scholarly journals Super-Adsorbent Hydrogels for Removal of Methylene Blue from Aqueous Solution: Dye Adsorption Isotherms, Kinetics, and Thermodynamic Properties

Macromol ◽  
2021 ◽  
Vol 1 (4) ◽  
pp. 256-275
Author(s):  
Buddhabhushan Salunkhe ◽  
Thomas P. Schuman
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Organic Dyes ◽  
Polymer Network ◽  
Dye Adsorption ◽  
Isotherm Models ◽  
High Adsorption ◽  
High Adsorption Capacity ◽  
Efficient Option ◽  
Sodium Styrenesulfonate

Removal of dyes through adsorption from wastewater has gained substantial interest in recent years, especially in development of hydrogel based adsorbents, owing to their easy use and economical nature. The aim of the present study was to design a super-adsorbent hydrogel based on sodium styrenesulfonate (NaSS) monomer for removal of dyes like methylene blue (MB). NaSS displays both an aromatic ring and strongly ionic group in its monomer structure that can enhance adsorption capacity. Poly(sodium styrenesulfonate-co-dimethylacrylamide) hydrogels were prepared by solution free radical polymerization using gelatin methacryloyl (GelMA) as crosslinker, creating a highly porous, three-dimensionally crosslinked polymer network contributing to higher swelling ratios of up to 27,500%. These super-adsorbent hydrogels exhibited high adsorption capacity of 1270 mg/g for MB adsorption with above 98% removal efficiency. This is the first report for such a high adsorption capacity for dye absorbance for NaSS-based hydrogels. Additionally, the adsorption kinetics using a pseudo-first-order and the Freundlich adsorption isotherm models for multilayer, heterogeneous adsorption processes has been reported. The adsorbents’ reusability was confirmed through 4 repeated cycles of desorption-adsorption. The results discussed herein illustrate that NaSS based chemistries can be used as an efficient option for removal of organic dyes from contaminated wastewater.

scholarly journals Study on Adsorption of Nickel and Methylene Blue in Aqueous Solution by Magnetic Carboxylate-Rich Carbon

2021 ◽  
Vol 37 (2) ◽  
Author(s):  
Doan Van Dat ◽  
Nguyen Hoai Thuong ◽  
Tran Thi Kieu Ngan ◽  
Le Thi Thanh Nhi ◽  
Dao My Uyen ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Adsorption Capacity ◽  
Ph Value ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
High Adsorption ◽  
Endothermic Process ◽  
High Adsorption Capacity

In this study, magnetic carboxylate-rich carbon material (Fe3O4@CRC) was synthesized via a low-temperature carbonization method and applied as an adsorbent for adsorption of Ni(II) ions and methylene blue (MB) in aqueous solution. The synthesized Fe3O4@CRC was characterized by various techniques (XRD, FTIR, FE-SEM, TEM, EDX, VSM, and BET). The adsorption kinetics, isotherms, thermodynamics, and the effects of key adsorption factors, including the pH value, initial adsorbate concentration, contact time, adsorbent dose and temperature were investigated in detail. The results showed that Fe3O4@CRC exhibited a high adsorption capacity for MB and Ni(II) with the maximum adsorption capacity of 187.26 mg/g and 106.75 mg/g, respectively. The adsorption of MB and Ni(II) on Fe3O4@CRC was a spontaneous and endothermic process, and was best described with the first-order kinetic model, Freundlich (for MB) and Langmuir (for Ni(II)) isotherm models. In addition, Fe3O4@CRC could maintain a high adsorption capacity after many consecutive cycles. Therefore, the Fe3O4@CRC material can be used as a highly efficient adsorbent for the removal of heavy metals and dyes from wastewater due to the advantages of high adsorption performance, easy separation, and good reusability.  

scholarly journals Study on the adsorption of methylene blue from aqueous solution using hydrogel glucomannan/graphene oxide

2021 ◽  
Vol 10 (1) ◽  
pp. 59-66
Author(s):  
Son Le Lam ◽  
Phu Nguyen Vinh ◽  
Hieu Le Trung ◽  
Tan Le Thua ◽  
Nhan Dang Thi Thanh ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Graphene Oxide ◽  
Adsorption Capacity ◽  
Organic Dyes ◽  
Dye Adsorption ◽  
Order Kinetic ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order

Glucomannan/graphene oxide (GM/GO) hydrogel was synthesized by using calcium hydroxide as the crosslinker. The synthesized material was characterized by using IR, XRD, SEM, EDX and RAMAN technology. The composite hydrogel was used for removal of organic dyes from aqueous solution. The results showed that the GM/GO hydrogel had a porous structure and a high adsorption capacity toward methylene blue (MB). The pseudo-second-order kinetic model could fit the rate equation of MB adsorption onto the GM/GO hydrogel. The adsorption of MB onto GM/GO hydrogel was a spontaneous process. In addition, the equilibrium adsorption isotherm data indicated that equilibrium data were fitted to the Langmuir isotherm and the maximum dye adsorption capacity was 198,69 mg.g-1. Moreover, the hydrogel was stable and easily recovered and adsorption capacity was around 97% of the initial saturation adsorption capacity after being used five times.

scholarly journals Revealing the role of the 1T phase on the adsorption of organic dyes on MoS2 nanosheets

