A halogen budget of the bulk silicate Earth points to a history of early halogen degassing followed by net regassing

2021 ◽  
Vol 118 (51) ◽  
pp. e2116083118
Author(s):  
Meng Guo ◽  
Jun Korenaga

Halogens are important tracers of various planetary formation and evolution processes, and an accurate understanding of their abundances in the Earth’s silicate reservoirs can help us reconstruct the history of interactions among mantle, atmosphere, and oceans. The previous studies of halogen abundances in the bulk silicate Earth (BSE) are based on the assumption of constant ratios of element abundances, which is shown to result in a gross underestimation of the BSE halogen budget. Here we present a more robust approach using a log-log linear model. Using this method, we provide an internally consistent estimate of halogen abundances in the depleted mid-ocean ridge basalts (MORB)-source mantle, the enriched ocean island basalts (OIB)-source mantle, the depleted mantle, and BSE. Unlike previous studies, our results suggest that halogens in BSE are not more depleted compared to elements with similar volatility, thereby indicating sufficient halogen retention during planetary accretion. According to halogen abundances in the depleted mantle and BSE, we estimate that ∼87% of all stable halogens reside in the present-day mantle. Given our understanding of the history of mantle degassing and the evolution of crustal recycling, the revised halogen budget suggests that deep halogen cycle is characterized by efficient degassing in the early Earth and subsequent net regassing in the rest of Earth history. Such an evolution of deep halogen cycle presents a major step toward a more comprehensive understanding of ancient ocean alkalinity, which affects carbon partitioning within the hydrosphere, the stability of crustal and authigenic minerals, and the development of early life.

1999 ◽  
Vol 36 (6) ◽  
pp. 999-1019 ◽  
Author(s):  
Jean H Bédard ◽  
Ross Stevenson

The Caldwell Group belongs to the Internal Nappe Domain of the Humber Zone and consists of basaltic lavas, quartzo-feldspathic sandstones, and mudslates. The lavas are clinopyroxene ± plagioclase ± olivine-phyric tholeiites, and are typically altered to epidote-, chlorite-, carbonate-, and (or) hematite-rich secondary assemblages. In most cases, the high field strength elements do not appear to have been perturbed by the alteration, and preserve magmatic signatures. Most Caldwell basalts exhibit coupled major and trace element variations compatible with low- to medium-pressure ([Formula: see text] 10 kbar, where 1 kbar = 100 MPa) fractional crystallization. Paleotectonic discriminants imply an ocean-floor or normal mid-ocean ridge basalt (N-MORB) affinity. Most basalts have flat N-MORB-normalized profiles, except for the highly incompatible elements (Ba, Th, Nb), which show slight relative enrichment. Melting models suggest that most of these lavas formed by about 20% melting from a mantle slightly less depleted than fertile MORB mantle (FMM). Subpopulations of Caldwell lavas (types 1b and 1a) are characterized by slightly higher incompatible element abundances, with similarly shaped N-MORB-normalized profiles, and can be modeled by slightly smaller degrees of melting (6-15%) of a similar source mantle. The Caldwell basalts erupted in the final stages of Iapetus rifting, when the predominant mantle source involved in melting was the depleted asthenosphere. Isotopic data preclude significant crustal contamination, yet the basalts are associated with sandstones, implying that a mature continental crust was present nearby. Nd isotopic data on the sandstones suggest erosion of an ancient Archean-Proterozoic composite terrane.


Author(s):  
David D. Nolte

This chapter presents the history of the development of the concept of phase space. Phase space is the central visualization tool used today to study complex systems. The chapter describes the origins of phase space with the work of Joseph Liouville and Carl Jacobi that was later refined by Ludwig Boltzmann and Rudolf Clausius in their attempts to define and explain the subtle concept of entropy. The turning point in the history of phase space was when Henri Poincaré used phase space to solve the three-body problem, uncovering chaotic behavior in his quest to answer questions on the stability of the solar system. Phase space was established as the central paradigm of statistical mechanics by JW Gibbs and Paul Ehrenfest.


Author(s):  
Stefan G. Chrissanthos

This chapter offers a brief history of military discipline in ancient armies, and also investigates how and to what degree societies inflicted discipline on their soldiers, and how, in various ways, soldiers imposed discipline on themselves. Then, it addresses the evolution of military discipline from Greece until eventually something similar to a modern system developed in the early Roman Empire. The death of Alexander had precipitated almost fifty years of continuous warfare that ultimately resulted in the development of the Hellenistic monarchies. The Roman army represented something completely new in ancient Mediterranean warfare. It is observed that the Principate represented a major step in the evolution of ancient military discipline.


2007 ◽  
Vol 1039 ◽  
Author(s):  
Philippe Bergonzo ◽  
Hassen Hamrita ◽  
Dominique Tromson ◽  
Caroline Descamps ◽  
Christine Mer ◽  
...  

