scholarly journals The Determination and Practical Application the Kinetic Constants of Destruction of Rocks with Modified Zhurkov’s Formula

2018 ◽  
Vol 41 ◽  
pp. 01030
Author(s):  
Dmitry Sirota ◽  
Vadim Ivanov

Any kind of destruction is bound to microckracks. One of the theoretical model of microcracking is kinetic concept of strength (KCS) by S.N. Zhurkov. This theory allows to associate the time to failure with the activation energy and activation volume in single formula. But however, there are options for destruction in which this formula is incorrect. In this article we presents new modification of Zhurkov’s formula. Also, we present two possible practice applications of kinetic constants of the destruction.

1998 ◽  
Vol 63 (11) ◽  
pp. 1945-1953 ◽  
Author(s):  
Jiří Hanika ◽  
Karel Sporka ◽  
Petr Macoun ◽  
Vladimír Kysilka

The activity of ruthenium, palladium, and nickel catalysts for the hydrogenation of 1,2-dihydroacenaphthylene in cyclohexane solution was studied at temperatures up to 180 °C and pressures up to 8 MPa. The GC-MS technique was used to identify most of the perhydroacenaphthylene stereoisomers, whose fractions in the product were found dependent on the nature of the active component of the catalyst. The hydrogenation was fastest on the palladium catalyst (3% Pd/C). The nickel catalyst Ni-NiO/Al2O3, which is sufficiently active also after repeated use, can be recommended for practical application. The activation energy of 1,2-dihydroacenaphthylene hydrogenation using this catalyst is 17 kJ/mol, the reaction order with respect to hydrogen is unity.


2021 ◽  
Author(s):  
Siddhant Agarwal ◽  
Nicola Tosi ◽  
Pan Kessel ◽  
Sebastiano Padovan ◽  
Doris Breuer ◽  
...  

<p>The thermal evolution of terrestrial planets depends strongly on several parameters and initial conditions that are poorly constrained. Often, direct or indirect observables from planetary missions such as elastic lithospheric thickness, crustal thickness and duration of volcanism are inverted to infer the unknown parameter values and initial conditions. The non-uniqueness and non-linearity of this inversion necessitates a probabilistic inversion framework. However, due to the expensive nature of forward dynamic simulations of thermal convection , Markov Chain Monte Carlo methods are rarely used. To address this shortcoming, some studies have recently shown the effectiveness of Mixture Density Networks (MDN) (Bishop 1995) in being able to approximate the posterior probability using only the dataset of simulations run prior to the inversion (Meier et al. 2007, de Wit et al. 2013, Käufl et al. 2016, Atkins et al. 2016).</p><p>Using MDNs, we systematically isolate the degree to which a parameter can be constrained using different “present-day” synthetic observables from 6130 simulations for a Mars-like planet. The dataset – generated using the mantle convection code GAIA (Hüttig et al. 2013)- is the same as that used by Agarwal et al. (2020) for a surrogate modelling study.</p><p>The loss function used to optimize the MDN (log-likelihood) provides a single robust quantity that can be used to measure how well a parameter can be constrained. We test different numbers and combinations of observables (heat flux at the surface and core-mantle boundary, radial contraction, melt produced, elastic lithospheric thickness, and duration of volcanism) to constrain the following parameters: reference viscosity, activation energy and activation volume of the diffusion creep rheology, an enrichment factor for radiogenic elements in the crust, and initial mantle temperature. If all observables are available, reference viscosity can be constrained to within 32% of its entire range (10<sup>19</sup>−10<sup>22</sup> Pa s), crustal enrichment factor (1−50) to within 15%, activation energy (10<sup>5</sup>−5×10<sup>5</sup> J mol-1 ) to within 80%, and initial mantle temperature (1600−1800K) to within 39%. The additional availability of the full present-day temperature profile or parts of it as an observable tightens the constraints further. The activation volume (4×10<sup>-6</sup> −10×10<sup>-6</sup>  m<sup>3</sup> mol<sup>-1</sup>) cannot be constrained and requires research into new observables in space and time, as well as fields other than just temperature. Testing different levels of uncertainty (simulated using Gaussian noise) in the observables, we found that constraints on different parameters loosen at different rates, with initial temperature being the most sensitive. Finally, we present how the marginal MDN proposed by Bishop (1995) can be modified to model the joint probability for all parameters, so that  the inter-parameter correlations and the associated degeneracy can be capture, thereby providing a more comprehensive picture of all the evolution scenarios that fit given observational constraints.</p>


2005 ◽  
Vol 863 ◽  
Author(s):  
Steve Kilgore ◽  
Craig Gaw ◽  
Haldane Henry ◽  
Darrell Hill ◽  
Dieter Schroder

AbstractElectromigration tests were performed on passivated electroplated Au four terminal Kelvin line structures using the conventional in situ resistance monitoring technique. The stress conditions were a current density of 2.0 MA/cm2 with ambient temperatures ranging from 325°C to 375°C. The temperature coefficients of resistance (TCR) values were measured prior to current stressing to calculate the Joule heated film temperatures. The times to failure (lifetimes) for the Au line structures were considered as a 50% ΔR/R0 change. The median time to failure (t50%) was plotted against the inverse film temperature to determine the activation energy value as 0.59 ± 0.09 eV. Failure analysis of void location and suggested diffusion mechanism will be discussed.


