Mussel byssus cuticle-inspired ultrastiff and stretchable triple-crosslinked hydrogels

Author(s):  
Chenglong Dong ◽  
Hailong Fan ◽  
Feng Tang ◽  
Xiaobin Gao ◽  
Kai Feng ◽  
...  

The triple-crosslinked hydrogel constructed through a crosslinking hierarchy exhibits significant increase in stiffness but without sacrificing the maximum elongation.

2021 ◽  
pp. 036354652110095
Author(s):  
Danko Dan Milinkovic ◽  
Christian Fink ◽  
Christoph Kittl ◽  
Petri Silanpää ◽  
Elmar Herbst ◽  
...  

Background: In contrast to the majority of existing techniques for reconstruction of the medial patellofemoral ligament (MPFL), the technique described in this article uses the adductor magnus muscle tendon to gain a flat, broad graft, leaving its distal femoral insertion intact, and does not require drilling within or near the femoral physis. It also allows for soft tissue patellar fixation and could facilitate anatomic MPFL reconstruction in skeletally immature patients. Purpose: To evaluate the anatomic and structural properties of the native MPFL and the adductor tendon (AT), followed by biomechanical evaluation of the proposed reconstruction. Study Design: Descriptive laboratory study. Methods: The morphological and topographical features of the AT and MPFL were evaluated in 12 fresh-frozen cadaveric knees. The distance between the distal insertion of the AT on the adductor tubercle and the adductor hiatus, as well as the desired length of the graft, was measured to evaluate this graft’s application potential. Load-to-failure tests were performed to determine the biomechanical properties of the proposed reconstruction construct. The construct was placed in a uniaxial testing machine and cyclically loaded 500 times between 5 and 50 N, followed by load to failure, to measure the maximum elongation, stiffness, and maximum load. Results: The mean ± SD length of the AT was 12.6 ± 1.5 cm, and the mean distance between the insertion on the adductor tubercle and adductor hiatus was 10.8 ± 1.3 cm, exceeding the mean desired length of the graft (7.5 ± 0.5 cm) by 3.3 ± 0.7 cm. The distal insertion of the AT was slightly proximal and posterior to the insertion of the MPFL. The maximum elongation after cyclical loading was 1.9 ± 0.4 mm. Ultimately, the mean stiffness and load to failure were 26.2 ± 7.6 N/mm and 169.7 ± 19.2 N, respectively. The AT graft failed at patellar fixation in 2 of the initially tested specimens and at the femoral insertion in the remaining 10. Conclusion: The described reconstruction using the AT has potential for MPFL reconstruction. The AT graft presents a graft of significant volume, beneficial anatomic topography, and adequate tensile properties in comparison with the native MPFL following the data from previously published studies. Clinical Relevance: Given its advantageous anatomic relationship as an application that avoids femoral drilling and osseous patellar fixation, the AT may be considered a graft for MPFL reconstruction in skeletally immature patients.


1996 ◽  
Vol 333 (1) ◽  
pp. 221-224 ◽  
Author(s):  
Christopher A. Klug ◽  
Luis A. Burzio ◽  
J.Herbert Waite ◽  
Jacob Schaefer

2016 ◽  
Vol 838-839 ◽  
pp. 568-573 ◽  
Author(s):  
Xiu Quan Han ◽  
Ming Jie Fu

The superplasticity of high Nb Ti3Al based alloy - Ti-23Al-17Nb (at.%) alloy sheet under the conditions of 940~1000°C and 5.5×10-5s-1~1.7×10-3s-1are studied. The results show the elongation changes as a parabola with the deformation temperature increasing, and the maximum elongation obtained at 960°C and 5.5x10-5s-1 is 1447.5%. Work hardening stage increases much more than softening stage when strain rate is decreased due to the increasing of element Nb. Compared with primary microstructure, the lath-like α2 grains gradually disappeared, the α2 grains became more equiaxed, and the content and size of α2 grains are decreasing with increasing of deformation temperature. The volume fraction ratio of α2 and β phase at the optimum deformation condition is 50:50%. The cavities mechanism at the fracture tip was discussed; it can be defined that the cavities could be avoided when deformation temperature is higher than 940°C.


