Исследование поверхностного окисления циркония активным тепловым методом

The possibility of testing the surface oxidation of zirconium has been investigated by the method of one-way active thermal non-destructive testing based on the analysis of radiation temperatures. The emissivity of the oxidized surface of zirconium samples obtained at different annealing temperatures was estimated at various stages and heating temperatures in the infrared wavelength range. It is shown that there is a principal possibility to remotely test the oxidation process of zirconium alloys used in the nuclear industry for the manufacture of fuel elements operating in the core of nuclear reactors.

Optical and microwave observation of forest restoration after abnormal fires

The paper discusses the possibility of a forest undergrowth detecting with help of polarimetric decompositions and time series analysis of ALOS-2/PALSAR-2 and Sentinel-1 radar images. The presented results show principal possibility of confidently identifying the growth of forest stands.

Application of spectral and spatial processing methods to sonar images

The paper proposes the use of the method of renormalization with limitation (MRL) for suppressing the speckle noise of images obtained using sonar. The method is tested on real images obtained by the interferometric side-view sonar. The principal possibility of a significant reduction in the speckle noise level is found due to the fact that the MRL renormalizes the spectrum of the sonar image to the universal reference spectrum (URS) model, which is a model of the spectrum of a "good" quality grayscale image. To increase the overall sharpness of the image, after applying the MRL, it is proposed to use spatial brightness transformations. The study allows us to conclude that the application of MRL to sonar images can significantly reduce speckle noise.

Study on the behavior of zinc and associated metal-impurities in the process of chlorinating roasting of dross

In this work the issue of processing of dross with preliminary separation of the metal part from the oxide one is reviewed. Based on a comparative analysis of the results of known works it is shown that this approach can be quite effective if a technology is developed for the separate processing of the oxide part to obtain a commercial product. The authors of this work proposed carrying out chlorinating roasting under oxidizing conditions with various chlorine-containing reagents as one of the effective ways of processing the oxide part of the dross. Based on the thermodynamic analysis of the reactions of interaction between the components of the oxide part of the dross and calcium and ammonium chlorides, the principal possibility of obtaining pure zinc oxide, suitable for use as mineral additives in animal feed has been shown. As a result of thermodynamic calculations of the reactions of interaction of impurity metals with calcium chloride and ammonium chloride, the values of Gibbs free energy and reaction rate constants were determined in the temperature range 973 and 1373 K. It has been established that under the conditions of roasting the oxide part of the dross with both calcium chloride and ammonium chloride, a high degree of sublimation of impurity metals from the dross in the form of their chlorides into dust is achieved. It has been shown that roasting the oxide part of the dross using ammonium chloride is more efficient than with calcium chloride.

Трехмерная рентгеновская томография промышленных объектов при ограниченных размерах регистрирующего экрана

The article investigates the possibilities of using a 3D tomograph with a limited-sizes registering screen for detecting arbitrarily oriented crack-like defects in large industrial objects. Circular and spiral scanning schemes are considered, the principal possibility of detecting defects in the case of two-pass spiral scanning and a registering screen covering half of the view field of the test object cross-section is shown. The performance of the 3D reconstruction algorithm for the selected scanning method has been demonstrated.

Changing the Sizes of Details Made of Aluminum Alloys during Microarc Oxidation Process

It is shown that microarc oxidation (MAO) makes it possible to increase the size of aluminum alloy details by forming dense ceramic coatings (MAO-coatings) on them. Found that MAO-process a duration of 50...80 minutes in a liquid solution according to conventional technology allows you to increase the size of the details made of deformable alloy AMg3 and D16 by 78...80 % of the thickness formed on them MAO-coating and MAO-process in solution of corundum particles opens the possibility of increasing the same details by 98...100 % of the thickness formed on them more thick MAO coating. Revealed that increasing solution temperature from 15 to 45 оС leads to a reduction in the thickness of MAO coating and an even more significant reduction in growth dimensions, as well as to reduce the quality of their surfaces. It is shown that the removal of the outer layers of MAO coatings to a thickness of 20 ... 25 μm by grinding contributes to a significant reduction in the roughness of the surfaces of details. It is confirmed that MAO coatings obtained in liquid solution and in solution with corundum particles have a similar mainly polycrystalline structure, but MAO coatings obtained in solution with corundum particles differ in greater thickness and higher corundum content (α-Al2O3). It is established that the outer layers of MAO coatings are characterized by a relatively low content of modifications of crystalline aluminum oxide, so after their removal, the strength properties of the surfaces of details also improve. The principal possibility of increasing the size of details made of deformable aluminum alloys by 150 μm with ensuring high quality of their surfaces is proved.