2020 ◽  
pp. 28-31
Author(s):  
Valentin Karpovich

Theoretical knowledge may contain various levels of abstraction represented by logical constructions from the observed characteristics of objects from the subject area of the theory. The degree of abstractness can be de-scribed by the complexity of the structures obtained from the initial observational terms. Such auxiliary construc-tions are characterized as explicit or implicitdefinitions of theoretical concepts in terms of observational. One of the techniques for constructing such definitions is the operationalization of abstractions by a system of reduction sentences. In this case a theoretical concept is characterized as “open” and plays a role of logical and methodo-logical constraints for expanding the possible connections of the theoretical model with the help of concepts from the domain of intended practical application.


Author(s):  
Stephen Springer

This chapter addresses the author’s model to assist faculty members in gaining a closer relationship with distance learning students. The model that will be discussed consists of a greeting, message, reminder, and conclusion (GMRC). The GMRC will provide concrete recommendations designed to lead the faculty through the four steps. Using these steps in writing and responding to electronic messages demonstrates to the distance learning student that in fact the faculty member is concerned with each learner and the learner’s specific questions and needs. It is a practical application of human relations theory and is based on ideas generated by counseling theory. In addition, the chapter will take the reader through issues and examples that will arise during the duration of discussions and exchange of information using electronic messages. It is the intent of the author to provide not simply a theoretical model, but a model that can be learned and applied immediately upon completion of reviewing the article.


2005 ◽  
Vol 109 (35) ◽  
pp. 16567-16570 ◽  
Author(s):  
Malcolm D. Ingram ◽  
Corrie T. Imrie ◽  
Zlatka Stoeva ◽  
Steven J. Pas ◽  
Klaus Funke ◽  
...  

1994 ◽  
Vol 338 ◽  
Author(s):  
Y.-C. Joo ◽  
C.V. Thompson

ABSTRACTNear-bamboo interconnects are susceptible to failure either at polygranular clusters or within bamboo grains (transgranular failure). Polygranular failure mechanisms are often dominant in lines with near-bamboo structures at test conditions, but at service conditions, transgranular failure mechanisms are expected to dominate. In order to study the temperature and current density dependence as well as the crystallographic dependence of these transgranular failure mechanisms, it is necessary to isolate them from other mechanisms. To do this, we have studied single crystal Al lines on oxidized silicon.We have tested lifetimes of passivated and unpassivated Al single crystal lines with various textures. In both passivated and unpassivated lines, the median time to failure, t50, was found to be texture-dependent, with t50(l11) > t50(133) > t50(110), and with t50(111) ∼ 10×t50(110). The activation energy for failure for both passivated and unpassivated (110) single crystal lines was about 1 eV. This value differs from that of aluminum bulk diffusion (1.4 eV), suggesting that interface diffusion is the dominant diffusion mechanism in these lines, and perhaps in bamboo regions of near-bamboo lines as well.


Author(s):  
В.Б. Шуман ◽  
А.Н. Лодыгин ◽  
Л.М. Порцель ◽  
А.А. Яковлева ◽  
Н.В. Абросимов ◽  
...  

AbstractThe decomposition of a solid solution of interstitial magnesium Mg_ i in silicon is studied. Float-Zone dislocation-free single-crystal n -Si with a resistivity of ~8 × 10^3 Ω cm and oxygen and carbon contents of ~5 × 10^14 cm^–3 and ~1 × 10^15 cm^–3 is used in the experiments. The samples are doped using the diffusion sandwich method at T =1100°C followed by quenching. Decomposition of the supersaturated Mg_ i solid solution is studied by observing the kinetics of increasing the resistivity of doped samples resulting from their annealing in the range T = 400–620°C. It is found that the decomposition is characterized by an activation energy of E _ a ≈ 1.6 eV, which is close to the previously determined diffusion activation energy of Mg_ i in silicon. It is also shown that Si:Mg exhibits stable properties at temperatures not exceeding 400°C, which is important for its possible practical application.


Author(s):  
Д.А. Индейцев ◽  
Е.В. Осипова

The main processes occurring during vacancy generation in aluminum in the presence of hydrogen are described on the base of ab initio methods using the meta-functional SCAN. It was shown that hydrogen reduces the vacancy generation energy from 2.8 eV to 0.8 eV. In this case, eight hydrogen atoms located in the tetrahedral voids of the lattice around one aluminum atom make it much easier for it to move to the interstitial site. In accordance with the kinetic concept of embrittlement the dependence of the activation energy of hydrogen embrittlement of aluminum is calculated on the concentration of hydrogen and temperature. It is shown that hydrogen reduces the time of aluminum embrittlement only if its concentration in aluminum is more than critical one (~3⋅〖10〗^(-4) at T=293 K).


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