An electrochemically neutralized energy-assisted low-cost acid-alkaline electrolyzer for energy-saving electrolysis hydrogen generation

2018 ◽  
Vol 6 (12) ◽  
pp. 4948-4954 ◽  
Author(s):  
Yan Li ◽  
Junxiang Chen ◽  
Pingwei Cai ◽  
Zhenhai Wen

The ability to reduce the energy consumed and the cost in water splitting is crucial for the generation of hydrogen, which can be stored and then oxidized to deliver clean, abundant, and sustainable energy with the regeneration of water.

2019 ◽  
Vol 91 (11) ◽  
pp. 1733-1747
Author(s):  
Filip Mamon ◽  
Radek Fajgar ◽  
Vera Jandova ◽  
Eva Koci ◽  
Ivo Jakubec ◽  
...  

Abstract This paper reports an original nonstandard green concept to obtain TiO2 microrods with polyhedral densely stacked 3D nanovoids prepared via the heat treatment of a hydrogen titanate. The intermediate hydrogen titanate was synthesized by a solid-liquid-solid (SLS) route from an ammonia-saturated aqueous solution of TiOSO4 at 0 °C. The effect of the postgrowth thermal annealing procedure to remove ice (water) and the proposed mechanism to explain the underlying transitions from the intermediate precursor to nanostructured TiO2 microrods with stacked 3D nanovoids were investigated. The small-angle X-ray scattering (SAXS) analysis indicates that at temperatures above 500 °C, the release of confined ice (water) takes place, which leads to the creation of self-assembled polyhedral nanovoids open to the surface. Their size ranges from 5 to 78 nm in both length and width, with a depth of ~3.88 nm. The first use of these stacked 1D TiO2 microrods as the working electrode in a photoelectrochemical (PEC) cell for water splitting is demonstrated. The estimated value of ζ-potential depends on both annealing temperature and crystallite size. Anatase sample 1D TiO/800 with ζ-potential (−29.1) mV and average crystallite size ~68 nm was observed to be highly stable in aqueous suspension. The SLS method yields low-cost 1D TiO2 materials possessing high photoreactivity with water. The PEC measurements indicate that three-dimensional hollow structures with a controlled geometry via patterned 1D TiO2 surface are promising materials for hydrogen generation from water splitting.


Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 277
Author(s):  
Ravichandran Janani ◽  
Raja Preethi V ◽  
Shubra Singh ◽  
Aishwarya Rani ◽  
Chang-Tang Chang

One of the major aspects and advantages of solar energy conversion is the photocatalytic hydrogen generation using semiconductor materials for an eco-friendly technology. Designing a low-cost efficient material to overcome limited light absorption as well as rapid recombination of photogenerated charge carriers is essential to achieve considerable hydrogen generation. In recent years, sulfide based semiconductors have attracted scientific research interest due to their excellent solar response and narrow band gap. The present review focuses on the recent approaches in the development of hierarchical ternary sulfide based photocatalysts with a special focus on ZnIn2S4. We also observe how the electronic structure of ZnIn2S4 is beneficial for water splitting and the various strategies involved for improving the material efficiency for photocatalytic hydrogen generation. The review places emphasis on the latest advancement/new insights on ZnIn2S4 being used as an efficient material for hydrogen generation through photocatalytic water splitting. Recent progress on essential aspects which govern light absorption, charge separation and transport are also discussed in detail.


Author(s):  
Zeyu Ge ◽  
Fei Wang ◽  
Junji Guo ◽  
Jungang Ma ◽  
Chunyan Yu ◽  
...  

Fabricating energy-saving, inexpensive and high activity electrocatalysts for overall water splitting has always been a significant challenge. Electrochemical deposition is considered as a promising method for large-scale industrial applications, but...


2020 ◽  
Vol 68 (1) ◽  
pp. 49-56
Author(s):  
Gour Chand Mazumder ◽  
SM Nasif Shams ◽  
Md Habibur Rahman ◽  
Saiful Huque

In this paper, a low-cost water electrolyzer is developed and its performance study is presented. Locally found materials are used to develop the electrolyzer. The electrolyzer has two cells connected in parallel and bipolar electrode configuration. In common, different cells are connected in series but for this electrolyzer parallel connection has been tested. A very thin polymer, Nylon-140 has been used as separator membranes for this electrolyzer. In separator membrane assembly, the designed geometry creates two separate gas channels internally which enables the direct collection of hydrogen and oxygen gas from the designated outlet port of the electrolyzer. The geometry excludes the need of external tubing into each cell-compartments to collect hydrogen and oxygen separately. The developed electrolyzer is found to be 42% efficient with its highest production rate of 227.27 mL/min. The purity of hydrogen is found to be more than 92% and justified with the burn test. The cost is 20 times less than the commercial electrolyzers. The development method and scheme can be helpful to popularize the small scale use of hydrogen in Bangladesh for various renewable energy applications. Dhaka Univ. J. Sci. 68(1): 49-56, 2020 (January)


Author(s):  
Karan S Belsare ◽  
Gajanan D Patil

A low cost and reliable protection scheme has been designed for a three phase induction motor against unbalance voltages, under voltage, over voltage, short circuit and overheating protection. Taking the cost factor into consideration the design has been proposed using microcontroller Atmega32, MOSFETs, relays, small CTs and PTs. However the sensitivity of the protection scheme has been not compromised. The design has been tested online in the laboratory for small motors and the same can be implemented for larger motors by replacing the i-v converters and relays of suitable ratings.


