scholarly journals Tensile Strength and Moisture Resistance Properties of Biocomposite Films Based on Polyvinyl Alcohol (PVA) with Cellulose as Reinforcement from Durian Peel Fibers

2021 ◽  
Vol 302 ◽  
pp. 02001
Author(s):  
Melbi Mahardika ◽  
Mochamad Asrofi ◽  
Devita Amelia ◽  
Edi Syafri ◽  
Sanjay Mavinkere Rangappa ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Polyvinyl Alcohol ◽  
Cellulose Fibers ◽  
Moisture Resistance ◽  
Solution Casting ◽  
Casting Method ◽  
Elongation At Break ◽  
Biocomposite Films ◽  
Solution Casting Method ◽  
Biocomposite Film

Polyvinyl Alcohol (PVA) based biocomposite film with cellulose was successfully fabricated by the solution casting method. The cellulose fibers were obtained by extraction of durian peel using alkalization and bleaching treatments. These treated cellulose fibers were used for the fabrication of PVA-based biocomposites. The durian peel cellulose fibers were varied by 2%, 4%, 6%, and 8% in the PVA matrix. Tensile test and moisture resistance of biocomposites were evaluated. The 6% addition of cellulose fibers in biocomposites increases the tensile strength up to 54% (37 MPa) than pure PVA film (24 MPa). Conversely, it reduces the elongation at break of the biocomposite film. Meanwhile, the moisture resistance properties of the biocomposites increased with the addition of cellulose fibers. The tensile strength and moisture resistance of biocomposites have been increased due to the homogeneous dispersion of the cellulose fibers and PVA matrix. These biocomposites able to reduce the environmental impacts by utilizing residual lignocellulosic biomass.

Comparison of Starch Fiber Filled-Polyvinyl Alcohol and Native Starch Filled-Polyvinyl Alcohol under Tensile Analysis

2015 ◽  
Vol 1113 ◽  
pp. 19-22 ◽  
Author(s):  
Mohd Salleh Shahrul Nizam ◽  
Norzila Mohd ◽  
Zarina Omar ◽  
Norkamruzita Saadon
Keyword(s):  
Tensile Strength ◽  
Polyvinyl Alcohol ◽  
Interfacial Adhesion ◽  
Continuous Phase ◽  
Distilled Water ◽  
Solution Casting ◽  
Test Results ◽  
Casting Method ◽  
Native Starch ◽  
Solution Casting Method

The tensile properties of starch fiber (SF) and native starch (NS) filled polyvinyl alcohol were investigated in this study. Polyvinyl Alcohol (PVA) was blend with starch fiber as well as native starch. Prior to compounding process, PVA was plasticized with 30 phr glycerol as well as 10 phr distilled water. A solution casting method was used to prepare the SF-PPVA and NS-PPVA film sheet. Based on the tensile test results SF filled PVA recorded the highest tensile strength (20.015 MPa) as compared to NS filled PVA (12.302MPa). The tensile strength of the blends film was depending to the interfacial adhesion between matrixes in the blends. In spite of that, NS filled PVA have noted the highest elongation during the test. SF and NS played important role in affecting the blends matrix through disturbing the arrangement of continuous phase of PVA.

scholarly journals FTIR spectroscopy characterization and critical comparison of poly(vinyl)alcohol and natural hydroxyapatite derived from fish bone composite for bone-scaffold

2021 ◽  
Vol 2120 (1) ◽  
pp. 012004
Author(s):  
May Teng Hooi ◽  
Siew Wei Phang ◽  
Hui Ying Yow ◽  
Edmund David ◽  
Ning Xin Kim ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Vinyl Alcohol ◽  
Fish Bone ◽  
Poly Vinyl Alcohol ◽  
Solution Casting ◽  
Casting Method ◽  
Elongation At Break ◽  
Solution Casting Method ◽  
Extrusion Method

Abstract This paper presents the interaction comparison of poly(vinyl) alcohol (PVA) with hydroxyapatite derived from Spanish Mackerel (SM) and Whitefin Wolf Herring (WWH) bones, in different processing method. PVA filament and solution casting method illustrated higher crystallinity in the FTIR graph as compared to the PVA pellet and filament extrusion method. Besides, minimal interactions between PVA with glycerol and HAp was observed as well. PVA pellet and solution casting method portrait higher interaction as compared to the PVA filament and extrusion method. As for the HAp of SM and WWH, WWH had higher crystallinity and better cell adhesion with a higher Ca/P ratio while SM had relatively better mechanical strength with Ca/P ratio near to stoichiometric value. The loading of HAp (0, 2.5, 5, 10, 20, 30%) does not affect interactions of PVA/HAp composite in FTIR, and thermal properties in TGA. However, it caused an increase in crystallinity at low HAp loading and decreased at higher loading of HAp above 10%. Upon addition of HAp, tensile strength increased and elongation at break decreased. As the loading of HAp increased, both mechanical properties decreased. Scaffold with WWH composite possessed lower tensile strength and higher elongation at break than SM composite. The result of mechanical properties corresponded to the SEM result. ANOVA analysis justified the effect of HAp variations and loading on the mechanical properties of the composite was prominent.

