2016 ◽  
Vol 6 (61) ◽  
pp. 56278-56286 ◽  
Author(s):  
Lei Chen ◽  
Zhang-Run Xu
Keyword(s):  
Graphene Oxide ◽  
Adsorption Capacity ◽  
Reduced Graphene Oxide ◽  
Self Assembly ◽  
Three Dimensional ◽  
High Adsorption ◽  
Reduced Graphene ◽  
One Step ◽  
Reduced Graphene Oxide Aerogel ◽  
High Adsorption Capacity

A 3D nickel-doped reduced graphene oxide aerogel was prepared by one-step reduction and self-assembly, which exhibited favorable selectivity and high adsorption capacity for isolating hemoglobin.

scholarly journals Super-Adsorbent Hydrogels for Removal of Methylene Blue from Aqueous Solution: Dye Adsorption Isotherms, Kinetics, and Thermodynamic Properties

Macromol ◽  
2021 ◽  
Vol 1 (4) ◽  
pp. 256-275
Author(s):  
Buddhabhushan Salunkhe ◽  
Thomas P. Schuman
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Organic Dyes ◽  
Polymer Network ◽  
Dye Adsorption ◽  
Isotherm Models ◽  
High Adsorption ◽  
High Adsorption Capacity ◽  
Efficient Option ◽  
Sodium Styrenesulfonate

Removal of dyes through adsorption from wastewater has gained substantial interest in recent years, especially in development of hydrogel based adsorbents, owing to their easy use and economical nature. The aim of the present study was to design a super-adsorbent hydrogel based on sodium styrenesulfonate (NaSS) monomer for removal of dyes like methylene blue (MB). NaSS displays both an aromatic ring and strongly ionic group in its monomer structure that can enhance adsorption capacity. Poly(sodium styrenesulfonate-co-dimethylacrylamide) hydrogels were prepared by solution free radical polymerization using gelatin methacryloyl (GelMA) as crosslinker, creating a highly porous, three-dimensionally crosslinked polymer network contributing to higher swelling ratios of up to 27,500%. These super-adsorbent hydrogels exhibited high adsorption capacity of 1270 mg/g for MB adsorption with above 98% removal efficiency. This is the first report for such a high adsorption capacity for dye absorbance for NaSS-based hydrogels. Additionally, the adsorption kinetics using a pseudo-first-order and the Freundlich adsorption isotherm models for multilayer, heterogeneous adsorption processes has been reported. The adsorbents’ reusability was confirmed through 4 repeated cycles of desorption-adsorption. The results discussed herein illustrate that NaSS based chemistries can be used as an efficient option for removal of organic dyes from contaminated wastewater.

Nanosponges based on self-assembled starfish-shaped cucurbit[6]urils functionalized with imidazolium arms

2021 ◽  
Author(s):  
Vincenzo Patamia ◽  
Davide Gentile ◽  
Roberto Fiorenza ◽  
Vera Muccilli ◽  
Placido Mineo ◽  
...  
Keyword(s):  
Porous Material ◽  
Porous Structure ◽  
Adsorption Capacity ◽  
High Adsorption ◽  
High Adsorption Capacity ◽  
Self Assembled

New porous material based on the first supramolecular cucurbituril-based nanosponge was synthetized by the functionalization of cucurbit[6]uril with twelve 1-(2-bromoethyl)-3-methyl-1H-imidazol-3-ium arms. The porous structure and the high adsorption capacity were...

Three dimensional MOF–sponge for fast dynamic adsorption

2017 ◽  
Vol 19 (8) ◽  
pp. 5746-5752 ◽  
Author(s):  
Huizeng Li ◽  
Mingzhu Li ◽  
Wenbo Li ◽  
Qiang Yang ◽  
Yanan Li ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Three Dimensional ◽  
Dynamic Adsorption ◽  
High Adsorption ◽  
Toxic Gases ◽  
High Adsorption Capacity ◽  
Fast Dynamic

Three-dimensional MOF–sponge with good permeability and high adsorption capacity was designed to dynamically purify toxic gases and effluents.

