scholarly journals Magnetization curves and hysteresis loops of nanostructured rare earth titanates

2018 ◽  
Vol 185 ◽  
pp. 03005
Author(s):  
Anatoly B. Rinkevich ◽  
Alexander V. Korolev ◽  
Mikhail I. Samoilovich ◽  
Sergej O. Demokritov ◽  
Dmitry V. Perov
Keyword(s):  
Magnetic Properties ◽  
Rare Earth ◽  
Hysteresis Loop ◽  
Magnetic Moment ◽  
Effective Magnetic Moment ◽  
Pyrochlore Structure ◽  
Hysteresis Loops ◽  
Nanocomposite Materials ◽  
Magnetization Curves ◽  
Crossing Point

Magnetic properties of the nanocomposite materials containing particles of rare earth titanates with pyrochlore structure have been investigated. For the nanocomposites with Gd2Ti2O7, La2Ti2O7 it has been observed that the effective magnetic moment in the nanocomposites differs substantially from that for Gd3+ and La3+ ions. The hysteresis loops was obtained for the nanocomposites with Dy3+, Gd3+, Yb3+, Er+, Sm3+ ions. There is no hysteresis loops for the nanocomposites with La2Ti2O7, Pr2Ti2O7 and Nd2Ti2O7 particles. It has been shown that nanocomposites with Yb2Ti2O7, Dy2Ti2O7 and Er2Ti2O7 particles have one crossing point on the descending branches of hysteresis loop in some temperature range.

scholarly journals Preparation and Magnetic Properties of CoFe2O4 Oriented Fiber Arrays by Electrospinning

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3860
Author(s):  
Chen Cheng ◽  
Jianfeng Dai ◽  
Zengpeng Li ◽  
Wei Feng
Keyword(s):  
Magnetic Properties ◽  
Magnetic Anisotropy ◽  
Hysteresis Loop ◽  
Magnetic Materials ◽  
Magnetic Moment ◽  
Easy Axis ◽  
Great Influence ◽  
Hysteresis Loops ◽  
Strong Anisotropy ◽  
Fiber Arrays

The morphology of magnetic materials has a great influence on the properties, which is attributed to the magnetic anisotropy of the materials. Therefore, it is worth studying the fabrication of the aligned fiber and the change of its domain distribution. Nanoparticles and nanofibers were prepared by the hydrothermal and electrospinning methods, respectively. At the same time, the arranged nanofibers were collected by the drum collecting device. After the same annealing at 700 °C, it was found that the diameter of fibers collected by different collecting drums is similar. By studying the hysteresis loops of nanoarrays, it was found that they had strong anisotropy. The easy axis was parallel to the long axis, the Hc and Mr of the easy axis and the hard axis were 1330.5 Oe, 32.39 Am2/kg, and 857.2 Oe, 24.8 Am2/kg, respectively. Due to the anisotropy of the shape and the interaction between the particles, the Hc could not be enhanced. Therefore, the Ms and Hc of the nanoparticles were 80.23 Am2/kg and 979.3 Oe, respectively. The hysteresis loop and the change of magnetic moment during the demagnetization of the CoFe2O4 nanofiber array were simulated via micromagnetic software. The simulated Hc was 1480 Oe, which was similar to the experimental value.

Ab initio calculation of magnetic properties of p-block element doped ZnO

RSC Advances ◽  
2014 ◽  
Vol 4 (85) ◽  
pp. 45598-45602 ◽  
Author(s):  
Palash Nath ◽  
Anirban Chakraborti ◽  
D. Sanyal
Keyword(s):  
Magnetic Properties ◽  
Ab Initio ◽  
Magnetic Moment ◽  
Ab Initio Calculation ◽  
Effective Magnetic Moment ◽  
Block Element ◽  
System P ◽  
Doped Zno

Effective magnetic moment for Zn54O53X (X = B, C, N, F, Al, Si, P, Cl, Ga, Ge, As) system.

Crystal Structure and Magnetic Properties of (2,2'-Dipyridyl)-(2-acetylphenolato)copper(II) Perchlorate

2002 ◽  
Vol 57 (10) ◽  
pp. 1129-1132 ◽  
Author(s):  
A. Elmali ◽  
Y. Elerman ◽  
I. Svoboda
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Magnetic Moment ◽  
Basal Plane ◽  
Effective Magnetic Moment ◽  
Mixed Ligand ◽  
Magnetic Susceptibility Data ◽  
Susceptibility Data ◽  
Dimeric Unit

The mixed-ligand dinuclear complex (2,2'-dipyridyl)-(2-acetylphenolato)copper(II) perchlorate was synthesized and its crystal structures determined. The structure consists of a dimeric unit involving a planar Cu2O2 group. The coordination sphere of the Cu atom can be described as an alongated octahedron where the basal plane is formed by the two N atoms of the 2,2'-dipyridyl molecule and the two O atoms of the acetophenon anion. Two apical Cu - O contacts complete the 4+2 coordination of the Cu atoms. They correspond to one of the O atoms of the perchlorate anion and to the O atom of the second unit. Magnetic susceptibility data obey the Curie-Weiss law with θ = -8.1(2) K. The decreasing of the effective magnetic moment from 1.94(8) μB at 300 K to 1.86(8) μB at 70 K and the negative Weiss constant indicate weak antiferromagnetic interactions between the two copper atoms in the dimeric units.