Preparation and Properties of Poly(L-Lactid Acid)/Organo-Montmorillonite Composites by Solution Casting Method

2015 ◽  
Vol 731 ◽  
pp. 578-583
Author(s):  
Ming Jun Niu ◽  
Rui Xia Duan ◽  
Li Xia Wang ◽  
Xiao Qing Shen ◽  
Kai Guo ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Composite System ◽  
Composite Films ◽  
Solution Casting ◽  
Casting Method ◽  
Elongation At Break ◽  
Steady Level ◽  
Solution Casting Method ◽  
Degree Of Order ◽  
Thermal Stability Of

PLLA / OMMT composite films were prepared through solution casting method, in which chloroform was used as solvent. Mechanical, thermal and crystallization properties of neat PLLA and PLLA / OMMT composites films were investigated as well as morphology through scanning electron microscope. It was shown that tensile strength of PLLA / OMMT composite films gradually increased with increasing OMMT content, but reduced when more filler were added. Loading of 2wt% of OMMT seemed to benifit PLLA in tensile strength most. With the increase of montmorillonite content, the elongation at break of PLLA decreased first and then reached to a steady level. When compared with pure PLLA, the composite system showed decreased spherulite size, lower degree of order and an increase in the number of grains. Thermal analysis has proved that the addition of OMMT greatly enhanced crystability and thermal stability of PLLA.

scholarly journals Preparation and Characterization of HPMC/PVP Blend Films Plasticized with Sorbitol

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
H. Somashekarappa ◽  
Y. Prakash ◽  
K. Hemalatha ◽  
T. Demappa ◽  
R. Somashekar
Keyword(s):  
Mechanical Properties ◽  
Hydroxypropyl Methylcellulose ◽  
Solution Casting ◽  
Casting Method ◽  
Elongation At Break ◽  
X Ray ◽  
Blend Films ◽  
X Ray Scattering ◽  
Solution Casting Method

The aim of this present work is to investigate the effect of plasticizers like Sorbitol on microstructural and mechanical properties of hydroxypropyl methylcellulose (HPMC) and Polyvinylpyrrolidone (PVP) blend films. The pure blend and plasticized blend films were prepared by solution casting method and investigated using wide angle X-ray scattering (WAXS) method. WAXS analysis confirms that the plasticizers can enter into macromolecular blend structure and destroy the crystallinity of the films. FTIR spectra show that there are a shift and decrease in the intensity of the peaks confirming the interaction of plasticizer with the blend. Mechanical properties like tensile strength and Young’s Modulus decrease up to 0.6% of Sorbitol content in the films. Percentage of elongation at break increases suggesting that the plasticized films are more flexible than pure blend films. These films are suitable to be used as environmental friendly and biodegradable packaging films.

Effect of Corn Husk Content on Tensile Properties of Polylactic Acid Biocomposite Films

2015 ◽  
Vol 754-755 ◽  
pp. 66-70
Author(s):  
Mohd Akmalhakim bin Dato’ Hasnan ◽  
Salmah Husseinsyah ◽  
Lim Bee Ying ◽  
Mohd Faizal Abd Rahman
Keyword(s):  
Tensile Strength ◽  
Tensile Properties ◽  
Polylactic Acid ◽  
Modulus Of Elasticity ◽  
Solvent Casting ◽  
Casting Method ◽  
Elongation At Break ◽  
Study Materials ◽  
Corn Husk ◽  
Biocomposite Films

Nowadays bioplastics is the most recent study materials as the substitute for conventional plastics. The interest in bioplastics has lead to the production of polylactic acid (PLA) biocomposite films. In this study the PLA/Corn husk (CH) biocomposite films were prepared by using solvent casting method and the effect of CH content on the tensile properties were studied. The result found that increasing of CH content decreased the tensile strength and elongation at break of the biocomposites film. While, the modulus of elasticity increased with the increasing of CH content in the PLA matrix.

A study on the mechanical properties of graphene oxide/epoxy nanocomposites

2021 ◽  
pp. 096739112110111
Author(s):  
Rahim Eqra ◽  
Mohammad Hadi Moghim ◽  
Navid Eqra
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Graphene Oxide ◽  
Solution Casting ◽  
Casting Method ◽  
Epoxy Nanocomposites ◽  
Epoxy Nanocomposite ◽  
Solution Casting Method ◽  
Good Agreement

The aims of this research are to elucidate the role of graphene oxide on the mechanical properties of epoxy and also to obtain an equation for the modeling of its behavior. Accordingly, graphene oxide/epoxy nanocomposite samples are fabricated using the solution casting method. Tensile, flexural, SEM and FTIR tests are conducted on epoxy and the nanocomposite samples afterwards. The obtained results show that the tensile strength of epoxy improves even at low contents of graphene oxide such that 0.3 wt.% of GO yields an improvement of approximately 11.5%. The flexural strength of epoxy is also enhanced by 5.8% with 0.5 wt.% GO. Then, it decreases due to the agglomeration with increasing the GO content. In order to predict the tensile strength of GO/epoxy nanocomposites, a modified Halpin–Tsai equation is obtained with a new introduced correction factor as K = 39.5 Vf 1.135exp(2.9−1644.6 Vf). The obtained equation is in good agreement with the experimental data.