RSC Advances ◽  
2019 ◽  
Vol 9 (49) ◽  
pp. 28345-28356 ◽  
Author(s):  
Asmaa M. Omar ◽  
Ossama I. Metwalli ◽  
Mohamed R. Saber ◽  
Gomaa Khabiri ◽  
Mohamed E. M. Ali ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Active Sites ◽  
Organic Dyes ◽  
Carboxyl Groups ◽  
Mos2 Nanosheets ◽  
High Adsorption ◽  
Strong Binding ◽  
High Adsorption Capacity

The high adsorption capacity of dyes onto the 1T-rich MoS2 samples is due to the strong binding between the hydroxide/carboxyl groups and the 1T active sites. The capacity can be tuned by controlling the ratio between 1T and 2H phases of MoS2 nanosheets.

scholarly journals Ginger Straw Waste-Derived Porous Carbons as Effective Adsorbents toward Methylene Blue

Molecules ◽  
2019 ◽  
Vol 24 (3) ◽  
pp. 469 ◽  
Author(s):  
Wenlin Zhang ◽  
Huihe Li ◽  
Jianmin Tang ◽  
Hongjia Lu ◽  
Yiqing Liu
Keyword(s):  
Methylene Blue ◽  
Porous Materials ◽  
Adsorption Capacity ◽  
Adsorption Rate ◽  
Dye Wastewater ◽  
Porous Carbons ◽  
High Adsorption ◽  
New Approach ◽  
High Adsorption Capacity

In this work, ginger straw waste-derived porous carbons, with high adsorption capacity, high adsorption rate, and good reusability for removing the toxic dye of methylene blue from wastewater, were prepared by a facile method under oxygen-limiting conditions. This study opens a new approach for the utilization of ginger straw waste, and the porous materials can be employed as great potential adsorbents for treating dye wastewater.

Self-assembled three-dimensional graphene-based materials for dye adsorption and catalysis

2015 ◽  
Vol 3 (18) ◽  
pp. 10031-10037 ◽  
Author(s):  
Xueping Zhang ◽  
Dong Liu ◽  
Lu Yang ◽  
Limin Zhou ◽  
Tianyan You
Keyword(s):  
Adsorption Capacity ◽  
Self Assembly ◽  
Three Dimensional ◽  
Dye Adsorption ◽  
Reduction Process ◽  
High Adsorption ◽  
Graphene Aerogel ◽  
High Adsorption Capacity ◽  
Self Assembled

Graphene aerogel (GA) fabricated via a simultaneous self-assembly and reduction process showed high adsorption capacity towards dyes.

scholarly journals Ce-doped UiO-67 nanocrystals with improved adsorption property for removal of organic dyes

RSC Advances ◽  
2019 ◽  
Vol 9 (47) ◽  
pp. 27674-27683 ◽  
Author(s):  
Xue Dong ◽  
Yongcen Lin ◽  
Yuqin Ma ◽  
Lang Zhao
Keyword(s):  
Adsorption Capacity ◽  
Hydrothermal Method ◽  
Negative Charge ◽  
Organic Dyes ◽  
Adsorption Property ◽  
Cationic Dyes ◽  
High Adsorption ◽  
One Step ◽  
High Adsorption Capacity

The Ce-doped UiO-67 nanocrystals were successfully synthesized via a one-step hydrothermal method. Ce doping increases the negative charge on the surface of the material, thus the adsorbent exhibits high adsorption capacity to cationic dyes.

Parametric and adsorption kinetic studies of methylene blue removal from simulated textile water using durian (Durio zibethinus murray) skin

2015 ◽  
Vol 72 (6) ◽  
pp. 896-907 ◽  
Author(s):  
S. M. Anisuzzaman ◽  
Collin G. Joseph ◽  
D. Krishnaiah ◽  
A. Bono ◽  
L. C. Ooi
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Dye Adsorption ◽  
Freundlich Isotherm ◽  
Kinetic Studies ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Durio Zibethinus

In this study, durian (Durio zibethinus Murray) skin was examined for its ability to remove methylene blue (MB) dye from simulated textile wastewater. Adsorption equilibrium and kinetics of MB removal from aqueous solutions at different parametric conditions such as different initial concentrations (2–10 mg/L), biosorbent dosages (0.3–0.7 g) and pH solution (4–9) onto durian skin were studied using batch adsorption. The amount of MB adsorbed increased from 3.45 to 17.31 mg/g with the increase in initial concentration of MB dye; whereas biosorbent dosage increased from 1.08 to 2.47 mg/g. Maximum dye adsorption capacity of the durian skin was found to increase from 3.78 to 6.40 mg/g, with increasing solution pH. Equilibrium isotherm data were analyzed according to Langmuir and Freundlich isotherm models. The sorption equilibrium was best described by the Freundlich isotherm model with maximum adsorption capacity of 7.23 mg/g and this was due to the heterogeneous nature of the durian skin surface. Kinetic studies indicated that the sorption of MB dye tended to follow the pseudo second-order kinetic model with promising correlation of 0.9836 < R2 < 0.9918.

High adsorption capacity of V-doped TiO2 for decolorization of methylene blue

2012 ◽  
Vol 258 (19) ◽  
pp. 7299-7305 ◽  
Author(s):  
Thanh-Binh Nguyen ◽  
Moon-Jin Hwang ◽  
Kwang-Sun Ryu
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
High Adsorption ◽  
Doped Tio2 ◽  
High Adsorption Capacity
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