scholarly journals Rhenium versus cadmium: an alternative structure for a thermally stable cadmium carbonyl compound

2020 ◽  
Vol 11 (43) ◽  
pp. 11763-11776
Author(s):  
Erika Amemiya ◽  
Aaron Loo ◽  
Daniel G. Shlian ◽  
Gerard Parkin

The previously reported novel cadmium carbonyl compound, [Cd(CO)3(C6H3Cl)]4, is better formulated as the rhenium compound, [Re(CO)3(C4N2H3S)]4.

1998 ◽  
Vol 512 ◽  
Author(s):  
C. Hecht ◽  
R. Kummer ◽  
A. Winnacker

ABSTRACTIn the context of spectral-hole burning experiments in 4H- and 6H-SiC doped with vanadium the energy positions of the V4+/5+ level in both polytypes were determined in order to resolve discrepancies in literature. From these numbers the band offset of 6H/4H-SiC is calculated by using the Langer-Heinrich rule, and found to be of staggered type II. Furthermore the experiments show that thermally stable electronic traps exist in both polytypes at room temperature and considerably above, which may result in longtime transient shifts of electronic properties.


1990 ◽  
Author(s):  
Elmer Klavetter ◽  
Tim O'Hern ◽  
Bill Marshall ◽  
Merrill Jr. ◽  
Frye Ray ◽  
...  

1984 ◽  
Vol 49 (6) ◽  
pp. 1448-1458
Author(s):  
Josef Kopešťanský

The effect of temperature and structure of the palladium surfaces on acetylene chemisorption was studied along with the interaction of the adsorbed layers with molecular and atomic hydrogen. The work function changes were measured and combined with the volumetric measurements and analysis of the products. At temperature below 100 °C, acetylene is adsorbed almost without dissociation and forms at least two different types of thermally stable adsorption complexes. Acetylene adsorbed at 200 °C is partly decomposed, especially in the low coverage region. Besides the above mentioned effects, the template effect of adsorbed acetylene was studied in the temperature range from -80° to 25 °C. It has been shown that this effect is a typical phenomenon of the palladium-acetylene system which is not due to surface impurities.


2019 ◽  
Vol 38 (24) ◽  
pp. 4615-4624 ◽  
Author(s):  
Alexander N. Selikhov ◽  
Andrey S. Shavyrin ◽  
Anton V. Cherkasov ◽  
Georgy K. Fukin ◽  
Alexander A. Trifonov

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Zhiyu Wang ◽  
Shun Wang ◽  
Guangyou Fang ◽  
Qunying Zhang

Nonpolarizable electrodes are applied widely in the electric field measurement for geophysical surveys. However, there are two major problems: (1) systematic errors caused by poor electrical contact in the high resistive terrains and (2) environmental damage associated with using nonpolarizable electrodes. A new alternative structure of capacitive electrode, which is capable of sensing surface potential through weak capacitive coupling, is presented to solve the above problems. A technique is introduced to neutralize distributed capacitance and input capacitance of the detection circuit. With the capacitance neutralization technique, the transmission coefficient of capacitive electrode remains stable when environmental conditions change. The simulation and field test results indicate that the new capacitive electrode has an operating bandwidth range from 0.1 Hz to 1 kHz. The capacitive electrodes have a good prospect of the applications in geophysical prospecting, especially in resistive terrains.


Author(s):  
Ramana Murthy Palle ◽  
Jing-Cai Zhang ◽  
Wei-Zhen Li

Pd-based catalysts are efficient for methane combustion but impractical at high temperatures due to sintering effect. Here in, we report a thermally stable Pd/SBA-15 catalyst that was prepared by using...


2021 ◽  
Author(s):  
Elena Gabirondo ◽  
Beatriz Melendez-Rodriguez ◽  
Carmen Arnal ◽  
Jose M. Lagaron ◽  
Antxon Martínez de Ilarduya ◽  
...  

Poly(ethylene furanoate) (PEF) films were first produced using thermo-compression. Thereafter, the chemical recyclability was demonstrated in the presence of a thermally stable organocatalyst followed by its repolymerization.


Polymer ◽  
2021 ◽  
pp. 123907
Author(s):  
Kazuma Yagura ◽  
Yunfan Zhang ◽  
Yukiko Enomoto ◽  
Tadahisa Iwata

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