Calcined Mg-Fe Layered Double Hydroxide Adsorbent for Acid Red G Dye Removal

2013 ◽  
Vol 864-867 ◽  
pp. 719-726
Author(s):  
Li Qun Sun ◽  
Zhi Quan Ren
Keyword(s):  
Adsorption Capacity ◽  
Dye Adsorption ◽  
Kinetic Studies ◽  
Order Kinetic ◽  
High Adsorption ◽  
Solution Ph ◽  
Equilibrium Data ◽  
High Adsorption Capacity ◽  
Co Precipitation ◽  
Acid Red G

The calcined Mg-Fe LDH adsorbent (CLDH) was fabricated by co-precipitation and calcination processes. The adsorbent was characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy. The adsorbent exhibited high adsorption capacity for the removal of acid red G (ARG) dye. The effects of the adsorbent dose, solution pH, contact time, reaction temperature and initial ARG dye concentrations upon the ARG dye adsorption were investigated in detail. The kinetic studies indicated that the adsorption process was fitted well with the pseudo-second-order kinetic model (R2> 0.99). The equilibrium data were well described by the Freundlich equation. Moreover, after three regeneration cycles, the CLDH still showed high adsorption capacity. The results showed that the CLDH is an efficient adsorbent for the removal of organic pollutants from wastewater.

Nanoscale Self-Assembly Using Ion and Electron Beam Techniques: A Rapid Review

MRS Advances ◽  
2020 ◽  
Vol 5 (64) ◽  
pp. 3507-3520
Author(s):  
Chunhui Dai ◽  
Kriti Agarwal ◽  
Jeong-Hyun Cho
Keyword(s):  
Electron Beam ◽  
Self Assembly ◽  
Ion Beam ◽  
Three Dimensional ◽  
The Self ◽  
Stress Generation ◽  
Rapid Review ◽  
High Yield ◽  
3D Nanostructures ◽  
Self Assembled

AbstractNanoscale self-assembly, as a technique to transform two-dimensional (2D) planar patterns into three-dimensional (3D) nanoscale architectures, has achieved tremendous success in the past decade. However, an assembly process at nanoscale is easily affected by small unavoidable variations in sample conditions and reaction environment, resulting in a low yield. Recently, in-situ monitored self-assembly based on ion and electron irradiation has stood out as a promising candidate to overcome this limitation. The usage of ion and electron beam allows stress generation and real-time observation simultaneously, which significantly enhances the controllability of self-assembly. This enables the realization of various complex 3D nanostructures with a high yield. The additional dimension of the self-assembled 3D nanostructures opens the possibility to explore novel properties that cannot be demonstrated in 2D planar patterns. Here, we present a rapid review on the recent achievements and challenges in nanoscale self-assembly using electron and ion beam techniques, followed by a discussion of the novel optical properties achieved in the self-assembled 3D nanostructures.

Mercury Removal from Wastewater by Steamed Hoof Powder

1999 ◽  
Vol 40 (7) ◽  
pp. 109-116 ◽  
Author(s):  
M. H. Ansari ◽  
A. M. Deshkar ◽  
P. S. Kelkar ◽  
D. M. Dharmadhikari ◽  
M. Z. Hasan ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Adsorption Capacity ◽  
Adsorption Process ◽  
Adsorption Equilibrium ◽  
Light Metal ◽  
Mercury Removal ◽  
High Adsorption ◽  
Surface Sites ◽  
Ph Values ◽  
High Adsorption Capacity

Steamed Hoof Powder (SHP), size < 53μ, was observed to have high adsorption capacity for Hg(II) with >95% removal from a solution containing 100 mg/L of Hg(II) with only 0.1% (W/V) concentration of SHP. The SHP has good settling properties and gives clear and odour free effluent. Studies indicate that pH values between 2 and 10 have no effect on the adsorption of Hg(II) on SHP. Light metal ions like Na+, K+, Ca2+ and Mg2+ up to concentrations of 500 mg/L and heavy metals like Cu2+, Zn2+, Cd2+, Co2+, Pb2+, Ni2+, Mn2+, Cr3+, Cr6+, Fe2+ and Fe3+ up to concentrations of 100 mg/L do not interfere with the adsorption process. Anions like sulphate, acetate and phosphate up to concentrations of 200 mg/L do not interfere. Chloride interferes in the adsorption process when Hg(II) concentration is above 9.7 mg/L. The adsorption equilibrium was established within two hours. Studies indicate that adsorption occurs on the surface sites of the adsorbent.

Sign in / Sign up

Export Citation Format

Share Document