Hierarchical Z-scheme Fe2O3@ZnIn2S4 core–shell heterostructures with enhanced adsorption capacity enabling significantly improved photocatalytic CO2 reduction

CrystEngComm ◽  
2020 ◽  
Vol 22 (47) ◽  
pp. 8221-8227
Author(s):  
Zihan Zhao ◽  
Chuanxin Shi ◽  
Qi Shen ◽  
Wenjuan Li ◽  
Dandan Men ◽  
...  

The challenge of sunlight-driven CO2 reduction is to achieve efficient photocatalysts with exceptional molecule adsorption ability and efficient charge-separation efficiency.

2018 ◽  
Vol 6 (21) ◽  
pp. 9839-9845 ◽  
Author(s):  
Sha-Sha Yi ◽  
Jun-Min Yan ◽  
Qing Jiang

The carbon quantum dot (CQD) sensitized integrated Ti:Fe2O3@g-C3N4 core–shell nanoarrays demonstrate superior PEC water oxidation performance which can be ascribed to efficient charge separation efficiency derived from the well-confined heterojunction structure together with the high catalytic activity of the CQDs for H2O2 decomposition.


2019 ◽  
Vol 9 (24) ◽  
pp. 6899-6908 ◽  
Author(s):  
Yong Liang ◽  
Yuexing Chen ◽  
Maojun Zhao ◽  
Li Lin ◽  
Rongtao Duan ◽  
...  

The spatially separated Pt/CdS/N–ZnO/CoOx graphene microtubule (PCNZCo-GM) with double cocatalysts is prepared by a capillary action assisted hydrothermal method for enhancing charge separation efficiency and photocatalytic oxidation ability.


2020 ◽  
Vol 8 (1) ◽  
pp. 334-341 ◽  
Author(s):  
Guoqiang Zhang ◽  
Xun Yang ◽  
Chuanxin He ◽  
Peixin Zhang ◽  
Hongwei Mi

This study provides new insights into constructing efficient nitrogen-fixing photocatalysts by optimizing the OV concentration to coordinate the charge separation efficiency and dissociative adsorption capacity of N2.


2021 ◽  
Vol 865 ◽  
pp. 158836
Author(s):  
Deli Jiang ◽  
Qianxiao Zhang ◽  
Donghai Chen ◽  
Baowei Wen ◽  
Qi Song ◽  
...  

2017 ◽  
Vol 41 (3) ◽  
pp. 1028-1036 ◽  
Author(s):  
Qizhao Wang ◽  
Yanbiao Shi ◽  
Yang Sun ◽  
Houde She ◽  
Jie Yu ◽  
...  

Charge separation efficiency is improved by the enhanced built-in photogenerated electric field.


Author(s):  
Yanan Wang ◽  
Rongrong Shi ◽  
Kai Song ◽  
Chunyang Liu ◽  
Fang He

Exploring and adjusting the transport path of photo-generated carriers is vital to promote charge separation efficiency and charge transfer ability for photocatalytic hydrogen performance of novel semiconductor composites. Herein, this...


Nano Letters ◽  
2016 ◽  
Vol 16 (6) ◽  
pp. 3463-3474 ◽  
Author(s):  
Lite Zhou ◽  
Chenqi Zhao ◽  
Binod Giri ◽  
Patrick Allen ◽  
Xiaowei Xu ◽  
...  

2018 ◽  
Vol 8 (4) ◽  
pp. 1161-1175 ◽  
Author(s):  
Chao Liang ◽  
Cheng-Gang Niu ◽  
Hai Guo ◽  
Da-Wei Huang ◽  
Xiao-Ju Wen ◽  
...  

The self-assembly dual Z-scheme photocatalyst Ag@AgI/BiOI/g-C3N4 was successfully fabricated with high charge separation efficiency.


Nanophotonics ◽  
2020 ◽  
Vol 9 (7) ◽  
pp. 2077-2088 ◽  
Author(s):  
Daixun Jiang ◽  
Xun Sun ◽  
Xilu Wu ◽  
Shuai Zhang ◽  
Xiaofei Qu ◽  
...  

AbstractThe strategy to improve the photocatalytic removal efficiencies towards organic pollutants is still a challenge for the novel Sillen–Aurivillius perovskite type Bi4NbO8Cl. Herein, we report carbon-supported TiO2/Bi4NbO8Cl (C-TiO2/Bi4NbO8Cl) heterostructures with enhanced charge separation efficiency, which were fabricated via molten-salt flux process. The carbon-supported TiO2 particles were derived from MXene Ti3C2 precursors, and attached on plate-like Bi4NbO8Cl, acting as electron-traps to achieve supressed recombination of photo-induced charges. The improved charge separation confers C-TiO2/Bi4NbO8Cl heterostructures superior photocatalytic performance with 53% higher than pristine Bi4NbO8Cl, towards rhodamine B removal with the help of photo-induced holes. Moreover, the C-TiO2/Bi4NbO8Cl heterostructures can be expanded to deal with other water contaminants, such as methyl orange, ciprofloxacin and 2,4-dichlorophenol with 44, 25 and 13% promotion, respectively, and thus the study offers a series of efficient photocatalysts for water purification.


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