Analysis of chemical forms of heavy metals in contaminated soil by sequential extraction methods

2013 ◽  
Vol 16 (4) ◽  
pp. 305-308 ◽  
Author(s):  
Oh-Hyeok Kwon ◽  
Kyungbae Jung ◽  
Kyoungkeun Yoo ◽  
Jay Hyun Park ◽  
Ui Kyu Choi
Keyword(s):  
Heavy Metals ◽  
Sequential Extraction ◽  
Contaminated Soil ◽  
Extraction Methods ◽  
Chemical Forms

scholarly journals The Determination of Chemical Forms of Heavy Metals in Shooting Area Contaminated Soil Using Sequential Extraction Method

2015 ◽  
Vol 20 (6) ◽  
pp. 111-116 ◽  
Author(s):  
Gyeonghye Moon ◽  
Hongki Park ◽  
Kyoungkeun Yoo ◽  
Jha Manis Kumar ◽  
Alorro Richad Diaz ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Sequential Extraction ◽  
Contaminated Soil ◽  
Extraction Method ◽  
Chemical Forms ◽  
Sequential Extraction Method

Effect of Soil pH on Immobilization of Lead by Phosphate-Solubilizing Bacteria

2014 ◽  
Vol 955-959 ◽  
pp. 3595-3599
Author(s):  
Li Ping Dong ◽  
Xiao Li Zhu ◽  
Ya Ya Xu ◽  
Jian Xia Zhang ◽  
Jiao Qin Liu ◽  
...  
Keyword(s):  
Sequential Extraction ◽  
Soil Ph ◽  
Contaminated Soil ◽  
Extraction Methods ◽  
Phosphate Solubilizing Bacteria ◽  
Chemical Forms ◽  
Selective Sequential Extraction ◽  
Remediation Efficiency ◽  
Phosphate Solubilizing ◽  
Pb Immobilization

Two phosphate-solubilizing bacteria were used to immobilize the lead in contaminated soil using the selective sequential extraction methods to detect the chemical forms of lead. The results showed that PSB 3-5-1-1 had higher ability of Pb immobilization compared with ID-a .The beat remediation efficiency could be obtained when pH is 6.

Influence of Decreasing Supplementation to Transformation of Chemical Forms of Ni, Zn and Cu During Composting of Sewage Sludge

2021 ◽  
Vol 23 ◽  
pp. 580-593
Author(s):  
Robert Sidełko
Keyword(s):  
Heavy Metals ◽  
Sewage Sludge ◽  
Organic Carbon ◽  
Ion Exchange ◽  
Beneficial Effect ◽  
Sequential Extraction ◽  
Nitrogen Concentration ◽  
Chemical Forms ◽  
N Value ◽  
Mobile Forms

This paper pertains to the influence of decreasing supplementation to transformation of chemical forms of Ni. Zn and Cu during composting of sewage sludge. A universally used supplementing material constituting a rich source of organic carbon is straw. Addition of straw to sewage sludge is aimed at increasing C/N proportion up to at least 15 due to the risk of formation of toxic forms of nitrogen, concentration of which in sewage sludge is exceptionally high. We have presented in this paper the results of speciation research of three elements applying Tessier’s sequential extraction. It’s been proven that decreasing of straw share in the composted mixture with sewage sludge down to the level of C/N value below the admissible value, has a beneficial effect on the allocation of tested heavy metals towards the forms that are permanently bound in compost matrix. A systematic increase of organic (IV) and residual (V) fractions share and decrease of mobile forms of heavy metals content in bioavailable fractions i.e. ion-exchange (I) and carbonate (II) has been ascertained.

scholarly journals Evaluation of Acid Leaching on the Removal of Heavy Metals and Soil Fertility in Contaminated Soil

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Chen-Yao Chu ◽  
Tzu-Hsing Ko
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Seed Germination ◽  
Soil Fertility ◽  
Sequential Extraction ◽  
Contaminated Soil ◽  
Contaminated Soils ◽  
Germination Rate ◽  
Extraction Procedure ◽  
Acid Leaching

Heavy metal-contaminated soils were leached with various acid reagents, and a series of treatments was assessed to understand soil fertility after acid leaching. Aqua regia digestion and a five-step sequential extraction procedure were applied to determine heavy metal distribution. The average total concentrations of Zn, Cd, Cu, and Pb for contaminated soil were 1334, 25, 263, and 525 mg·kg−1 based on the ICP/AES quantitative analysis. Other than Pb extracted by H2SO4, over 50% removal efficiency of other heavy metals was achieved. A five-step sequential extraction revealed that the bound-to-carbonate and bound-to-Fe-Mn oxides were the major forms of the heavy metals in the soil. The addition of organic manure considerably promoted soil fertility and increased soil pH after acid leaching. Seed germination experiments demonstrated that after acid leaching, the soil distinctly inhibited plant growth and the addition of manure enhanced seed germination rate from 35% to 84%. Furthermore, the procedure of soil turnover after acid leaching and manure addition greatly increased seed germination rate by 61% and shortened the initial germination time. Seed germination in untreated soil was superior to that in acid-leached soil, illustrating that the phytotoxic effect of acid leaching is more serious than that of heavy metals.