2019 ◽  
Vol 2019 (4) ◽  
pp. 7-22
Author(s):  
Georges Bridel ◽  
Zdobyslaw Goraj ◽  
Lukasz Kiszkowiak ◽  
Jean-Georges Brévot ◽  
Jean-Pierre Devaux ◽  
...  

Abstract Advanced jet training still relies on old concepts and solutions that are no longer efficient when considering the current and forthcoming changes in air combat. The cost of those old solutions to develop and maintain combat pilot skills are important, adding even more constraints to the training limitations. The requirement of having a trainer aircraft able to perform also light combat aircraft operational mission is adding unnecessary complexity and cost without any real operational advantages to air combat mission training. Thanks to emerging technologies, the JANUS project will study the feasibility of a brand-new concept of agile manoeuvrable training aircraft and an integrated training system, able to provide a live, virtual and constructive environment. The JANUS concept is based on a lightweight, low-cost, high energy aircraft associated to a ground based Integrated Training System providing simulated and emulated signals, simulated and real opponents, combined with real-time feedback on pilot’s physiological characteristics: traditionally embedded sensors are replaced with emulated signals, simulated opponents are proposed to the pilot, enabling out of sight engagement. JANUS is also providing new cost effective and more realistic solutions for “Red air aircraft” missions, organised in so-called “Aggressor Squadrons”.


Author(s):  
Seyed Ehsan Hosseini

Renewable and sustainable energy has an evolving story as the ongoing trade war in the word is influencing crude oil prices. Moreover, the global warming is an inevitable consequence of the worldwide increasing rate of fossil fuel utilization which has persuaded the governments to invest on the clean and sustainable energy resources. In recent years, the cost of green energy has tumbled, making the price of renewables competitive to the fossil fuels. Although, the hydrogen fuel is still extremely expensive compared to the crude oil price, investigations about clean hydrogen fuel production and utilization has been developed significantly which demonstrate the importance of the hydrogen fuel in the future. This article aims to scrutinize the importance of green hydrogen fuel production from solar/wind energy.


2020 ◽  
Vol 67 (1) ◽  
pp. 142-147
Author(s):  
Alina A. Aleksandrova ◽  
Maksim S. Zhuzhin ◽  
Yuliya M. Dulepova

Energy saving today is an integral part of the development strategy of agricultural organizations. Considerable attention is paid to the modernization and automation of technological processes in agricultural enterprises, which can improve the quality of work and reduce the cost of production. The direction of modernization is to reduce the consumption of electric energy by improving the water treatment system in livestock complexes. (Research purpose) The research purpose is to determine the potential of solar energy used in the Nizhny Novgorod region and to determine the possibility of its use for water heating in livestock complexes and to consider the cost-effectiveness of using a device to heat water through solar energy. (Materials and methods) Authors used an improved algorithm of Pixer and Laszlo, applied in the NASA project «Surface meteorology and Energy», which allows to calculate the optimal angle of inclination of the device for heating water. (Results and discussion) Designed a mock-up of a livestock complex with a solar water heater installed on the roof, protected by patent for invention No. 2672656. A mathematical model was designed experimentally to predict the results of the plant operation in non-described modes. (Conclusions) The article reveales the optimal capacity of the circulation pump. Authors have created a mathematical model of the device that allows to predict the water heating in a certain period of time. The article presents the calculations on the energy and economic efficiency of using a solar water heater. An electric energy saving of about 30 percent, in the economic equivalent of 35 percent.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Dingwang Huang ◽  
Lintao Li ◽  
Kang Wang ◽  
Yan Li ◽  
Kuang Feng ◽  
...  

AbstractA highly efficient, low-cost and environmentally friendly photocathode with long-term stability is the goal of practical solar hydrogen evolution applications. Here, we found that the Cu3BiS3 film-based photocathode meets the abovementioned requirements. The Cu3BiS3-based photocathode presents a remarkable onset potential over 0.9 VRHE with excellent photoelectrochemical current densities (~7 mA/cm2 under 0 VRHE) and appreciable 10-hour long-term stability in neutral water solutions. This high onset potential of the Cu3BiS3-based photocathode directly results in a good unbiased operating photocurrent of ~1.6 mA/cm2 assisted by the BiVO4 photoanode. A tandem device of Cu3BiS3-BiVO4 with an unbiased solar-to-hydrogen conversion efficiency of 2.04% is presented. This tandem device also presents high stability over 20 hours. Ultimately, a 5 × 5 cm2 large Cu3BiS3-BiVO4 tandem device module is fabricated for standalone overall solar water splitting with a long-term stability of 60 hours.


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