CONSTRUCTION OF OPTICAL CONTROL ALGORITHMS FOR SMALL-SIZE DISTANT LIGHT OBJECTS

A mathematical model of the brightness structure of an ensemble of small-sized distant light objects in the plane of a photodetector is presented. The structure and principles of construction of optoelectronic systems for registration of distant and small-sized light objects are considered. A method for constructing of algorithms for determining the parameters of an ensemble of objects of different distances, obtained by an optoelectronic system with a digital camera of the light field, taking into account its characteristic features, is developed. A special experimental stand for the study of objects in distant conditions based on a telescopic system and a digital registrator is presented. The principal possibility of creating a light field correlator is shown. A number of algorithms and functions are described, as well as their capabilities to accurately measure the coordinates and parameters of small-sized light objects. The advantages and disadvantages of algorithms based on the continuous wavelet transform are investigated. A comparative analysis of the accuracy of determining the coordinates, dimensions, and features of small-sized objects by various algorithms is presented. It is shown, that the accuracy of determining the coordinates and parameters of small-sized remote objects by digital cameras of the light field is several times higher than by traditional digital cameras.

LIQUID LIGHT FILTER FOR THE VISIBLE SPECTRUM BASED ON HYDROPHILIC SOLUTIONS

The principal possibility of designing a liquid light filter using hydrophilic solutions is considered. Search for hydrophilic solutions with the most uniform light transmission at all wavelengths of the visible spectrum.

Effect of Fluorescent Labels on DNA Affinity for Gold Nanoparticles

Fluorophore (FD) labeling is widely used for detection and quantification of various compounds bound to nanocarriers. The systems, composed of gold nanoparticles (GNPs) and oligonucleotides (ONs) labeled with FDs, have wide applications. Our work was aimed at a systemic study of how FD structure (in composition of ON-FDs) influenced the efficiency of their non-covalent associates’ formation with GNPs (ON-FD/GNPs). We examined ONs of different length and nucleotide composition, and corresponding ON-FDs (FDs from a series of xanthene, polymethine dyes; dyes based on polycyclic aromatic hydrocarbons). Methods: fluorometry, dynamic light scattering, high performance liquid chromatography, gel electrophoresis, molecular modeling and methods of thermodynamic and statistical analysis. We observed significant, differing several times, changes in surface density and Langmuir constant values of ON-FDs vs. ONs, evidence for the critical significance of FD nature for binding of ON-FDs with GNPs. Surface density of ON-FD/GNPs; hydrophobicity and total charge of ON or ON-FD; and charge and surface area of FDs were revealed as key factors determining affinity (Langmuir constant) of ON or ON-FDs for GNPs. These factors compose a specific set, which makes possible the highly reliable prediction of efficiency of ONs and ON-FDs binding with GNPs. The principal possibility of creating an algorithm for predictive calculation of efficiency of ONs and GNPs interaction was demonstrated. We proposed a hypothetical model that described the mechanism of contact interaction between negatively charged nano-objects, such as citrate-stabilized GNPs, and ONs or ON-FDs.

ANALYSIS OF METHODS FOR CALCULATING HEAT TRANSFER IN THERMOELECTRIC COOLING SYSTEMS FOR HEAT-STRESSED ELEMENTS

На основе уравнений теплопереноса в движущейся среде и соотношений теплопередачи в термоэлектрическом охладителе приведен сравнительный анализ методик расчета поля температуры в теплонапряженном элементе. Рассмотрены методики на основе: 1) теплового баланса, 2) среднего коэффициента теплоотдачи, 3) дифференциального коэффициента теплоотдачи, 4) прямого расчета в рамках метода конечных элементов. Установлено, что первые две методики не дают адекватного распределения поля температур, но могут быть полезны для определения принципиальной возможности заданного охлаждения с использованием термоэлектрических элементов. Последние две методики позволяют корректно рассчитать температурное поле, но для использования третьей методики необходим дифференциальный коэффициент теплоотдачи, который может быть найден из расчета по четвертой методике. Сделан вывод о необходимости комбинированного использования методик в общем случае. Методы теплового баланса и среднего коэффициента теплоотдачи позволяют определить принципиальную возможность использования термоэлектрического охлаждения конкретного теплонапряженного элемента (ТЭ). Реальные параметры системы охлаждения должны определяться в рамках комбинации методов дифференциального коэффициента теплоотдачи и конечных элементов (МКЭ). Первый из них позволяет определить теплонапряженные области и рассчитать параметры системы охлаждения, которые обеспечивают тепловую разгрузку этих областей. Второй метод используется для проведения численных экспериментов по определению коэффициента теплоотдачи реальной конструкции The article presents on the basis of the equations of heat transfer in a moving medium and the relations of heat transfer in a thermoelectric cooler, a comparative analysis of methods for calculating the temperature field in a heat-stressed element. We considered methods based on: 1) heat balance, 2) average heat transfer coefficient, 3) differential heat transfer coefficient, 4) direct calculation using the finite element method. We established that the first two methods do not provide an adequate distribution of the temperature field but can be useful for determining the principal possibility of a given cooling using thermoelectric elements. The last two methods allow us to correctly calculate the temperature field; but to use the third method, we need a differential heat transfer coefficient, which can be found from the calculation using the fourth method. We made a conclusion about the need for combined use of methods in a general case. The methods of thermal balance and average heat transfer coefficient allow us to determine the principal possibility of using thermoelectric cooling of a specific heat-stressed element. The actual parameters of the cooling system should be determined using a combination of the differential heat transfer coefficient and the finite element method. The first of them allows us to determine the heat-stressed areas and calculate the parameters of the cooling system that provide thermal discharge of these areas. The second method is used to perform numerical experiments to determine the heat transfer coefficient of a real structure