AbstractCVD diamond combines attractive properties for the fabrication of detection devices operating in specific environments. One problem that remains critical for device stability is the presence of defect levels that alter the detection performances, and the detection characteristics often appear as they are very depending on time, temperature, and history of the preceding irradiations.One issue we have proposed is to adapt one technique that is commonly used for time of flight spectroscopy in order to maintain a uniform electric field in the probed device, and based on the synchronisation of the device bias with the period of the excitation source. This can be applied to several types of detection applications, as long as we can rely on periodical triggering in order to synchronise the device polarisation. We apply it here to a LINAC electron accelerator used for photon pulse generation at the frequency of 25Hz. The result is a remarkable improvement of the performance of a polycrystalline diamond detector that exhibits a particularly defective response when used in the steady state excitation, to reach that of a perfectly stable and reproducible device response in the pulsed mode. We claim this method to be applicable to several types of excitations and particularly to present a high interest for monitoring accelerator sources, e.g. for medical dosimetry applications.


Minerals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 25
Author(s):  
Shuang-Shuang Chen ◽  
Tong Hou ◽  
Jia-Qi Liu ◽  
Zhao-Chong Zhang

Shikoku Basin is unique as being located within a trench-ridge-trench triple junction. Here, we report mineral compositions, major, trace-element, and Sr-Nd-Pb isotopic compositions of bulk-rocks from Sites C0012 (>18.9 Ma) and 1173 (13–15 Ma) of the Shikoku Basin. Samples from Sites C0012 and 1173 are tholeiitic in composition and display relative depletion in light rare earth elements (REEs) and enrichment in heavy REEs, generally similar to normal mid-ocean ridge basalts (N-MORB). Specifically, Site C0012 samples display more pronounced positive anomalies in Rb, Ba, K, Pb and Sr, and negative anomalies in Th, U, Nb, and Ta, as well as negative Nb relative to La and Th. Site 1173 basalts have relatively uniform Sr-Nd-Pb isotopic compositions, close to the end member of depleted mantle, while Site C0012 samples show slightly enriched Sr-Nd-Pb isotopic signature, indicating a possible involvement of enriched mantle 1 (EM1) and EM2 sources, which could be attributed to the metasomatism of the fluids released from the dehydrated subduction slab, but with the little involvement of subducted slab-derived sedimentary component. Additionally, the Shikoku Basin record the formation of the back-arc basin was a mantle conversion process from an island arc to a typical MORB. The formation of the Shikoku Basin is different from that of the adjacent Japan Sea and Parece Vela Basin, mainly in terms of the metasomatized subduction-related components, the nature of mantle source, and partial melting processes.


1992 ◽  
Vol 6 ◽  
pp. 16-16 ◽  
Author(s):  
Richard K. Bambach ◽  
J. John Sepkoski

The first two ranks above the species level in the traditional Linnean hierarchy — the genus and family — are species based: genera have been erected to unify groups of morphologically similar, closely related species and families have been erected to group genera recognized as closely related because of the shared morphologic characteristics of their species. Diversity patterns of traditional genera and families thus appear congruent with those of species in (a) the Recent (e. g., latitudinal gradients in many groups), (b) compilations of all marine taxa for the entire Phanerozoic (including the stage level), (c) comparisons through time within individual taxa (e. g., Foraminifera, Rugosa, Conodonta), and (d) simulation studies. Genera and families often have a more robust fossil record of diversity than species, especially for poorly sampled groups (e. g., echinoids), because of the range-through record of these polytypic taxa. Simulation studies indicate that paraphyly among traditionally defined taxa is not a fatal problem for diversity studies; in fact, when degradation of the quality of the fossil record is modelled, both diversity and rates of origination and extinction are better represented by including paraphyletic taxa than by restricting data to monophyletic clades. This result underscores the utility of traditional rank-based analyses of the history of diversity.In contrast, the three higher ranks of the Linnean hierarchy — orders, classes and phyla — are defined and recognized by key character complexes assumed to be rooted deep in the developmental program and, therefore, considered to be of special significance. These taxa are unified on the basis of body plan and function, not species morphology. Even if paraphyletic, recognition of such taxa is useful because they represent different functional complexes that reflect biological organization and major evolutionary innovations, often with different ecological capacities. Phanerozoic diversity patterns of orders, classes and phyla are not congruent with those of lower taxa; the higher groups each increased rapidly in the early Paleozoic, during the explosive diversification of body plans in the Cambrian, and then remained stable or declined slightly after the Ordovician. The diversity history of orders superficially resembles that of lower taxa, but this is a result only of ordinal turnover among the Echinodermata coupled with ordinal radiation in the Chordata; it is not a highly damped signal derived from the diversity of species, genera, or families. Despite the stability of numbers among post-Ordovician Linnean higher taxa, the diversity of lower taxa within many of these Bauplan groups fluctuated widely, and these diversity patterns signal embedded ecologic information, such as differences in flexibility in filling or utilizing ecospace.Phylogenetic analysis is vital for understanding the origins and genealogical structure of higher taxa. Only in such fashion can convergence and its implications for ecological constraints and/or opportunities be understood. But blind insistence on the use of monophyletic classifications in all studies would obscure some of the important information contained in traditional taxonomic groupings. The developmental modifications that characterize Linnean higher taxa (and traditionally separate them from their paraphyletic ancestral taxa) provide keys to understanding the role of shifting ecology in macroevolutionary success.