2021 ◽  
Author(s):  
Ziwei Ge ◽  
Hongyan Liu

Abstract Rockfall triggered by earthquakes can cause severe infrastructure losses and even fatalities. The flexible protective barrier is an efficient rockfall protection system that has been widely used against rockfall. This studyproposed a novel approach to simulate a field test of rockfall impacting the flexible barrier, and the simulation results showed an excellent match with the field test results. Based on this approach, the seismic loading was applied to the numerical model, and four types of seismic loading were adopted, e.g., non-seismic, x-directional seismic, y-directional seismic, and z-directional seismic. This study aims at investigating the dynamic behavior of the flexible protective barrier under different seismic loading during the rockfall impact process. The following findings can be obtained from the simulation results. First of all, the seismic loading can increase the maximum elongation and decrease the final elongation of the flexible protective barrier comparing to non-seismic loading. Second, the largest deformation area of the protective barrier is at the diagonal position when x-directional seismic loading was applied, which is at the vertical bisector position when y-directional and z-directional seismic loading was applied. Third, the maximum elongation of the protective barrier decreased with the increasing seismic wave period. But in general, the amplitude and period of seismic waves have negligible effects on the elongation, maximum normal stress, and maximum shear stress of the flexible protective barrier.


2018 ◽  
Vol 13 (12) ◽  
pp. 1800146 ◽  
Author(s):  
Jia Wang ◽  
Thomas Scheibel

Materials ◽  
2019 ◽  
Vol 12 (18) ◽  
pp. 3005 ◽  
Author(s):  
Xianjie Yuan ◽  
Xuanhui Qu ◽  
Haiqing Yin ◽  
Zhenwei Yan ◽  
Zhaojun Tan

In this research, the effects of the compaction velocity on the sinterability of the Al–Fe–Cr–Ti powder metallurgy (PM) alloy by high velocity compaction were investigated. The Al–Fe–Cr–Ti alloy powder was compacted with different velocities by high velocity compaction and then sintered under a flow of high pure (99.999 wt%) nitrogen gas. Results indicated that both the sintered density and mechanical properties increased with increasing compaction velocity. By increasing the compaction velocity, the shrinkage of the sintered samples decreased. A maximum sintered density of 2.85 gcm−3 (relative density is 98%) was obtained when the compaction velocity was 9.4 ms−1. The radial and axial shrinkage were controlled to less than 1% at a compaction velocity of 9.4 ms−1. At a compaction velocity of 9.4 ms−1, sintered compacts with an ultimate tensile strength of 222 MPa and a yield strength of 160 MPa were achieved. The maximum elongation was observed to be 2.6%. The enhanced tensile properties of the Al–Fe–Cr–Ti alloy were mainly due to particle boundary strengthening.


2019 ◽  
Vol 6 (23) ◽  
pp. 1902043 ◽  
Author(s):  
Quan Xu ◽  
Meng Xu ◽  
Chun‐Yu Lin ◽  
Qiang Zhao ◽  
Rui Zhang ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 403 ◽  
Author(s):  
Yongqiang Du ◽  
Jian Zheng ◽  
Guibo Yu

Hydroxyl terminated polybutadiene (HTPB) coating is widely used in a solid rocket motor, but an aging phenomenon exists during long-term storage, which causes irreversible damage to the performance of this HTPB coating. In order to study the effect of aging on the dynamic mechanical properties of the HTPB coating, the thermally-accelerated aging test was carried out. The variation of maximum elongation and crosslinking density with aging time was obtained, and a good linear relationship between maximum elongation and crosslinking density was found by correlation analysis. The changing regularity of dynamic mechanical properties with aging time was analyzed. It was found that with the increase of aging time, Tg of HTPB coating increased, Tα, tan β and tan α decreased, and the functional relationships between the loss factor parameters and crosslinking density were constructed. The storage modulus and loss modulus of HTPB coating increased with the increase of aging time, and decreased with the increase of pre-strain. The aging enhanced the Payne effect of HTPB coating, while the pre-strain had a weakening effect. In view of the Payne effect of HTPB coating, the crosslinking density was introduced into Kraus model as aging evaluation parameter, and the crosslinking density modified models with and without pre-strain were established. The proposed models can effectively solve the problem that the Kraus model has a poor fitting effect under the condition of small strain (generally less than 1%) and on the loss modulus, which have improved the correlations between the fitting results and the test results.


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