scholarly journals Highly efficient and selective membrane separation of copper from nickel in ammoniacal solution using mixtures of M5640 and BESO as membrane carriers

RSC Advances ◽  
2020 ◽  
Vol 10 (32) ◽  
pp. 18860-18867
Author(s):  
Hengpan Duan ◽  
Hongpan Liu ◽  
Chengbo Hu ◽  
Xiangjun Yang ◽  
Xuequan Wang

A FSSLM system developed with M5640/BESO as the synergistic carrier was used for selective separation of copper and nickel.


2021 ◽  
Author(s):  
Wei Liu ◽  
Ming Yang ◽  
Jing Liu ◽  
Meijia Yang ◽  
Jing Li ◽  
...  

Abstract The unique magnetic, electronic and optical features derived from their unpaired electrons have made radical polymers an attractive material platform for various applications. Here, we report solution-processable radical polymer membranes with multi-level porosities and study the impact of free radicals on important membrane separation processes including solar vapor generation, hydrogen separation and CO2 capture. The radical polymer is a supreme light absorber over the full solar irradiation range with sufficient water transport channels, leading to a highly efficient solar evaporation membrane. In addition, the radical polymer with micropores and adjustable functional groups are broad-spectrum gas separation membranes for both hydrogen separation and CO2 capture. First principle calculations indicate that the conjugated polymeric network bearing radicals is more chemically reactive with CO2, compared with H2, N2 and CH4. This is evidenced by a high CO2 permeability in gas separation membranes made of the conjugated radical polymer.



Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2468
Author(s):  
Viktoriya Polevaya ◽  
Anton Vorobei ◽  
Andrey Gavrikov ◽  
Samira Matson ◽  
Olga Parenago ◽  
...  

The modification of highly permeable films of brominated 1,2-disubstituted polyacetylene, poly(4-methyl-2-penthyne), via incorporation of in situ formed butylimidazolium bromide is reported for the first time. Principal possibility and efficiency of supercritical CO2 and CHF3 use as reaction media for the corresponding process, namely for quaternization of butylimidazole by brominated polymer are revealed. As a result, we prepared new membrane materials possessing promising properties such as stability toward organic solvents, good mechanical properties and significantly improved CO2-selectivity while maintaining gas permeability at high values. Comparative analysis of the results allowed us to determine content and conditions for the incorporation of butylimidazolium groups optimal for most efficient separation of CO2 from industrial gas mixtures. These results are of interest for the designing of new CO2 selective membranes.



2013 ◽  
Vol 86 (11) ◽  
pp. 1670-1675 ◽  
Author(s):  
F. Karimian ◽  
G. H. Rounaghi ◽  
M. H. Arbab-Zavar


2019 ◽  
Vol 20 (8) ◽  
pp. 1939 ◽  
Author(s):  
Loïc Henaux ◽  
Jacinthe Thibodeau ◽  
Geneviève Pilon ◽  
Tom Gill ◽  
André Marette ◽  
...  

The valorization of by-products from natural organic sources is an international priority to respond to environmental and economic challenges. In this context, electrodialysis with filtration membrane (EDFM), a green and ultra-selective process, was used to separate peptides from salmon frame protein hydrolysate. For the first time, the simultaneous separation of peptides by three ultrafiltration membranes of different molecular-weight exclusion limits (50, 20, and 5 kDa) stacked in an electrodialysis system, allowed for the generation of specific cationic and anionic fractions with different molecular weight profiles and bioactivity responses. Significant decreases in peptide recovery, yield, and molecular weight (MW) range were observed in the recovery compartments depending on whether peptides had to cross one, two, or three ultrafiltration membranes. Moreover, the Cationic Recovery Compartment 1 fraction demonstrated the highest increase (42%) in glucose uptake on L6 muscle cells. While, in the anionic configuration, both Anionic Recovery Compartment 2 and Anionic Recovery Compartment 3 fractions presented a glucose uptake response in basal condition similar to the insulin control. Furthermore, Cationic Recovery Compartment 3 was found to contain inhibitory peptides. Finally, LC-MS analyses of the bioassay-guided bioactive fractions allowed us to identify 11 peptides from salmon by-products that are potentially responsible for the glucose uptake improvement.



2017 ◽  
Vol 178 ◽  
pp. 56-65 ◽  
Author(s):  
Marjorie F.S. Dubreuil ◽  
Kelly Servaes ◽  
Dominic Ormerod ◽  
Diane Van Houtven ◽  
Wim Porto-Carrero ◽  
...  


2000 ◽  
Vol 24 (9-10) ◽  
pp. 2115-2123 ◽  
Author(s):  
Ana M Eliceche ◽  
Ana I Alonso ◽  
Inmaculada Ortiz


2016 ◽  
Vol 194 ◽  
pp. 1040-1047 ◽  
Author(s):  
Ruixia Gao ◽  
Xihui Cui ◽  
Yi Hao ◽  
Lili Zhang ◽  
Dechun Liu ◽  
...  


Author(s):  
Mingzhen Shi ◽  
Wenjie Xiong ◽  
Zhuoheng Tu ◽  
Xiaomin Zhang ◽  
Xingbang Hu ◽  
...  




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