Structure and Magnetic Properties of a Dinuclear Complex with Iron(III) in Octahedral and Pyramidal Coordination

1994 ◽  
Vol 49 (9) ◽  
pp. 1239-1242 ◽  
Author(s):  
Ayhan Elmali ◽  
Yalcin Elerman ◽  
Ingrid Svoboda ◽  
Hartmut Fuess ◽  
Klaus Griesar ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Magnetic Moment ◽  
Effective Magnetic Moment ◽  
Dinuclear Complex ◽  
Monoclinic Space Group ◽  
Temperature Dependent ◽  
Space Group ◽  
Binuclear Unit

[FeL(MeOH)Cl]2 (L = N-(2-hydroxyphenyl)salicylaldimine) was synthesized and its crystal structure determined, [C27H20N 2O5Cl2Fe2], monoclinic, space group P21/c, a = 9.528(1), b = 7.684(1), c = 18.365(2) Å, β = 109.83(1)°, V = 1264.8 Å3, Z = 2. Two identical [FeL(MeOH)Cl] fragments, related by an inversion centre, are combined by the two bridging O atoms, to form a binuclear unit. The iron(III) centers are separated by 3.163(2) Å and weakly antiferromagnetically coupled (J = -8 .0 (1 ) cm-1), which follows from temperature - dependent magnetic susceptibility measurements in the range 4.2 to 288 K. The effective magnetic moment per iron(III) is μeff = 7.4 μB at 288 K

A water-soluble gadolinium metallofullerenol: facile preparation, magnetic properties and magnetic resonance imaging application

2016 ◽  
Vol 45 (21) ◽  
pp. 8696-8699 ◽  
Author(s):  
Jie Li ◽  
Taishan Wang ◽  
Yongqiang Feng ◽  
Ying Zhang ◽  
Mingming Zhen ◽  
...  
Keyword(s):  
Magnetic Resonance Imaging ◽  
Magnetic Properties ◽  
Magnetic Resonance ◽  
Magnetic Moment ◽  
Effective Magnetic Moment ◽  
Water Soluble ◽  
Resonance Imaging ◽  
Imaging Application ◽  
Facile Preparation ◽  
Imaging Performance

A new water-soluble gadolinium metallofullerenol with an enhanced effective magnetic moment and improved T1-weighted relaxivity and magnetic resonance imaging performance in the liver.

Magnetic Properties of Rare Earth Atoms in Palladium - Crystal Field Effects EPR and Magnetic Moment

1973 ◽  
Author(s):  
H. C. Praddaude ◽  
R. P. Guertin ◽  
S. Foner ◽  
E. J. McNiff ◽  
Hugh C. Wolfe ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Rare Earth ◽  
Crystal Field ◽  
Magnetic Moment ◽  
Field Effects

scholarly journals OBTAINING HYSTERESIS LOOPS AT LOW FREQUENCY FOR CHARACTERIZATION OF MATERIALS TO BE USED IN BIOMEDICAL APPLICATIONS

2015 ◽  
Vol 16 (1) ◽  
Author(s):  
Atika Arshad ◽  
Rumana Tasnim ◽  
Sheroz Khan ◽  
A.H.M Zahirul Alam
Keyword(s):  
Magnetic Field ◽  
Magnetic Properties ◽  
Hysteresis Loop ◽  
Magnetic Materials ◽  
Research Work ◽  
Low Frequency ◽  
Hysteresis Loops ◽  
Simple Circuit ◽  
Characterization Of Materials

The promising development of magnetic sensors in biomedical field demands an appropriate level of understanding of the magnetic properties of the materials used in their fabrication. To date only few of the types of magnetic materials are encountered where their magnetic properties, characterization techniques and magnetization behavior are yet to be explored more suitably in the light of their applications. This research work studies the characterization of materials by using a cost effective and simple circuit consisting of inductive transducer and an OP-AMP as a voltage integrator. In this approach the circuit was simulated using PSPICE and experiments have been conducted to achieve the desired results. The simulation and experimental results are obtained for three test materials namely iron, steel and plastic. The novelty lies in applying the simple circuit for material testing and characterization via obtaining simulation results and validating these results through experiment. The magnetic properties in low external magnetic field are studied with materials under test. The magnetization effect of a magneto-inductive sensor is detected in low frequency range for different magnetic core materials. The results have shown magnetization behaviour of magnetic materials due to the variation of permeability and magnetism. The resulted hysteresis loops appeared to have different shapes for different materials. The magnetic hysteresis loop found for iron core demonstrated a bigger coercive force and larger reversals of magnetism than these of steel core, thus obtaining its magnetic saturation at a larger magnetic field strength. The shape of the hysteresis loop itself is found to be varying upon the nature of the material in use. The resulted magnetization behaviors of the materials proved their possible applicability for use in sensing devices. The key concern of this work is found upon selecting the appropriate magnetic materials at the desired frequency of operation for magneto resistive applications, magneto-resistive sensors and for an extensive range of biomedical sensor application. 