Toxicity Assessment of some Crude Oil Contaminated Soils in the Niger Delta

2009 ◽  
Vol 62-64 ◽  
pp. 451-455 ◽  
Author(s):  
F.A. Aisien ◽  
J.C. Chiadikobi ◽  
E.T. Aisien
Keyword(s):  
Heavy Metals ◽  
Moisture Content ◽  
Crude Oil ◽  
Contaminated Soil ◽  
Contaminated Soils ◽  
Niger Delta ◽  
Extraction Methods ◽  
Toxicity Assessment ◽  
Soil Samples ◽  
Physiochemical Parameters

This paper considered the toxicity assessment of some crude oil contaminated soils in Niger Delta areas. The soil samples were collected from different horizontal distances, vertical depths and contaminated soil of different ages. The heavy metals in the contaminated soils were digested and extracted using di-acid digested and DTPA extraction methods respectively. The physiochemical parameters (moisture content, pH, N, P and heavy metals (Ni, Pb and Cd) were analysed with APHA method. The heavy metals concentration was determined using atomic absorption spectrophotometer (AAS). The results show that the metals concentration decreased with the age of the contaminated soil and with increased vertical depths. However, the metals concentrations were almost constant at different horizontal distances. Similar trend was observed for the moisture content, pH, N, P and K.

scholarly journals Especiación de metales en sedimentos del río Cuchivero, Venezuela

2016 ◽  
Author(s):  
Arístide Márquez ◽  
Gregorio Martínez ◽  
Julio Figuera ◽  
William James Senior ◽  
Antonio Benítez ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Sequential Extraction ◽  
Environmental Risk ◽  
Total Concentration ◽  
Pollution Indices ◽  
Chemical Forms ◽  
Absorption Spectrophotometry ◽  
Del Rio

The total concentration and the chemical forms of heavy metals were determined insuperficial sediments of the Cuchivero river, Venezuela, using sequential extraction andatomic absorption spectrophotometry with flame. Pollution indices were used to study thedistribution, pollution and environmental risk in the sediments. Total values ranged from,394-457 mgkg-1 Fe, 46,87-74,82 Mn, 6,45-11,92 Zn, 1,70-5,75 Ni, 0,39-3,7 Cu, 1,25-3,63Cr, 0,37-1,82 Co, 0,10-0,30 Cd y

scholarly journals Determination of forms of heavy metals in bottom ash from households using sequential extraction

2018 ◽  
Vol 44 ◽  
pp. 00116 ◽  
Author(s):  
Kamila Mizerna
Keyword(s):  
Heavy Metals ◽  
Sequential Extraction ◽  
Water Environment ◽  
Bottom Ash ◽  
Total Content ◽  
Solid Material ◽  
Speciation Analysis ◽  
Extraction Methods ◽  
Residual Fraction ◽  
Sequential Extraction Method

The paper presents the results of heavy metals mobility obtained by sequential extraction method and leaching test. Heavy metals in solid waste material occur in different forms and phases that differ in terms of the toxicity, mobility and bioavailability. The sequential extraction analysis is widely used in order to predict the behaviour of heavy metals in a solid material. The sequential extraction methods involve a gradual separation of metals in various forms by means of specific extractants. The material used in the research applied bottom ash derived from households. The results of heavy metals concentrations (Cd, Pb, Ni, Cr, Cu, Zn) in extractable forms and total content in waste were presented. The five forms of heavy metals were determined. The concentrations of heavy metals were analyzed by FAAS. The lowest concentrations of analyzed heavy metals were determined in the exchangeable form. The author observed that the particular elements occurred mainly in forms: zinc and cadmium associated with carbonates, lead and copper in the organic and residual form, chromium and nickel in the residual form. Heavy metals in the residual fraction do not pose a possible environment hazard. The application of speciation analysis of heavy metals in bottom ash provide the means to assess the content of dissoluble forms of metals in water relative to their total content. This information is useful in assessing the migration capabilities of heavy metal ions from waste to the ground-water environment. The potential for the reuse of bottom ash was also discussed in the paper.

Prediction of Heavy Metals Mobility and Bioavailability in Contaminated Soil Using Sequential Extraction and Biosensors

2009 ◽  
Vol 135 (9) ◽  
pp. 839-844 ◽  
Author(s):  
May-Lin Almendras ◽  
Marta Carballa ◽  
Ludo Diels ◽  
Karolien Vanbroekhoven ◽  
Rolando Chamy
Keyword(s):  
Heavy Metals ◽  
Sequential Extraction ◽  
Contaminated Soil

Study of Heavy Metal Speciation in Surface Sediments of Lugu Lake, China

2013 ◽  
Vol 448-453 ◽  
pp. 293-298
Author(s):  
Zheng Gang Gu ◽  
Min Wu ◽  
Ping Ning
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Heavy Metal ◽  
Sequential Extraction ◽  
Surface Sediment ◽  
Extraction Methods ◽  
Metal Mobility ◽  
Risk Assessment Code ◽  
Bcr Sequential Extraction ◽  
Lugu Lake

The speciation of the heavy metals Cu, Cr, and Pb in surface sediment samples collected from Lugu Lake in China was analyzed by European Community Bureau of Reference (BCR) sequential extraction methods. Heavy metal bioavailability was assessed by risk assessment code. This study demonstrates that BCR sequential extraction methods and risk assessment code can be used as valuable tools to assess heavy metal mobility, bioavailability and eco-toxicity. The distribution of Cu, Cr, and Pb in the surface sediment of Lugu Lake showed that all three metals were mainly present in the reducible fraction. The bioavailability of the heavy metals in the surface sediment was in the order Cu > Cr > Pb.

Sign in / Sign up

Export Citation Format

Share Document