Stable Quantum Dots/Polymer Matrix and Their Versatile 3D Printing Frameworks

Author(s):  
Ruda Xu ◽  
Qiao Chen ◽  
Min Xia ◽  
Bing Bai ◽  
Yuemei Li ◽  
...  

Efficient utilization of quantum dots (QDs) in bulk-scale matrix with good enough performance but small quantity is important in real industrial applications. Including the concern of traditional problems of QDs,...

2021 ◽  
Vol 144 (4) ◽  
Author(s):  
Dylan Joralmon ◽  
Evangeline Amonoo ◽  
Yizhen Zhu ◽  
Xiangjia Li

Abstract Lightweight and cost-effective polymer matrix composites (PMCs) with extraordinary mechanical performance will be a key to the next generation of diverse industrial applications, such as aerospace, electric automobile, and biomedical devices. Limpet teeth made of mineral-polymer composites have been proved as nature’s strongest material due to the unique hierarchical architectures of mineral fiber alignment. Here, we present an approach to build limpet teeth inspired structural materials with precise control of geometric morphologies of microstructures by magnetic field-assisted 3D printing (MF-3DP). α-Iron (III) oxide-hydroxide nanoparticles (α-FeOOHs) are aligned by the magnetic field during 3D printing and aligned α-FeOOHs (aFeOOHs) bundles are further grown to aligned goethite-based bundles (aGBs) by rapid thermal treatment after printing. The mechanical reinforcement of aGBs in PMCs can be modulated by adjusting the geometric morphology and alignment of α-FeOOHs encapsulated inside the 3D printed PMCs. In order to identify the mechanical enhancement mechanism, physics-based modeling, simulation, and tests were conducted, and the results further guided the design of bioinspired goethite-based PMCs. The correlation of the geometric morphology of self-assembled α-FeOOHs, curing characteristics of α-FeOOHs/polymer composite, and process parameters were identified to establish the optimal design of goethite-based PMCs. The 3D printed PMCs with aGBs show promising mechanical reinforcement compared with PMCs without aGBs. This study opens intriguing perspectives for designing high strength 3D printed PMCs on the basis of bioinspired architectures with customized configurations.


Author(s):  
Dylan Joralmon ◽  
Evangeline Amonoo ◽  
Yizhen Zhu ◽  
Xiangjia Li

Abstract Lightweight and cost-effective polymer matrix composites (PMCs) with extraordinary mechanical performance will be a key to the next generation of diverse industrial applications such as aerospace, electric automobile, and biomedical devices. Limpet teeth made of mineral-polymer composites have been proved as nature’s strongest material due to the unique hierarchical architectures of mineral fiber alignment. Here, we present an approach to build limpet teeth inspired structural materials with precise control of geometric morphologies of microstructures by magnetic field-assisted 3D printing (MF-3DP). α-Iron (III) oxide-hydroxide nanoparticles (α-FeOOHs) are aligned by the magnetic field during 3D printing and aligned α-FeOOHs bundles are further grown to aligned goethite-based bundles (aGBs) by rapid thermal treatment after printing. The mechanical reinforcement of goethite-based fillers in PMCs can be modulated by adjusting the geometric morphology and alignment of mineral particles encapsulated inside the 3D printed PMCs. In order to identify the mechanical enhancement mechanism, physics-based modeling, simulation, and tests were conducted and the results further guided the design of bioinspired goethite-based PMCs. The correlation of the geometric morphology of self-assembled α-FeOOHs, curing characteristics of α-FeOOHs/polymer composite, and process parameters were identified to establish the optimal design of goethite-based PMCs. The 3D-printed PMCs with aGBs show promising mechanical reinforcement. This study opens intriguing perspectives for designing high strength 3D printed PMCs on the basis of bioinspired architectures with customized configurations.


2021 ◽  
pp. 109679
Author(s):  
Yiwei Hu ◽  
Raj B. Ladani ◽  
Milan Brandt ◽  
Yazhi Li ◽  
Adrian P. Mouritz

Author(s):  
Xingjian Wei ◽  
Li Zeng ◽  
Zhijian Pei

Medical models are physical models of human or animal anatomical structures such as skull and heart. Such models are used in simulation and planning of complex surgeries. They can also be utilized for anatomy teaching in medical curriculum. Traditionally, medical models are fabricated by paraffin wax or silicone casting. However, this method is time-consuming, of low quality, and not suitable for personalization. Recently, 3D printing technologies are used to fabricate medical models. Various applications of 3D printed medical models in surgeries and anatomy teaching have been reported, and their advantages over traditional medical models have been well-documented. However, 3D printing of medical models bears some special challenges compared to industrial applications of 3D printing. This paper reviews more than 50 publications on 3D printing of medical models between 2006 and 2016, and discusses knowledge gaps and potential research directions in this field.


