scholarly journals Determination of the concentration of CO2 and H2O vapor under conditions of overlapping spectral lines

2021 ◽  
Vol 2127 (1) ◽  
pp. 012042
Author(s):  
M M Kugeiko ◽  
A A Baravik
Keyword(s):  
Component Composition ◽  
Spectral Lines ◽  
Measurement Information ◽  
Multicomponent Media ◽  
Different Temperatures ◽  
Regression Relations ◽  
Temperature And Pressure ◽  
Analytical Expressions ◽  
Gas Medium

Abstract The efficiency of determining the concentration of CO2 and H2O vapors in the atmosphere has been investigated taking into account the overlap of their spectral lines. It is proposed to use regression relationships established between the determined and measured parameters of the investigated medium. These ratios can be set both for fixed values of temperature and pressure, and for a set range of their values. When calculating the absorption value, all overlaps of spectral lines are taken into account, taking into account their broadening at different temperatures and pressures. This allows the method to be used in multicomponent media with strongly overlapping spectral lines. The established regression relations are resistant to errors in the measurement information, which also improves the accuracy of determining the concentrations of the component composition of the gas medium. In addition, they are determined promptly (in real time), since the calculation of concentrations using established relationships (analytical expressions) between the determined and measured values does not present computational difficulties.

Quantitative Assessment of Soluble Fibrin in Plasma by Affinity Chromatography – A Comparative Study with desAA-Fibrin, desAABB-Fibrin and Fibrinogen

1985 ◽  
Vol 54 (02) ◽  
pp. 533-538 ◽  
Author(s):  
Wilfried Thiel ◽  
Ulrich Delvos ◽  
Gert Müller-Berghaus
Keyword(s):  
Affinity Chromatography ◽  
Calcium Ions ◽  
Quantitative Assessment ◽  
Fluid Phase ◽  
Soluble Fibrin ◽  
Binding Characteristics ◽  
Different Temperatures ◽  
Immobilized Proteins ◽  
Sepharose 4B

SummaryA quantitative determination of soluble fibrin in plasma was carried out by affinity chromatography. For this purpose, desAA-fibrin and fibrinogen immobilized on Sepharose 4B were used at the stationary side whereas batroxobin-induced 125I-desAA-fibrin or thrombin-induced 125I-desAABB-fibrin mixed with plasma containing 131I-fibrinogen represented the fluid phase. The binding characteristics of these mixtures to the immobilized proteins were compared at 20° C and 37° C. Complete binding of both types of fibrin to the immobilized desAA-fibrin was always seen at 20° C as well as at 37° C. However, binding of soluble fibrin was accompanied by substantial binding of fibrinogen that was more pronounced at 20° C. Striking differences depending on the temperature at which the affinity chromatography was carried out, were documented for the fibrinogen-fibrin interaction. At 20° C more than 90% of the applied desAA-fibrin was bound to the immobilized fibrinogen whereas at 37° C only a mean of 17% were retained at the fibrinogen-Sepharose column. An opposite finding with regard to the tested temperature was made with the desAABB-fibrin. Nearly complete binding to insolubilized fibrinogen was found at 37° C (95%) but only 58% of the desAABB-fibrin were bound at 20° C. The binding patterns did not change when the experiments were performed in the presence of calcium ions. The opposite behaviour of the two types of soluble fibrin to immobilized fibrinogen at the different temperatures, together with the substantial binding of fibrinogen in the presence of soluble fibrin to insolubilized fibrin in every setting tested, devaluates affinity chromatography as a tool in the quantitative assessment of soluble fibrin in patients’ plasma.

Diagnostics of the location of damage to tubing oil well pipes

2019 ◽  
Vol 5 (4) ◽  
pp. 115-128
Author(s):  
Timur A. Ishmuratov ◽  
Rif G. Sultanov ◽  
Milyausha N. Khusnutdinova
Keyword(s):  
Fluid Motion ◽  
Oil Well ◽  
General Belief ◽  
Oil Flow ◽  
Specialized Equipment ◽  
Improving Accuracy ◽  
Analytical Expressions ◽  
Technical Measures ◽  
Quick Determination

