scholarly journals Experimental investigation of frost induced damage of cement mortar

2019 ◽  
Vol 282 ◽  
pp. 02103
Author(s):  
Alicja Wieczorek ◽  
Marcin Koniorczyk ◽  
Kalina Grabowska
Keyword(s):  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Cement Mortar ◽  
Cement Matrix ◽  
Capillary Absorption ◽  
Water Absorption Coefficient ◽  
Cement Mortars ◽  
Water Saturated ◽  
The Impact

Questions connected to influence of frost degradation on microstructure and physical properties of water saturated cement mortars and their resistance to cyclic water freezing are the objectives of research. The main aim of the investigation is to analyze the ice-induced deterioration of cement mortars with different water/cement ratios (w/c=0.50 and 0.40) in a accelerated durability tests. The changes of pore size distribution and water absorption coefficient are investigated by means of mercury intrusion porosimetry and capillary absorption test. Additionally, the analysis of the impact of drying temperature (40°C, 60°C, 80°C and 105°C) on the microstructure is introduced.The performed tests enabled to estimate that the destruction of the cement matrix and the range of observed changes depend on the initial pore size distribution and their volume in the cement matrix. It is also established that the increase of transport properties is correlated with the change of pore size distribution. The obtained results allow to conclude a decrease of content of small pores (up to 150nm) and increase of larger pores for mortar with w/c=0.50. Application of superplasticizer, which resulting in reduction of water to cement ratio up to 0.40, allows to obtained resistant to 150 frost cycles cement mortar.

scholarly journals Effect of High-Dispersible Graphene on the Strength and Durability of Cement Mortars

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 915
Author(s):  
Xiaoqiang Qi ◽  
Sulei Zhang ◽  
Tengteng Wang ◽  
Siyao Guo ◽  
Rui Ren
Keyword(s):  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Cement Mortar ◽  
Chloride Ion ◽  
Cementitious Materials ◽  
Chloride Ion Penetration ◽  
Cement Mortars ◽  
Strength And Durability ◽  
Durability Performance

Graphene’s outstanding properties make it a potential material for reinforced cementitious composites. However, its shortcomings, such as easy agglomeration and poor dispersion, severely restrict its application in cementitious materials. In this paper, a highly dispersible graphene (TiO2-RGO) with better dispersibility compared with graphene oxide (GO) is obtained through improvement of the graphene preparation method. In this study, both GO and TiO2-RGO can improve the pore size distribution of cement mortars. According to the results of the mercury intrusion porosity (MIP) test, the porosity of cement mortar mixed with GO and TiO2-RGO was reduced by 26% and 40%, respectively, relative to ordinary cement mortar specimens. However, the TiO2-RGO cement mortars showed better pore size distribution and porosity than GO cement mortars. Comparative tests on the strength and durability of ordinary cement mortars, GO cement mortars, and TiO2-RGO cement mortars were conducted, and it was found that with the same amount of TiO2-RGO and GO, the TiO2-RGO cement mortars have nearly twice the strength of GO cement mortars. In addition, it has far higher durability, such as impermeability and chloride ion penetration resistance, than GO cement mortars. These results indicate that TiO2-RGO prepared by titanium dioxide (TiO2) intercalation can better improve the strength and durability performance of cement mortars compared to GO.

Trapping patterns during capillary displacements in disordered media

2022 ◽  
Vol 933 ◽  
Author(s):  
Fanli Liu ◽  
Moran Wang
Keyword(s):  
Numerical Simulations ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Disordered Media ◽  
Pore Geometry ◽  
Control Parameters ◽  
Pore Throat ◽  
The Impact ◽  
Theoretical Analyses

We investigate the impact of wettability distribution, pore size distribution and pore geometry on the statistical behaviour of trapping in pore-throat networks during capillary displacement. Through theoretical analyses and numerical simulations, we propose and prove that the trapping patterns, defined as the percentage and distribution of trapped elements, are determined by four dimensionless control parameters. The range of all possible trapping patterns and how the patterns are dependent on the four parameters are obtained. The results help us to understand the impact of wettability and structure on trapping behaviour in disordered media.