2018 ◽  
Vol 6 (28) ◽  
pp. 7584-7593 ◽  
Author(s):  
Cole D. Brubaker ◽  
Talitha M. Frecker ◽  
James R. McBride ◽  
Kemar R. Reid ◽  
G. Kane Jennings ◽  
...  

3D printing of cadmium sulfur selenide quantum dot functionalized materials compatible with fused deposition modeling type processes and applications.


2018 ◽  
Vol 935 ◽  
pp. 11-14
Author(s):  
Azamat L. Slonov ◽  
Azamat A. Zhansitov ◽  
Ismel V. Musov ◽  
Elina V. Khakyasheva ◽  
L.Kh. Kuchmenova ◽  
...  

The results of the studies of the effect of excipients of mineral and organic origin on the mechanical properties of polyether sulfone based on 4,4'-dihydroxydiphenyl and 4,4'-dichlordiphenylsulfone are adduced. It has been shown that the introduction of hard fillers is accompanied by the increased modulus and reduced ductility of the polymer matrix, the intensity of these effects depends on the concentration, shape and particle size additives. It was revealed that the composites with talc and discrete carbon fibers were characterized by higher mechanical properties. Their test as materials for FDM 3D printing method shows the highest suitability composites with talc for this technology.


Author(s):  
Judah Balli ◽  
Subha Kumpaty ◽  
Vince Anewenter

The purpose of this paper is to understand and research literature on the “continuous liquid interface production (CLIP)” of 3D objects to address the current challenges. This proprietary technology was originally owned by EiPi Systems but is now being developed by Carbon 3D. Unlike conventional rapid prototyping of printing layer-by-layer to print 3D objects, CLIP is achieved with an oxygen-permeable window made of proprietary glass membrane and the ultraviolet image projection plane below it, which allows the continuous liquid interface to produce 3D objects where photo-polymerization is restricted between the window and the polymerizing part. This process eliminates the time requirement in between the layers resulting in the faster production of 3D objects with a resolution less than 100 microns. It is a known factor that the “supports” play a vital role in any liquid based 3D printing techniques and this does not change in CLIP. In addition to the parameters of support structure like shape, size, strength, ease of removability, surface finish after removal of supports etc, CLIP needs to deal with different types of materials. The support structure needs to be designed according to the respective material’s properties. There are two broad categories of the materials available from Carbon 3D, prototyping resins, and engineering resins. While the prototyping resin is used for the cosmetic models and the engineering resins are used for the practical applications. There are 6 types of engineering resins developed for the end user; of these, EPU and CE are more challenging to work with. EPU parts needs more supports and careful handling till the completion of post processing as the material is soft. CE parts are fragile and needs more systematic handling to complete the successful production. Although printing parts of EPU and CE is more time consuming when compared to the normal CLIP process, they are worth for their unmatched industrial applications. None of the existing 3D printing technologies offers this quality. The support structure, orientation and pot life are the influencing parameters for all resins. In this study, it is statistically proven that by optimizing the part orientation with respect to the slicing of each layer and customized supports; parts are built way better than before. The part orientation is optimized by ensuring each layer is supporting the subsequent layer and minimizing the islands. It is noticed that the results are always better by tilting the part 5 to 10 degrees in both X and Y axis in the build setup and this applies for most of the straight geometrical parts. For parts of specific geometry which can create a vacuum while pulling up the part needs to be oriented in a different way or create a re-closable air passage that can prevent the vacuum being created.


2020 ◽  
Vol 4 (2) ◽  
pp. 42 ◽  
Author(s):  
Ignazio Blanco

Nowadays, all production, from the smallest ones to large companies, and research activities are affected by the use of 3D printing technology. The major limitation, in order to cover as many fields of application as possible, is represented by the set of 3D printable materials and their limited spectrum of physico-chemical properties. To expand this spectrum and employ the 3D-printed objects in areas such as biomedical, mechanical, electronical and so on, the introduction of fibers or particles in a polymer matrix has been widely studied and applied. In this review, all those studies that proposed modified polymer presenting advantages associated with rapid prototyping are reported.


2020 ◽  
Vol 51 (1) ◽  
pp. 1771-1774
Author(s):  
Yiyang Gao ◽  
Maksym F. Prodanov ◽  
Swadesh K. Gupta ◽  
Chengbin Kang ◽  
Valerii V. Vashchenko ◽  
...  

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