The study is devoted to the mathematical description of the process of oil outflow in places of leakage of the tubing string, which allows a computer to locate a leakage in the tubing. The authors propose methodology for identifying defects in the tubing and determining the location of the leak. The uniqueness of this methodology lies in quick determination of the place of leakage without the use of specialists, sophisticated and specialized equipment. Mathematical modeling of oil flow in the tubing requires the apparatus of continuum mechanics. It is a general belief that the movement of oil in the pipe flows at low speeds due to its outflow from the hole. Using the general equations of mass and energy balance, the authors have obtained differential equations of fluid motion in a vertical pipe in the process of its outflow from the tubing and in the process of injection. Analytical expressions are the solution to these equations, as they can help in estimating the degree of damage and its location, as well as the feasibility of its eliminating. The results show that an increase in the leakage and injection times leads to improving accuracy of locating damage. Thus, when conducting various geological and technical measures (GTM) at the well, it is possible to assess the presence of leakage and its intensity when deciding on the repair of tubing.

scholarly journals The Semiclassical Limit of the Gailitis Formula Applied to Electron Impact Broadening of Spectral Lines of Ionized Atoms

Atoms ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 29
Author(s):  
Sylvie Sahal-Bréchot
Keyword(s):  
Electron Impact ◽  
Classical Limit ◽  
Semiclassical Limit ◽  
Spectral Lines ◽  
Stark Broadening ◽  
Feshbach Resonances

The present paper revisits the determination of the semi-classical limit of the Feshbach resonances which play a role in electron impact broadening (the so-called “Stark“ broadening) of isolated spectral lines of ionized atoms. The Gailitis approximation will be used. A few examples of results will be provided, showing the importance of the role of the Feshbach resonances.

scholarly journals Determination of Load-Carrying Capacity of C-Profile Glued Ti-Al Column under Temperature Environment

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3013
Author(s):  
Leszek Czechowski
Keyword(s):  
Carrying Capacity ◽  
Tensile Tests ◽  
Discrete Models ◽  
Image Correlation ◽  
Load Carrying Capacity ◽  
Lagrange Equations ◽  
Load Carrying ◽  
Different Temperatures ◽  
Influence Of Temperature On

The paper deals with an examination of the behaviour of glued Ti-Al column under compression at elevated temperature. The tests of compressed columns with initial load were performed at different temperatures to obtain their characteristics and the load-carrying capacity. The deformations of columns during tests were registered by employing non-contact Digital Image Correlation Aramis® System. The numerical computations based on finite element method by using two different discrete models were carried out to validate the empirical results. To solve the problems, true stress-logarithmic strain curves of one-directional tensile tests dependent on temperature both for considered metals and glue were implemented to software. Numerical estimations based on Green–Lagrange equations for large deflections and strains were conducted. The paper reveals the influence of temperature on the behaviour of compressed C-profile Ti-Al columns. It was verified how the load-carrying capacity of glued bi-metal column decreases with an increase in the temperature increment. The achieved maximum loads at temperature 200 °C dropped by 2.5 times related to maximum loads at ambient temperature.

scholarly journals THE EFFECTS ON BIOLOGICAL MATERIALS OF FREEZING AND DRYING BY VACUUM SUBLIMATION

1954 ◽  
Vol 100 (1) ◽  
pp. 81-88 ◽  
Author(s):  
Donald Greiff ◽  
Henry Pinkerton
Keyword(s):  
Influenza Virus ◽  
Biological Materials ◽  
Continuous Operation ◽  
Virus Suspension ◽  
Vacuum Sublimation ◽  
End Point ◽  
Different Temperatures ◽  
Time Required

A vacuum sublimation apparatus is described which will permit, (a) the removal of water from virus suspensions at temperatures ranging down to –80°C., (b) continuous operation with a minimum of attention from the investigator, (c) sealing off of samples at operating pressures (10–5 mm. Hg), (d) simultaneous lyophilization of aliquot samples at different temperatures, (e) isolation of a portion of the apparatus without disturbing the remainder of the system, and (f) determination of the end-point of sublimation without disturbing the samples. The time required for drying 0.1 ml. of influenza virus suspension was shown to increase markedly with decrease of temperature, 8 days being required for dehydration at –80°C. in contrast to 2 days at –30°C. and 1 day at 0°C.

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