2007 ◽  
Vol 41 (4) ◽  
pp. 6-8 ◽  
Author(s):  
Gerald Kooyman

The history of animal-borne instrumentation is reviewed from the first basic depth gauge invented in the late 1800s, to the complex animal-borne imagery and archival systems of the present day. A major breakthrough occurred in 1964 when the first time-depth recorder was deployed on a Weddell Seal in McMurdo Sound, Antarctica. The next phase in the study of animals at sea was the use of microprocessors as archival recorders in the mid-1980s. These also were first attached to Weddell seals in McMurdo Sound. Microprocessor technology made possible the next major step of attaching a video camera housed in a submersible case (Crittercam) to a loggerhead turtle. Since the 1990s the field of “Biologging” has flourished, with new additions of satellite and GPS tracking, and resulted in three major international symposiums in the past four years (2003-2007).


1999 ◽  
Vol 12 (1) ◽  
pp. 112-125 ◽  
Author(s):  
Geoff Hide

SUMMARY The history of human sleeping sickness in East Africa is characterized by the appearance of disease epidemics interspersed by long periods of endemicity. Despite the presence of the tsetse fly in large areas of East Africa, these epidemics tend to occur multiply in specific regions or foci rather than spreading over vast areas. Many theories have been proposed to explain this phenomenon, but recent molecular approaches and detailed analyses of epidemics have highlighted the stability of human-infective trypanosome strains within these foci. The new molecular data, taken alongside the history and biology of human sleeping sickness, are beginning to highlight the important factors involved in the generation of epidemics. Specific, human-infective trypanosome strains may be associated with each focus, which, in the presence of the right conditions, can be responsible for the generation of an epidemic. Changes in agricultural practice, favoring the presence of tsetse flies, and the important contribution of domestic animals as a reservoir for the parasite are key factors in the maintenance of such epidemics. This review examines the contribution of molecular and genetic data to our understanding of the epidemiology and history of human sleeping sickness in East Africa.


2019 ◽  
Vol 9 ◽  
pp. 59-64
Author(s):  
Ramesh Agrawal ◽  
Dolly P. Patel ◽  
Bhagyashree B. Desai

The current paper depicts the challenges faced during the treatment of a complicated case of mandibular condylar head fracture, facial asymmetry, and centric relation-centric occlusion (CR-CO) discrepancy along with Class III malocclusion. A 20-year-old female reported with the chief complaint of difficulty in chewing and concern with her appearance due to deviated jaw and had a history of trauma over chin region. The clinical and radiographic examination revealed significant facial asymmetry with long face, right-sided deviation of the mandible, fractured condyle, CR-CO discrepancy, cross- bite with Class III malocclusion, and a missing mandibular single incisor along with non-vital 21 and 22. She was treated with 0.022 MBT appliance along with guiding plane for CR-CO correction followed by asymmetric bilateral sagittal split osteotomy and differential set back on the right and left sides and finally rigid fixation. A good facial profile and functional occlusion were achieved and non-vital 21 and 22 were esthetically rehabilitated with PFM crowns. The stability of surgical as well as orthodontic corrections was excellent and appreciable in the records obtained 2-year post-treatment. When faced with mutilated malocclusion, with multiple problems, sequential correction of functional malocclusion with dental decompensation followed by skeletal correction with surgical approach has yielded a appreciable facial correction with good stability showing 2-year post-treatment follow-up.


Diachronica ◽  
2018 ◽  
Vol 35 (3) ◽  
pp. 338-366 ◽  
Author(s):  
Hanne Martine Eckhoff

Abstract This paper illustrates how enriched diachronic treebank data can shed new light on an old and vexed topic, even when that topic is primarily morphological and semantic in nature rather than syntactic. The topic is the rise of the Russian po delimitatives, a change seen as crucial in most accounts of the history of Russian aspect, since it represents a major step in generalising the derivational aspect system. Earlier accounts concur that the po delimitatives spread fairly recently, too recently for the development to be connected to the loss of the aorist tense, which also had delimitative readings with atelic verbs. Using treebank data from the Tromsø Old Russian and Old Church Slavonic Treebank, enriched with tags for derivational morphology and semantics, I show that the po delimitatives were not marginal even in the earliest Slavic sources, either in terms of frequency or semantics, and that they first complemented and then competed with the delimitative aorists. It can thus be claimed that the exotic po delimitatives grew organically out of the old Indo-European inflectional aspect system.


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