scholarly journals Acoustic travel time gauges for in-situ determination of pressure and temperature in multi-anvil apparatus

2015 ◽  
Vol 118 (6) ◽  
pp. 065901 ◽  
Author(s):  
Xuebing Wang ◽  
Ting Chen ◽  
Xintong Qi ◽  
Yongtao Zou ◽  
Jennifer Kung ◽  
...  
2022 ◽  
Author(s):  
Qingze Li ◽  
Xiping Chen ◽  
Lei Xie ◽  
Tiexin Han ◽  
Jiacheng Sun ◽  
...  

Abstract Here, simultaneous in-situ calibration of pressures and temperatures was performed in a hinge-type second-stage cubic large volume press (LVP) up to 15 GPa and 1400 K by an acoustic travel-time approach. Based on the recently reported P-t S and P-T-t P -t S equations for Al2O3 buffer rod, the cell pressures and temperatures in the chamber of LVP were in-situ determined, in comparison with those by conventional off-line (or fixed-points) pressure calibration method and direct thermocouple measurement, respectively. It is found that the cell pressures of the LVP chamber are significantly reduced after annealing at simultaneous high pressures and high temperatures, owing to the stress relaxation as accumulate in the LVP chamber. This acoustic travel-time method is validated to be a good way for precise determination of thermal (cell) pressures at high temperature conditions, and is of great importance and necessity to conduct in-situ physical property measurements under extreme high P-T conditions, especially when the precious synchrotron X-ray/neutron diffraction beams are not available.


1961 ◽  
Vol 38 (4) ◽  
pp. 545-562 ◽  
Author(s):  
L. Kecskés ◽  
F. Mutschler ◽  
I. Glós ◽  
E. Thán ◽  
I. Farkas ◽  
...  

ABSTRACT 1. An indirect paperchromatographic method is described for separating urinary oestrogens; this consists of the following steps: acidic hydrolysis, extraction with ether, dissociation of phenol-fractions with partition between the solvents. Previous purification of phenol fraction with the aid of paperchromatography. The elution of oestrogen containing fractions is followed by acetylation. Oestrogen acetate is isolated by re-chromatography. The chromatogram was developed after hydrolysis of the oestrogens 'in situ' on the paper. The quantity of oestrogens was determined indirectly, by means of an iron-reaction, after the elution of the iron content of the oestrogen spot, which was developed by the Jellinek-reaction. 2. The method described above is satisfactory for determining urinary oestrogen, 17β-oestradiol and oestriol, but could include 16-epioestriol and other oestrogenic metabolites. 3. The sensitivity of the method is 1.3–1.6 μg/24 hours. 4. The quantitative and qualitative determination of urinary oestrogens with the above mentioned method was performed in 50 pregnant and 9 non pregnant women, and also in 2 patients with granulosa cell tumour.


2020 ◽  
Author(s):  
Keishiro Yamashita ◽  
Kazuki Komatsu ◽  
Hiroyuki Kagi

An crystal-growth technique for single crystal x-ray structure analysis of high-pressure forms of hydrogen-bonded crystals is proposed. We used alcohol mixture (methanol: ethanol = 4:1 in volumetric ratio), which is a widely used pressure transmitting medium, inhibiting the nucleation and growth of unwanted crystals. In this paper, two kinds of single crystals which have not been obtained using a conventional experimental technique were obtained using this technique: ice VI at 1.99 GPa and MgCl<sub>2</sub>·7H<sub>2</sub>O at 2.50 GPa at room temperature. Here we first report the crystal structure of MgCl2·7H2O. This technique simultaneously meets the requirement of hydrostaticity for high-pressure experiments and has feasibility for further in-situ measurements.


2020 ◽  
Author(s):  
Satoshi Morooka ◽  
Nobuo Nakada ◽  
Yuhki Tsukada ◽  
Wu Gong ◽  
Takuro Kawasaki ◽  
...  

1995 ◽  
Vol 31 (7) ◽  
pp. 51-59 ◽  
Author(s):  
Ian Guymer ◽  
Rob O'Brien

Previously, the design of sewer systems has been limited to studies of their hydraulic characteristics, in particular the ability of the system to convey the maximum discharge. Greater environmental awareness has necessitated that new designs, and some existing schemes, are assessed to determine the environmental load which the scheme will deliver to any downstream component. This paper describes a laboratory programme which has been designed to elucidate the effects of manholes on the longitudinal dispersion of solutes. A laboratory system is described, which allows in situ measurements to be taken of the concentration of a fluorescent solute tracer, both up- and down-stream of a surcharged manhole junction. Results are presented from a preliminary series of studies undertaken for a single manhole geometry over a range of discharges, with varying levels of surcharge. Results are presented showing the variation of travel time, change in second moment of the distribution and of a dispersion factor with surcharge, assuming a Taylor approach and determining the dispersion factor using a ‘change in moment’ method. The effect of the stored volume within the manhole is clearly evident. The limitations and the applicability of this approach are discussed.


2013 ◽  
Vol 10 (4) ◽  
pp. 498-504 ◽  
Author(s):  
Lorena Martiniano ◽  
Joseany Almeida ◽  
Glene Cavalcante ◽  
Edmar Marques ◽  
Teresa Fonseca ◽  
...  

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