scholarly journals Preparation of PBS/PLLA/HAP Composites by the Solution Casting Method: Mechanical Properties and Biocompatibility

Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1778
Author(s):  
Muzamil Ahmad Khan ◽  
Zakir Hussain ◽  
Usman Liaqat ◽  
Muhammad Arman Liaqat ◽  
Muhammad Zahoor
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Tissue Regeneration ◽  
Solution Casting ◽  
X Ray Diffraction ◽  
Casting Method ◽  
Butylene Succinate ◽  
Polymeric Scaffolds ◽  
Solution Casting Method ◽  
Xrd Patterns

The use of biodegradable polymeric scaffolds for tissue regeneration is becoming a common practice in the clinic. Therefore, an inclined trend is developing with regards to improving the mechanical properties of these scaffolds. Here, we aim to improve the mechanical properties of poly (butylene succinate) (PBS)/poly (l-lactic acid) (PLLA) blends by incorporating hydroxyapatite nanoparticles (HAP) in the blends to form composites. PBS/PLLA = 100/0, 95/5, 90/10, 85/15, and 0/100 wt% blends, along-with the loadings of a few mg of HAPs, were prepared using the solution casting method. A scanning electron microscope showed the voids and droplets, indicating the immiscibility of blends. Due to this immiscibility, the tensile strength values of the blends were found to be in between that of pure PBS (42.85 MPa) and pure PLLA (31.39 MPa). HAPs act as a compatibilizer by incorporating themselves in the voids and spaces caused by the immiscibility, thus increasing the overall tensile strength of the resulting composite to a certain extent, e.g., the tensile strength of PBS/PLLA = 95/5 loaded with 50 mg HAPs was found to be 51.16 MPa. The structural analysis employing the X-ray diffraction (XRD) patterns confirmed the formation of polymer blends and composites. The contact angle analysis showed that the addition of HAPs increased the hydrophilicity of the resulting composites. Selective samples were investigated based on mechanical properties to see if the blends and composites are biocompatible. The obtained results showed that all of the samples with better mechanical properties demonstrated good biocompatibility. This indicates the effectiveness of scaffolds for tissue regeneration.

Synthesis, characterization and optical properties of polyvinyl alcohol–cerium oxide nanocomposite films

RSC Advances ◽  
2016 ◽  
Vol 6 (78) ◽  
pp. 74354-74366 ◽  
Author(s):  
K. S. Hemalatha ◽  
K. Rukmani
Keyword(s):  
Optical Properties ◽  
Polyvinyl Alcohol ◽  
Cerium Oxide ◽  
Nanocomposite Films ◽  
Solution Casting ◽  
Uv Filters ◽  
Casting Method ◽  
Solution Casting Method

PVA–CeO2 nanocomposite films were synthesized by solution casting method and exhibit tape like nanoribbon structure in the 25 wt% CeO2 films. The 2.5 wt% and 25 wt% CeO2 films are suitable for UV filters while the 2.5 wt% film shows highest photoluminescence.

scholarly journals Electrical and Mechanical Properties of Sugarcane Bagasse Pyrolyzed Biochar Reinforced Polyvinyl Alcohol Biocomposite Films

2021 ◽  
Vol 5 (9) ◽  
pp. 249
Author(s):  
Kawsar Ahmed ◽  
Mahbub Hasan ◽  
Julfikar Haider
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Polyvinyl Alcohol ◽  
Sugarcane Bagasse ◽  
Electrical Conductance ◽  
Biocomposite Films ◽  
Thermochemical Processing ◽  
Biocomposite Film ◽  
Experimental Findings ◽  
A Minor

Biochar obtained from the oxygen-deficient thermochemical processing of organic wastes is considered to be an effective reinforcing agent in biocomposite development. In the present research, biocomposite film was prepared using sugarcane bagasse pyrolyzed biochar and polyvinyl alcohol (PVA), and its electrical and mechanical properties were assessed. The biocomposite films were produced by varying content (5 wt.%, 8 wt.% and 12 wt.%) of the biochar produced at 400 °C, 600 °C, 800 °C and 1000 °C and characterized using X-Ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy. The experimental findings revealed that biochar produced at a higher pyrolyzing temperature could significantly improve the electrical conductance of the biocomposite film. A maximum electrical conductance of 7.67 × 10−2 S was observed for 12 wt.% addition of biochar produced at 1000 °C. A trend of improvement in the electrical properties of the biocomposite films suggested a threshold wt.% of the biochar needed to make a continuous conductive network across the biocomposite film. Rapid degradation of tensile strength was observed with an increasing level of biochar dosage. The lowest tensile strength 3.12 MPa was recorded for the film with 12 wt.% of biochar produced at 800 °C. Pyrolyzing temperature showed a minor impact on the mechanical strength of the biocomposite. The prepared biocomposites could be used as an electrically conductive layer in electronic devices.

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