scholarly journals Impact of Polymer Binders on the Structure of Highly Filled Zirconia Feedstocks

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2247
Author(s):  
Claire Delaroa ◽  
René Fulchiron ◽  
Eric Lintingre ◽  
Zoé Buniazet ◽  
Philippe Cassagnau
Keyword(s):  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
High Density Polyethylene ◽  
Mercury Porosimetry ◽  
High Density ◽  
Organic Binder ◽  
Molten State ◽  
Homogeneous Dispersion ◽  
The Impact

The impact of polypropylene and high-density polyethylene backbone binders on the structure of organic matrix, feedstock, and ceramic parts is investigated in terms of morphology in this paper. The miscibility of wax with polyethylene and polypropylene is investigated in the molten state via a rheological study, revealing wax full miscibility with high-density polyethylene and restricted miscibility with polypropylene. Mercury porosimetry measurements realized after wax extraction allow the characterization of wax dispersion in both neat organic blends and zirconia filled feedstocks. Miscibility differences in the molten state highly impact wax dispersion in backbone polymers after cooling: wax is preferentially located in polyethylene phase, while it is easily segregated from polypropylene phase, leading to the creation of large cracks during solvent debinding. The use of a polyethylene/polypropylene ratio higher than 70/30 hinders wax segregation and favors its homogeneous dispersion in organic binder. As zirconia is added to organic blends containing polyethylene, polypropylene, and wax, the pore size distribution created by wax extraction is shifted towards smaller pores. Above zirconia percolation at 40 vol%, the pore size distribution becomes sharp attesting of wax homogeneous dispersion. As the PP content in the organic binder decreases from 100% to 0%, the pore size distribution is reduced of 30%, leading to higher densification ability. In order to ensure a maximal densification of the final ceramic, polyethylene/polypropylene ratios with a minimum content of 70% of high-density polyethylene should be employed.

scholarly journals Physical parameters of Fluvisols on flooded and non-flooded terraces

2017 ◽  
Vol 31 (1) ◽  
pp. 73-82 ◽  
Author(s):  
Milena Kercheva ◽  
Zofia Sokołowska ◽  
Mieczysław Hajnos ◽  
Kamil Skic ◽  
Toma Shishkov
Keyword(s):  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Mercury Intrusion Porosimetry ◽  
Water Retention Curve ◽  
Anthropogenic Factors ◽  
Physical Parameters ◽  
Water Desorption ◽  
Mercury Intrusion ◽  
The Impact

Abstract The heterogeneity of soil physical properties of Fluvisols, lack of large pristine areas, and different moisture regimes on non-flooded and flooded terraces impede the possibility to find a soil profile which can serve as a baseline for estimating the impact of natural or anthropogenic factors on soil evolution. The aim of this study is to compare the pore size distribution of pristine Fluvisols on flooded and non-flooded terraces using the method of the soil water retention curve, mercury intrusion porosimetry, nitrogen adsorption isotherms, and water vapour sorption. The pore size distribution of humic horizons of pristine Fluvisols on the non-flooded terrace differs from pore size distribution of Fluvisols on the flooded terrace. The peaks of textural and structural pores are higher in the humic horizons under more humid conditions. The structural characteristics of subsoil horizons depend on soil texture and evolution stage. The peaks of textural pores at about 1 mm diminish with lowering of the soil organic content. Structureless horizons are characterized by uni-modal pore size distribution. Although the content of structural pores of the subsoil horizons of Fluvisols on the non-flooded terrace is low, these pores are represented by biopores, as the coefficient of filtration is moderately high. The difference between non-flooded and flooded profiles is well expressed by the available water storage, volume and mean radius of pores, obtained by mercury intrusion porosimetry and water desorption, which are higher in the surface horizons of frequently flooded Fluvisols.

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