scholarly journals Engineering Sr-doping for enabling long-term stable FAPb1−xSrxI3 quantum dots with 100% photoluminescence quantum yield

2021 ◽  
Vol 9 (5) ◽  
pp. 1555-1566
Author(s):  
Andrés F. Gualdrón-Reyes ◽  
David F. Macias-Pinilla ◽  
Sofia Masi ◽  
Carlos Echeverría-Arrondo ◽  
Said Agouram ◽  
...  

The Pb substitution in quantum dots (PQDs) with lesser toxic metals has been widely searched to be environmentally friendly, and be of comparable or improved performance compared to the lead-perovskite.

Author(s):  
Lin Yang ◽  
Bowen Fu ◽  
Xu Li ◽  
Hao Chen ◽  
Lili Li

All inorganic perovskite quantum dots (QDs) have received great attention owing to their excellent performance in optoelectronic applications. However, they often suffer from the defect-related photoluminescence (PL) quenching and phase...


Nanoscale ◽  
2021 ◽  
Author(s):  
Dongdong Yan ◽  
Qionghua Mo ◽  
Shuangyi Zhao ◽  
Wensi Cai ◽  
Zhigang Zang

With a high photoluminescence quantum yield (PLQY) being able to exceed 90% for those prepared by hot injection method, CsPbBr3 quantum dots (QDs) have attracted intensive attentions for white light-emitting...


Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 710 ◽  
Author(s):  
Sujeong Jung ◽  
Jae Ho Kim ◽  
Jin Woo Choi ◽  
Jae-Wook Kang ◽  
Sung-Ho Jin ◽  
...  

We determine the influence of substitutional defects on perovskite quantum dots through experimental and theoretical investigations. Substitutional defects were introduced by trivalent dopants (In, Sb, and Bi) in CsPbBr3 by ligand-assisted reprecipitation. We show that the photoluminescence (PL) emission peak shifts toward shorter wavelengths when doping concentrations are increased. Trivalent metal-doped CsPbBr3 enhanced the PL quantum yield (~10%) and air stability (over 10 days). Our findings provide new insights into the influence of substitutional defects on substituted CsPbBr3 that underpin their physical properties.


Nanoscale ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 2484-2491 ◽  
Author(s):  
Yue Zhai ◽  
Xue Bai ◽  
Gencai Pan ◽  
Jinyang Zhu ◽  
He Shao ◽  
...  

Co-doping of cation (La3+) and anion (F−) ions is a feasible method to improve the optical properties of CsPbCl3 QDs, and high photoluminescence quantum yield of 36.5% is achieved in CsPb(Cl0.7F0.3)3:La3+ QDs.


2020 ◽  
Vol 5 (3) ◽  
pp. 580-585 ◽  
Author(s):  
Yalong Shen ◽  
Jun Yin ◽  
Bo Cai ◽  
Ziming Wang ◽  
Yuhang Dong ◽  
...  

Lead-free Bi-based perovskite FA3Bi2X9 (X = Cl, Br, and I) quantum dots (QDs) are synthesized for the first time at room temperature. The ligand-passivated FA3Bi2Br9 QDs exhibit blue emission at 437 nm with photoluminescence quantum yield (PLQY) up to 52%.


RSC Advances ◽  
2016 ◽  
Vol 6 (32) ◽  
pp. 27068-27076 ◽  
Author(s):  
C. Zaba ◽  
O. Bixner ◽  
F. Part ◽  
C. Zafiu ◽  
C.-W. Tan ◽  
...  

We present the preparation of PEGylated mixed dispersant QDs from water-soluble nanocrystals, relevant for biomedical applications and environmental monitoring. We mastered control over grafting densities and PEG-conformation while retaining PLQY.


2015 ◽  
Vol 229 (1-2) ◽  
Author(s):  
Christian Würth ◽  
Daniel Geißler ◽  
Ute Resch-Genger

AbstractIn order to assess the anisotropy-related uncertainties of relatively determined photoluminescence quantum yields (


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