Universality of mesoporous coal gasification slag for reinforcement and deodorization in four common polymers

2021 ◽  
Author(s):  
Jiupeng Zhang ◽  
Jing Zuo ◽  
Yang Liu ◽  
Junyu Zhang ◽  
Wenjing Fu ◽  
...  

Abstract Mesoporous adsorbents and polymer deodorants are difficult to implement on a large scale because of their complicated preparation methods. Herein, a mesoporous adsorbent (CGSA) with a specific surface area of 564 m2 g−1 and a pore volume of 0.807 cm3 g−1 was prepared from solid waste coal gasification slag (CGS) using a simple acid leaching process. The adsorption thermodynamics and adsorption kinetics results verified that the adsorption mechanism of propane on CGSA was mainly physisorption. Then the universality of CGSA in different polymers was investigated by introducing CGSA and its commercialized counterparts (CaCO3, and zeolite) into four common polymers. When the filler content was 30 wt%, the average reinforcement effect of CGSA on the tensile, flexural, and impact strengths of the four polymers was 46.68, 83.62, and 211.90% higher than that of CaCO3, respectively. Gas chromatography results also showed that CGSA significantly decreased total volatile organic compound (VOCs) emissions from the composites, and its optimal deodorization performance reached 69.58, 81.33, and 91.09% for different polymers, respectively, far exceeding that of zeolite. Therefore, this study showed that low-cost, high-performance, and multifunctional mesoporous polymer fillers with excellent universality can be manufactured from solid contaminants.

2019 ◽  
Vol 16 (3) ◽  
pp. 117-123
Author(s):  
Tsung-Ching Huang ◽  
Ting Lei ◽  
Leilai Shao ◽  
Sridhar Sivapurapu ◽  
Madhavan Swaminathan ◽  
...  

Abstract High-performance low-cost flexible hybrid electronics (FHE) are desirable for applications such as internet of things and wearable electronics. Carbon nanotube (CNT) thin-film transistor (TFT) is a promising candidate for high-performance FHE because of its high carrier mobility, superior mechanical flexibility, and material compatibility with low-cost printing and solution processes. Flexible sensors and peripheral CNT-TFT circuits, such as decoders, drivers, and sense amplifiers, can be printed and hybrid-integrated with thinned (<50 μm) silicon chips on soft, thin, and flexible substrates for a wide range of applications, from flexible displays to wearable medical devices. Here, we report (1) a process design kit (PDK) to enable FHE design automation for large-scale FHE circuits and (2) solution process-proven intellectual property blocks for TFT circuits design, including Pseudo-Complementary Metal-Oxide-Semiconductor (Pseudo-CMOS) flexible digital logic and analog amplifiers. The FHE-PDK is fully compatible with popular silicon design tools for design and simulation of hybrid-integrated flexible circuits.


2016 ◽  
Vol 36 (4) ◽  
pp. 329-362 ◽  
Author(s):  
Nurul F. Himma ◽  
Sofiatun Anisah ◽  
Nicholaus Prasetya ◽  
I Gede Wenten

Abstract Polypropylene (PP) is one of the most used polymers for microporous membrane fabrication due to its good thermal stability, chemical resistance, mechanical strength, and low cost. There have been numerous studies reporting the developments and applications of PP membranes. However, PP membrane with high performance is still a challenge. Thus, this article presents a comprehensive overview of the advances in the preparation, modification and application of PP membrane. The preparation methods of PP membrane are firstly reviewed, followed by the modification approaches of PP membrane. The modifications includes hydrophilic and superhydrophobic modification so that the PP membranes become more suitable to be applied either in aqueous applications or in non-aqueous ones. The fouling resistant of hydrophilized PP membrane and the wetting resistant of superhydrophobized PP membrane are then reviewed. Finally, special attention is given to the various potential applications and industrial outlook of the PP membranes.


Author(s):  
Guixiang Wang ◽  
Haitao Zou ◽  
Xiaobo Zhu ◽  
Mei Ding ◽  
Chuankun Jia

Abstract Zinc-based redox flow batteries (ZRFBs) have been considered as ones of the most promising large-scale energy storage technologies owing to their low cost, high safety, and environmental friendliness. However, their commercial application is still hindered by a few key problems. First, the hydrogen evolution and zinc dendrite formation cause poor cycling life, of which needs to ameliorated or overcome by finding suitable anolytes. Second, the stability and energy density of catholytes are unsatisfactory due to oxidation, corrosion, and low electrolyte concentration. Meanwhile, highly catalytic electrode materials remain to be explored and the ion selectivity and cost efficiency of membrane materials demands further improvement. In this review, we summarize different types of ZRFBs according to their electrolyte environments including ZRFBs using neutral, acidic, and alkaline electrolytes, then highlight the advances of key materials including electrode and membrane materials for ZRFBs, and finally discuss the challenges and perspectives for the future development of high-performance ZRFBs.


