scholarly journals Black titania nanotubes/spongy graphene nanocomposites for high-performance supercapacitors

RSC Advances ◽  
2019 ◽  
Vol 9 (22) ◽  
pp. 12555-12566 ◽  
Author(s):  
Dalia M. El-Gendy ◽  
Nabil A. Abdel Ghany ◽  
Nageh K. Allam

A simple method is demonstrated to prepare functionalized spongy graphene/hydrogenated titanium dioxide (FG-HTiO2) nanocomposites as interconnected, porous 3-dimensional (3D) network crinkly sheets.

2021 ◽  
pp. 25-61
Author(s):  
Leya Rose Raphael ◽  
Krishnan M A ◽  
Jarin D. Joyner ◽  
Akhila Das ◽  
Neethu T. M. Balakrishnan ◽  
...  

Author(s):  
Mark H. Ellisman

The increased availability of High Performance Computing and Communications (HPCC) offers scientists and students the potential for effective remote interactive use of centralized, specialized, and expensive instrumentation and computers. Examples of instruments capable of remote operation that may be usefully controlled from a distance are increasing. Some in current use include telescopes, networks of remote geophysical sensing devices and more recently, the intermediate high voltage electron microscope developed at the San Diego Microscopy and Imaging Resource (SDMIR) in La Jolla. In this presentation the imaging capabilities of a specially designed JEOL 4000EX IVEM will be described. This instrument was developed mainly to facilitate the extraction of 3-dimensional information from thick sections. In addition, progress will be described on a project now underway to develop a more advanced version of the Telemicroscopy software we previously demonstrated as a tool to for providing remote access to this IVEM (Mercurio et al., 1992; Fan et al., 1992).


Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 202
Author(s):  
Yexin Dai ◽  
Jie Ding ◽  
Jingyu Li ◽  
Yang Li ◽  
Yanping Zong ◽  
...  

In this work, reduced graphene oxide (rGO) nanocomposites doped with nitrogen (N), sulfur (S) and transitional metal (Ni, Co, Fe) were synthesized by using a simple one-step in-situ hydrothermal approach. Electrochemical characterization showed that rGO-NS-Ni was the most prominent catalyst for glucose oxidation. The current density of the direct glucose alkaline fuel cell (DGAFC) with rGO-NS-Ni as the anode catalyst reached 148.0 mA/cm2, which was 40.82% higher than the blank group. The DGAFC exhibited a maximum power density of 48 W/m2, which was more than 2.08 folds than that of blank group. The catalyst was further characterized by SEM, XPS and Raman. It was speculated that the boosted performance was due to the synergistic effect of N, S-doped rGO and the metallic redox couples, (Ni2+/Ni3+, Co2+/Co3+ and Fe2+/Fe3+), which created more active sites and accelerated electron transfer. This research can provide insights for the development of environmental benign catalysts and promote the application of the DGAFCs.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jeongpil Kim ◽  
Jeong-Hyun Eum ◽  
Junhyeok Kang ◽  
Ohchan Kwon ◽  
Hansung Kim ◽  
...  

AbstractHerein, we introduce a simple method to prepare hierarchical graphene with a tunable pore structure by activating graphene oxide (GO) with a two-step thermal annealing process. First, GO was treated at 600 °C by rapid thermal annealing in air, followed by subsequent thermal annealing in N2. The prepared graphene powder comprised abundant slit nanopores and micropores, showing a large specific surface area of 653.2 m2/g with a microporous surface area of 367.2 m2/g under optimized conditions. The pore structure was easily tunable by controlling the oxidation degree of GO and by the second annealing process. When the graphene powder was used as the supercapacitor electrode, a specific capacitance of 372.1 F/g was achieved at 0.5 A/g in 1 M H2SO4 electrolyte, which is a significantly enhanced value compared to that obtained using activated carbon and commercial reduced GO. The performance of the supercapacitor was highly stable, showing 103.8% retention of specific capacitance after 10,000 cycles at 10 A/g. The influence of pore structure on the supercapacitor performance was systematically investigated by varying the ratio of micro- and external surface areas of graphene.


Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 372
Author(s):  
Liyang Lin ◽  
Susu Chen ◽  
Tao Deng ◽  
Wen Zeng

The metal oxides/graphene nanocomposites have great application prospects in the fields of electrochemical energy storage and gas sensing detection. However, rational synthesis of such materials with good conductivity and electrochemical activity is the topical challenge for high-performance devices. Here, SnO2/graphene nanocomposite is taken as a typical example and develops a universal synthesis method that overcome these challenges and prepares the oxygen-deficient SnO2 hollow nanospheres/graphene (r-SnO2/GN) nanocomposite with excellent performance for supercapacitors and gas sensors. The electrode r-SnO2/GN exhibits specific capacitance of 947.4 F g−1 at a current density of 2 mA cm−2 and of 640.0 F g−1 even at 20 mA cm−2, showing remarkable rate capability. For gas-sensing application, the sensor r-SnO2/GN showed good sensitivity (~13.8 under 500 ppm) and short response/recovering time toward methane gas. These performance features make r-SnO2/GN nanocomposite a promising candidate for high-performance energy storage devices and gas sensors.


2016 ◽  
Vol 7 (2) ◽  
pp. 148-158 ◽  
Author(s):  
Rafeed A. Chaudhury ◽  
Victor Atlasman ◽  
Girish Pathangey ◽  
Nicholas Pracht ◽  
Ronald J. Adrian ◽  
...  

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