Local chemical fluctuation mediated ultra-sluggish martensitic transformation in high-entropy intermetallics

2022 ◽  
Author(s):  
Y. Wu ◽  
Fei Zhang ◽  
Fengshou Li ◽  
Yi Yang ◽  
Jiaming Zhu ◽  
...  

Superelasticity associated with the martensitic transformation has found a broad range of engineering applications such as low-temperature devices in aerospace industry. Nevertheless, the narrow working temperature range and strong temperature...

The specific heats of lithium metal of three different isotopic compositions (main components 99.99 at. % 7 Li, 92.7 at. % 7 Li ( ~ naturallithium) and 99.3 at. % 6 Li, respectively) and of sodium metal have been measured in the temperature range 3 to 30 °K. The 99.99 % 7 Li sample was also measured in the temperature range 0.4 to 1.5 °K. Within experimental error the differences in the lattice specific heats of the lithium samples are in accord with theoretical expectation. The values of the Debye temperatures in the low-temperature limit are 337.0±2*5 °K for 99.99% 7 Li, 344.0±2.5 °K for 92.7% 7 Li and 367.5±2.5 for 99.3% 6 Li. However, the temperature variation of the lattice specific heats of all the lithium samples is anomalous since the usual minimum in the Debye temperature as a function of temperature is not observed. Both lithium and sodium undergo a martensitic transformation on cooling to the temperature range of the present experiments. It was found that the amount of lithium transformed to the low-temperature phase is not increased appreciably by cooling below 20 °K, whereas the amount of sodium transformed is significantly increased on cooling below this temperature. After rapid cooling of the sodium sample to 3 °K, spontaneous heating is observed in the temperature range 4 to 16 °K ; the total heat emitted being about 0.05 cal/gatom . This is believed to correspond to annealing out of some of the defects introduced by the martensitic transformation. By thermally cycling the sodium sample up to 90 °K and back to 3 °K, the martensitic transformation was partially inhibited and the specific heats below 30 °K of the separated b.c.c. and h.c.p. phases were deduced, the low temperature limiting Debye temperatures being about 152.5 and 159 °K, respectively.


2005 ◽  
Vol 473-474 ◽  
pp. 237-242 ◽  
Author(s):  
E. Nagy ◽  
Valéria Mertinger ◽  
Ferenc Tranta ◽  
Jenő Sólyom

During thermomechanical treatment of austenitic stainless steel a’ martensite and e martensite form in the austenite matrix. The martensitic transformation and deforming existing together result a high elongation at the investigated steel belonging to the TRIP grades. The amount of a’and e martensite depends on the strain level as well as on the deforming temperature in this steel. In the course of thermomechanical treatments we measured the amount and texture of the existing phases at different temperature and strain. It has been stated that the martensites are dominant in low temperature range, they have a considerable amount, and the transformation from e martensite to a’ martensite also takes place. The amount of a’ martensite increases by increasing the strain while the amount of e martensite shows a maximum. By investigating the relationship between the quantity of existing phases and the effect of texture, it has been stated that the transformation takes place in certain given plates in the textured matrix.


In this work, we studied the low-temperature plasticity, elastic and dissipative characteristics, as well as the microstructural evolution of the Fe40Mn40Co10Cr10 high-entropy alloy in a wide temperature range of 300 - 0.5 K. The temperature dependences of yield strength, strain hardening, strength and ductility, as well as acoustic absorption and dynamic Young's modulus are obtained. It was found that the structure of Fe40Mn40Co10Cr10 alloy in the initial state is single-phase with fcc lattice, and in the deformed state at low temperatures it becomes two-phase due to the deformation-induced phase transition. In addition, EBSD analysis of the alloy structure revealed a change in grain morphology and the appearance of twin dislocations after plastic deformation at all investigatedtemperatures. Acoustic studies showed that the transition from the initial to the deformed state changes the character of the temperature dependence of the dynamic Young's modulus from almost linear to exponential, and reduces the absolute values. The Fe40Mn40Co10Cr10 alloy has excellent strength and ductility at a high strain hardening rate, which is explained by the significant contribution of the twinning process. With a decrease in temperature from 300 to 4.2 K, a strong temperature dependence of the yield strength is observed, which indicates the thermal activation of the nature of the plastic deformation of the alloys in this temperature range. In the temperature range of 0.5-4.2 K, an anomaly of the yield strength was observed, namely a decrease in the value of the yield strength with decreasing temperature from 4.2 K to 0.5 K. The anomalous dependence of the yield strength is due to a change in the mechanism of overcoming local barriers from thermoactivated to inertial one, when part of the local obstacles is overcome by dislocations without activation. This leads to a decrease in yield strength with decreasing temperature. At a temperature of 4.2 K and below, the smooth nature of the plastic deformation changes from smooth to serrated. The jumps begin immediately after the yield strength and gradually increase from 40 MPa to ~ 160 MPa. The results obtained are important for practical applications of high-entropy alloys at low temperatures.


2019 ◽  
Author(s):  
Dong Geun Kim ◽  
Yong Hee Jo ◽  
Junha Yang ◽  
Won-Mi Choi ◽  
Hyoung Seop Kim ◽  
...  

2020 ◽  
Vol 26 (S2) ◽  
pp. 2916-2917
Author(s):  
Luis Laguna Zubia ◽  
C.G. Garay-Reyes ◽  
M.A. Ruiz-Esparza-Rodriguez ◽  
J.M. Mendoza-Duarte ◽  
Ivanovich Estrada ◽  
...  

Author(s):  
Liyong Du ◽  
Dongxue Wang ◽  
Kuikun Gu ◽  
Mingzhe Zhang

The sensor based on 4 wt% PdO-loaded double-shell ZnSnO3 hollow microspheres shows rapid response/recovery speed to n-propanol at low working temperature.


Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 742
Author(s):  
Motomichi Koyama ◽  
Takeaki Gondo ◽  
Kaneaki Tsuzaki

The effects of ausforming in an Fe30Mn10Cr10Co high-entropy alloy on the microstructure, hardness, and plastic anisotropy were investigated. The alloy showed a dual-phase microstructure consisting of face-centered cubic (FCC) austenite and hexagonal close-packed (HCP) martensite in the as-solution-treated condition, and the finish temperature for the reverse transformation was below 200 °C. Therefore, low-temperature ausforming at 200 °C was achieved, which resulted in microstructure refinement and significantly increased the hardness. Furthermore, plasticity anisotropy, a common problem in HCP structures, was suppressed by the ausforming treatment. This, in turn, reduced the scatter of the hardness.


2003 ◽  
Vol 17 (27n28) ◽  
pp. 1453-1460
Author(s):  
ILEANA LUPSA

The magnetic properties of U 1-x Dy x Al y Ni 5-y (y=0,1) systems were investigated in the 2(5)–600 K temperature range and for fields up to 80 kOe. The systems having x≥0.2 are magnetically ordered with low transition temperatures and magnetization mainly due to the Dy contribution. The nickel exhibits magnetic moments, very weak in the low temperature range and well-defined effective moments over transition temperatures. The nickel behavior is discussed in terms of the spin fluctuation model.


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