scholarly journals Research on chromium and arsenic speciation in atmospheric particulate matter: short review

2018 ◽  
Vol 28 ◽  
pp. 01026 ◽  
Author(s):  
Katarzyna Nocoń ◽  
Wioletta Rogula-Kozłowska ◽  
Kamila Widziewicz
Keyword(s):  
Particulate Matter ◽  
Arsenic Speciation ◽  
Atmospheric Precipitation ◽  
Speciation Analysis ◽  
Short Review ◽  
Atmospheric Particulate Matter ◽  
Potential Threat ◽  
Atmospheric Particulate ◽  
Size Fractions ◽  
As Species

Atmospheric particulate matter (PM) plays an important role in the distribution of elements in the environment. The PM-bound elements penetrates into the other elements of the environment, in two basic forms - those dissolved in the atmospheric precipitation and those permanently bound to PM particles. Those forms differs greatly in their mobility, thus posing a potential threat to living organisms. They can also be an immediate threat, while being inhaled. Chromium (Cr) and arsenic (As) belong to the group of elements whose certain chemical states exhibit toxic properties, that is Cr(VI) and As(III). Thus, recognition of the actual threat posed by Cr and As in the environment, including those present in PM, is possible only through the in depth speciation analysis. Research on the Cr and As speciation in PM, more than the analogous studies of their presence in other compartments of the environment, have been undertaken quite rarely. Hence the knowledge on the speciation of PM-bound As and Cr is still limited. The state of knowledge in the field of PM-bound Cr and As is presented in the paper. The issues related to the characterization and occurrence of Cr and As species in PM, the share of Cr and As species mass in different PM size fractions, and in PM of different origin is also summarized. The analytical techniques used in the speciation analysis of PM-bound Cr and As are also discussed. In the existing literature there is no data on the physical characteristics of Cr and As (bound to a different PM size fractions), and thus it still lack of data needed for a comprehensive assessment of the actual environmental and health threat posed by airborne Cr and As.

Arsenic speciation of atmospheric particulate matter (PM10) in an industrialised urban site in southwestern Spain

Chemosphere ◽  
2007 ◽  
Vol 66 (8) ◽  
pp. 1485-1493 ◽  
Author(s):  
Daniel Sánchez-Rodas ◽  
Ana Ma Sánchez de la Campa ◽  
Jesús D. de la Rosa ◽  
Vanesa Oliveira ◽  
José Luis Gómez-Ariza ◽  
...  
Keyword(s):  
Particulate Matter ◽  
Arsenic Speciation ◽  
Atmospheric Particulate Matter ◽  
Urban Site ◽  
Atmospheric Particulate

scholarly journals Effects of urban atmospheric particulate matter on higher plants using Lycopersicon esculentum as model species

2021 ◽  
Vol 3 (9) ◽  
Author(s):  
Katalin Hubai ◽  
Nora Kováts ◽  
Gábor Teke
Keyword(s):  
Particulate Matter ◽  
Lycopersicon Esculentum ◽  
Protein Content ◽  
Higher Plants ◽  
Nutrient Content ◽  
Atmospheric Particulate Matter ◽  
Dose Effect ◽  
Atmospheric Particulate ◽  
Wide Range ◽  
Treatment Experiment

AbstractAtmospheric particulate matter (PM) is one of the major environmental concerns in Europe. A wide range of studies has proved the ecotoxic potential of atmospheric particles. PM exerts chemical stress on vegetation by its potentially toxic constituents; however, relatively few studies are available on assessing phytotoxic effects under laboratory conditions. In our study, aqueous extract of particulate matter was prepared and used for treatment. Experiment was following the procedure defined by the No. 227 OECD Guideline for the Testing of Chemicals: Terrestrial Plant Test. Tomato (Lycopersicon esculentum Mill.) plants were used; elucidated toxicity was assessed based on morphological and biochemical endpoints such as biomass, chlorophyll-a and chlorophyll-b, carotenoids, and protein content. Biomass reduction and protein content showed a clear dose–effect relationship; the biomass decreased in comparison with the control (100%) in all test groups (TG) at a steady rate (TG1: 87.73%; TG2: 71.77%; TG3: 67.01%; TG4: 63.63%). The tendency in protein concentrations compared to the control was TG1: 113.61%; TG2: 148.21% TG3: 160.52%; TG4: 157.31%. However, pigments showed a ‘Janus-faced’ effect: nutrient content of the sample caused slight increase at lower doses; actual toxicity became apparent only at higher doses (chlorophyll-a concentration decrease was 84.47% in TG4, chlorophyll-b was 77.17%, and finally, carotene showed 83.60% decrease in TG4).

scholarly journals Toxic Organic Contaminants in Airborne Particles: Levels, Potential Sources and Risk Assessment

2021 ◽  
Vol 18 (8) ◽  
pp. 4352
Author(s):  
Donatella Pomata ◽  
Patrizia Di Filippo ◽  
Carmela Riccardi ◽  
Federica Castellani ◽  
Giulia Simonetti ◽  
...  
Keyword(s):  
Risk Assessment ◽  
Particulate Matter ◽  
Organic Contaminants ◽  
Human Health Risk ◽  
Airborne Particulate Matter ◽  
Principal Component ◽  
Cardiovascular Effects ◽  
Atmospheric Particulate Matter ◽  
Emission Source ◽  
Size Fractions

In the last years, many studies have focused on risk assessment of exposure of workers to airborne particulate matter (PM). Several studies indicate a strong correlation between PM and adverse health outcomes, as a function of particle size. In the last years, the study of atmospheric particulate matter has focused more on particles less than 10 μm or 2.5 μm in diameter; however, recent studies identify in particles less than 0.1 μm the main responsibility for negative cardiovascular effects. The present paper deals with the determination of 66 organic compounds belonging to six different classes of persistent organic pollutants (POPs) in the ultrafine, fine and coarse fractions of PM (PM < 0.1 µm; 0.1 < PM < 2.5 µm and 2.5 < PM < 10 µm) collected in three outdoor workplaces and in an urban outdoor area. Data obtained were analyzed with principal component analysis (PCA), in order to underline possible correlation between sites and classes of pollutants and characteristic emission sources. Emission source studies are, in fact, a valuable tool for both identifying the type of emission source and estimating the strength of each contamination source, as useful indicator of environment healthiness. Moreover, both carcinogenic and non-carcinogenic risks were determined in order to estimate human health risk associated to study sites. Risk analysis was carried out evaluating the contribution of pollutant distribution in PM size fractions for all the sites. The results highlighted significant differences between the sites and specific sources of pollutants related to work activities were identified. In all the sites and for all the size fractions of PM both carcinogenic and non-carcinogenic risk values were below acceptable and safe levels of risks recommended by the regulatory agencies.

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