Interactions of cationic surfactant cetyl-trimethyl ammonium bromide with ammonium nitrate: Surface and thermodynamic studies

2021 ◽  
Vol 34 (4) ◽  
pp. 480-486
Author(s):  
Noor Rehman ◽  
Zia Ul Haq ◽  
Hidayat Ullah ◽  
Inamullah Mian ◽  
Xian Li
2014 ◽  
Vol 472 ◽  
pp. 861-866
Author(s):  
Cui Ping Mao ◽  
Shu Bin Wu

The kieselguhr was modified by the lignin-based cationic surfactant which obtained from the Mannich reaction. Modified organic kieselguhr exhibited favorable adsorption to adhesive and fine colloidal substance. Dissolved and colloidal substances (DCS) appeared in the secondary fibre reuse process interfered the pulping and papermaking seriously. The organic clay could remove the stickies substances through adsorption approach technically. In this paper, PVAc was chosen as the simulacrum of stickies because of its wide application as the adhesives in wood, textile, paint, paper processing and other industries. The organic kieselguhr was characterized by scanning electron microscope (SEM) and infrared spectrum (IR), etc. Then the adsorption experiment of PVAc emulsion from aqueous solution was carried out. 78.61% of the adhesive was absorbed by the organic kieselguhr, while the untreated clay only removed 53.41%. Common cationic surfactant, such as dodecyl trimethyl ammonium bromide (DTAB) and cetyl trimethyl ammonium bromide (CTAB), the modified clays were taken as the reference substance. The results indicated that the modified organic kieselguhr had well absorption efficacy to the stickies simulacrum, which provided a novel approach for the stickies controlling.


2011 ◽  
Vol 356-360 ◽  
pp. 190-194 ◽  
Author(s):  
Ai Lan Luo ◽  
Xian Jin Liu

Soil contamination with pesticide has caused critical environmental and health defects and increasing attention has been paid for developing innovative technology for cleaning up this contamination. In this study, the effects of cationic surfactant cetyl trimethyl ammonium bromide, anionic surfactant sodium dodecylbenzenesulfonate, and non-ionic Tween 80 on the adsorption of fluazinam at the concentration of 1/2 CMC, 1 × CMC and 2 × CMC in three soils were evaluated by using batch equilibrium experiment. The K values followed the order as: S1 > S2 > S3 in absence of surfactants. The use of a nonionic surfactant considerably weaken the fluazinam retention, while that of cationic surfactant has the reverse trend. The effects of anionic surfactant on the adsorption of fluazinam in soils is related to soil physicochemical properties and anionic surfactant concentration. These results are of practical interest in developing effective surfactant remediation technology for fluazinam contaminated soils.


Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1617
Author(s):  
Silviu-Adrian Predoi ◽  
Carmen Steluta Ciobanu ◽  
Mikael Motelica-Heino ◽  
Mariana Carmen Chifiriuc ◽  
Monica Luminita Badea ◽  
...  

In the present study, a new low-cost bioceramic nanocomposite based on porous hydroxyapatite (HAp) and cetyl trimethyl ammonium bromide (CTAB) as surfactant was successfully obtained by a simple chemical co-precipitation. The composition and structure of the HAp-CTAB were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), scanning electron microscope (SEM) equipped with an energy dispersive X-ray (EDX) spectrometer, and N2 adsorption/desorption analysis. The capacity of HAp-CTAB nanocomposites to remove the lead ions from aqueous solutions was studied by adsorption batch experiments and proved by Langmuir and Freundlich models. The Pb2+ removal efficiency of HAp-CTAB biocomposite was also confirmed by non-destructive ultrasound studies. The cytotoxicity assays showed that the HAp-CTAB nanocomposites did not induce any significant morphological changes of HeLa cells after 24 h of incubation or other toxic effects. Taken together, our results suggests that the obtained porous HAp-CTAB powder could be used for the decontamination of water polluted with heavy metals, such as Pb2+.


2011 ◽  
Vol 71-78 ◽  
pp. 122-125 ◽  
Author(s):  
Ling Li Song ◽  
Ren Yuan Zhang ◽  
Ling Bo Mao ◽  
Wen Jie Zhu ◽  
Miao Yan Zheng

The influences of dispersant type, supersonic time and concentration on the dispersion property of the nano-aluminium powders in glycol water were systematically studied by using Sodium dodecyl sulfate (SDS),cetyl trimethyl ammonium bromide (CTAB) and sodium hexa metah posphate(SHMP)as dispersants. During the first stage of the experiments, influences of dispersant type and ultrasonic time with these dispersants were evaluated. The next stage of the study was focused on SHMP concentration. The influence of SHMP concentration was assessed. The results show that with the increasing of ultrasonic time, the dispersion property of nano-aluminum powders first increases and then decreases, and SHMP is the best one. The excellent dispersing condition on the dispersion property of nano-aluminium is: 5g/L SHMP and 50 min ultrasonic vibration.


Author(s):  
Saurabh Singh ◽  
Bimlesh Kumar ◽  
Narendra Kumar Pandey ◽  
Barinder Kaur ◽  
Arun Kumar ◽  
...  

Objective: The present study highlights the development of a method to synthesize copper nanoparticles (CuNPs).Methods: CuNPs were developed using 0.01 M copper penta sulfate and 0.11 M of ascorbic acid (AA) and 0.03 M of cetyl trimethyl ammonium bromide solution. The synthesized CuNPs were differentiated through filtration and washed by water (deionized). CuNPs were kept in dialysis bag 70 KD in a 250 mL glass beaker along with distilled water. The assembly was kept on a magnetic stirrer for 24 h at 500 rpm. Then, the dialysis bag containing CuNPs solution was filtered by a filter assembly with 0.2 μm nylon filter. The filtered CuNPs were spray dried with the help of spray drier.Results: The prepared CuNPs were found to be 440 nm with zeta potential of −10 mV and polydispersity index 0.314.Conclusion: The investigation deciphers the promising and material technique to synthesis of CuNPs by methods for synthetic reduction utilizing strategy using AA (0.2 M) and sodium hydroxide (1 M), and Syloid 244FP.


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