NANO ◽  
2020 ◽  
Vol 15 (05) ◽  
pp. 2050062
Author(s):  
Zhaolei Meng ◽  
Xiaojian He ◽  
Song Han ◽  
Zijian Hu

Carbon materials are generally employed as supercapacitor electrodes due to their low- cost, high-chemical stability and environmental friendliness. However, the design of carbon structures with large surface area and controllable porous structure remains a daunt challenge. In this work, a three-dimensional (3D) hybrid aerogel with different contents of MoS2 nanosheets in 3D graphene aerogel (MoS2-GA) was synthesized through a facial hydrothermal process. The influences of MoS2 content on microstructure and subsequently on electrochemical properties of MoS2-GA are systematically investigated and an optimized mass ratio with MoS2: GA of 1:2 is chosen to achieve high mechanical robustness and outstanding electrochemical performance in the hybrid structure. Due to the large specific surface area, porous structure and continuous charge transfer network, such MoS2-GA electrodes exhibit high specific capacitance, good rate capability and excellent cyclic stability, showing great potential in large-scale and low-cost fabrication of high-performance supercapacitors.


2018 ◽  
Vol 217 ◽  
pp. 291-299 ◽  
Author(s):  
Yingyuan Zhao ◽  
Nian Jiang ◽  
Xu Zhang ◽  
Jing Guo ◽  
Yanqiang Li ◽  
...  

Molecules ◽  
2020 ◽  
Vol 25 (23) ◽  
pp. 5558
Author(s):  
Dimitra Vernardou ◽  
Charalampos Drosos ◽  
Andreas Kafizas ◽  
Martyn E. Pemble ◽  
Emmanouel Koudoumas

The need for clean and efficient energy storage has become the center of attention due to the eminent global energy crisis and growing ecological concerns. A key component in this effort is the ultra-high performance battery, which will play a major role in the energy industry. To meet the demands in portable electronic devices, electric vehicles, and large-scale energy storage systems, it is necessary to prepare advanced batteries with high safety, fast charge ratios, and discharge capabilities at a low cost. Cathode materials play a significant role in determining the performance of batteries. Among the possible electrode materials is vanadium pentoxide, which will be discussed in this review, due to its low cost and high theoretical capacity. Additionally, aqueous electrolytes, which are environmentally safe, provide an alternative approach compared to organic media for safe, cost-effective, and scalable energy storage. In this review, we will reveal the industrial potential of competitive methods to grow cathodes with excellent stability and enhanced electrochemical performance in aqueous media and lay the foundation for the large-scale production of electrode materials.


2020 ◽  
Vol 100 ◽  
pp. 106084
Author(s):  
Jinyi Zhang ◽  
Jing Zuo ◽  
Yinshan Jiang ◽  
Dandan Zhu ◽  
Jiupeng Zhang ◽  
...  

Nanoscale ◽  
2013 ◽  
Vol 5 (13) ◽  
pp. 6173 ◽  
Author(s):  
Irene Emmanuelawati ◽  
Jie Yang ◽  
Jun Zhang ◽  
Hongwei Zhang ◽  
Liang Zhou ◽  
...  

2014 ◽  
Vol 602-603 ◽  
pp. 151-154 ◽  
Author(s):  
Chuan Shan Li ◽  
Ru Li ◽  
Xiao Yong Du ◽  
Ming Xia Zhang ◽  
Jie Tang ◽  
...  

Continuous multi-filament boron nitride fibers have been prepared on a large scale using the melt drawn technique from a low-cost boracic acid. Boracic acid was heated to obtain the molten boric oxide in a melting tank. Molten boric oxide was melt spun in a conventional manner through an 200-tip bushing to produce a continuous multifilament yarn consisting of 200 filaments of boric oxide. Boric oxide fibers were nitrided in an ammonia and were annealed in an inert atmosphere while simultaneously subjecting the fibers to sufficient longitudinal tension as to at least prevent longitudinal shrinkage of the fibers. The resulting fibers, consisting essentially of boron nitride, were less than about 8 μm in diameter and greater than 500 m in length. It indicated that the boron nitride fibers has a sound mechanical function with tensile strength of 1.40 GPa. The continuous boron nitride fibers of high-performance were especially suitable for reinforcing plastic, ceramic or metal matrices in the preparation of fiber reinforced composites.


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