Magnetic Properties of PrхY1-xFe3(BO3)4

2015 ◽  
Vol 233-234 ◽  
pp. 360-363
Author(s):  
A.I. Pankrats ◽  
A.A. Demidov ◽  
D.A. Velikanov ◽  
V.I. Tugarinov ◽  
V.L. Temerov
Keyword(s):  
Magnetic Field ◽  
Experimental Data ◽  
Magnetic Properties ◽  
Rare Earth ◽  
Field Model ◽  
Field Approximation ◽  
Magnetization Curves ◽  
Extensive Experimental Data ◽  
Theory And Experiment ◽  
Good Agreement

The magnetic properties of trigonal PrxY1-xFe3(BO3)4 compound have been investigated. Anomalies on the magnetization curves induced by a magnetic field are observed for each composition. The calculations were performed using a molecular-field approximation and a crystal-field model for the rare-earth subsystem. Extensive experimental data on the magnetic properties of PrxY1-xFe3(BO3)4 have been interpreted and good agreement between theory and experiment has been achieved.

Transition from Itinerant Electron Magnetism to Localized Spin Magnetism in Ni3Al1-YMny Alloys

2010 ◽  
Vol 168-169 ◽  
pp. 149-152 ◽  
Author(s):  
A.V. Korolyov ◽  
N.I. Kourov ◽  
S.Z. Nazarova ◽  
Y.A. Dorofeev ◽  
N.V. Volkova ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Curie Temperature ◽  
Magnetic Moment ◽  
Effective Magnetic Moment ◽  
Average Distance ◽  
Magnetic Moments ◽  
Itinerant Electron ◽  
Spin Magnetism ◽  
Spontaneous Magnetic Moment

Magnetic properties of Ni3Al1-yMny alloys at y≤0.6 were investigated at T≤400 K in magnetic fields H≤4 MA/m. The concentration y dependencies of the spontaneous magnetic moment s, the effective magnetic moment eff, the Curie temperature ТС, the Weiss constant , and the temperature independent part of the magnetic susceptibility 0 were determined. The behavior of the Rhodes-Wohlfarth parameter р(y) in the transition region from the itinerant electron magnetism to the spin localized one is related to the increase in the spontaneous magnetic moment of Ni atoms inversely proportional to the average distance between Mn atoms with the highly localized magnetic moments.

Synthesis, Structure Determination, and Magnetic Properties of [Cr3(dpa)4Cl2][CuCl2], a Compound Comprising a Trinuclear Chain Cation

2012 ◽  
Vol 67 (8) ◽  
pp. 759-764 ◽  
Author(s):  
Dilahan Aydin-Cantürk ◽  
Hanne Nuss Max-Planck
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Partial Oxidation ◽  
Ethyl Ether ◽  
Structure Determination ◽  
Magnetic Moment ◽  
Effective Magnetic Moment ◽  
X Ray ◽  
Weiss Constant ◽  
Paramagnetic Behavior

The new compound [Cr3(dpa)4Cl2][CuCl2] (1) (dpa = di-2,2'-pyridylamido) was synthesized by reacting Cr2(dpa)4 and anhydrous CuCl2 in dry tetrahydrofuran. Partial oxidation of Cr2(dpa)4 by Cu(II) forms Cr3+ ions, which coordinate to the free N donor atoms of the dpa ligands, and led to the formation of a trinuclear chain cation [Cr3(dpa)4Cl2]+. Recrystallization from CH2Cl2/ethyl ether yielded dark-brown, block-shaped crystals suitable for X-ray structure determination (Pccn (no. 56), a=1246:8(5), b=1487:3(3), c=2184:8(1) pm, V =4051.6(8) ·106 pm3, Z =4). The crystal structure is composed of discrete [Cr3(dpa)4Cl2]+ cations and [CuCl2]- anions. The Cr3 chain comprises quadruply-bonded diamagnetic (Cr2)4+ dimers and a pseudo-octahedrally coordinated, paramagnetic Cr3+ ion, manifesting itself in the effective magnetic moment μeff of 3:54μB (d3, S = 3=2) and the almost ideal Curie-paramagnetic behavior observed between 2 and 300 K with a Weiss constant θ = -0:25(4)K and χ0 = 4:9(7)×10-4 emu mol-1

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