The effect of organosilane on corrosion resistance of epoxy coating containing cerium nitrate

2013 ◽  
Vol 28 (2) ◽  
pp. 151-160 ◽  
Author(s):  
Sadeq Hooshmand Zaferani ◽  
Davood Zaarei ◽  
Iman Danaee ◽  
Nazgol Mehrabian
2021 ◽  
pp. 51640
Author(s):  
Siti Maznah Kabeb ◽  
Azman Hassan ◽  
Faiz Ahmad ◽  
Zurina Mohamad ◽  
Zalilah Sharer ◽  
...  

Coatings ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 844 ◽  
Author(s):  
Xuepei Miao ◽  
An Xing ◽  
Lifan He ◽  
Yan Meng ◽  
Xiaoyu Li

In this paper, hyperbranched polyether functionalized graphene oxide (EHBPE-GO) was prepared by a facile one-step method. Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), thermogravimetric analyzer (TGA), and trans-mission electron microscopy (TEM) results confirmed the formation of EHBPE-GO. Then, EHBPE-GO was cured with phenolic amides at room temperature to prepare epoxy coatings. The corrosion resistance of epoxy coatings was investigated systematically by using electrochemical and traditional immersion methods. Results show that a small amount of EHBPE-GO (8 wt % of Diglycidyl ether of bisphenol A (DGEBA)) in epoxy coating achieves 50% higher improvement in acid-resistance than unmodified neat DGEBA resin. For the nanocomposite epoxy coating, the superior acid-resistance is attributed to the increased crosslink density and the impermeable 2D structure of EHBPE-GO. This work provides a facile strategy to develop the effective improved corrosion resistance nanofiller for epoxy coating.


2019 ◽  
Vol 66 (2) ◽  
pp. 188-194
Author(s):  
Yingjun Zhang ◽  
Xue-Jun Cui ◽  
Yawei Shao ◽  
Yanqiu Wang ◽  
Guozhe Meng ◽  
...  

PurposeThis paper aims to prepare a residual rust epoxy coating by adding different quantities of phytic acid (PA) on the surface of the rusty steel and investigate the corrosion protection of PA and its action mechanisms.Design/methodology/approachA residual rust epoxy coating by adding different quantities of PA was prepared on the surface of the rusty steel. The influence of PA on the corrosion resistance of epoxy-coated rusty steel was investigated by means of electrochemical impedance spectroscopy and adhesion testing.FindingsResults indicated that PA can substantially improve the corrosion resistance of epoxy-coated rusty steel. This improvement is due to the reaction of PA with residual rust and generation of new compounds with protection properties and increased adhesive strength effects on the coating/metal interface. The coating showed better protection performance when 2 per cent PA was added.Originality/valueConsidering the structure of the active groups, PA has strong chelating capability with many metal ions and can form stable complex compounds on the surface of a metal substrate, thereby improving corrosion resistance. In recent years, PA has been reported to be useful in the conversion of coatings or as green corrosion inhibitor. To the best of the authors’ knowledge, few studies have reported the use of PA as a rust converter or residual rust coating. The present work aims to improve the corrosion resistance of residual rust epoxy coating by adding PA.


Coatings ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 118 ◽  
Author(s):  
Alam ◽  
Samad ◽  
Sherif ◽  
Poulose ◽  
Mohammed ◽  
...  

Epoxy coating formulations containing 1%, 3%, and 5% SiO2 nanoparticles were produced and applied on a mild steel substrate to achieve the objective of high performance corrosion resistance. The electrochemical impedance spectroscopy (EIS) technique was employed to measure the anticorrosive properties of coatings. The corrosion tests were performed by exposing the coated samples in a solution of 3.5% NaCl for different periods of time, varied from 1 h and up to 30 days. Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) analyses revealed the presence of nanoparticles in the final cured samples. Establishing the incorporation of the nanoparticles in the coating formulations was confirmed by employing both of XRD and FT-IR techniques. The FT-IR spectra have proved to be satisfactory indicating that there was a complete reaction between the epoxy resin with the hardener. EIS measurements confirmed that the presence and the increase of SiO2 nanoparticles greatly improved the corrosion resistance of the epoxy coating. The highest corrosion resistance for the coatings was obtained for the formulation with 5% SiO2 nanoparticles content, particularly with prolonging the immersion time to 30 days.


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