scholarly journals Optimisation Of Nano-ZnO And Nano-SiO2 Mixing Time For Bitumen Modification

2021 ◽  
Vol 1202 (1) ◽  
pp. 012017
Author(s):  
Judita Gražulytė ◽  
Audrius Vaitkus ◽  
Simona Bitarytė

Abstract Nanotechnologies have gradually penetrated to the field of bitumen modification especially where durable asphalt mixtures have to be designed. Longer mixing time, higher temperatures or/and higher rotation (shearing) speeds are needed to increase the dispersion of nanoparticles in bitumen. However, this is not necessarily beneficial to the physical and mechanical properties of the final material. As a result, in this study nano-zinc oxide (nano-ZnO) and nano-silica (nano-SiO2) mixing time for bitumen modification was optimized considering the physical and mechanical properties of the final bitumen. For this purpose bitumen PMB 25/55-60 was modified with nanoparticles at 180 °C using a laboratory high-shear mixer at a rotation speed of 4000 rpm for different modification time selected on the basis of literature review (60 and 90 minutes). Penetration, softening point, viscosity at 135 °C, recovery and non-recoverable creep compliance (multiple stress creep and recovery test) at 60 °C were measured in order to determine the optimal mixing time. The results showed that 60 minutes ensures the dispersion of nano-ZnO and nano-SiO2 in the bitumen PMB 25/55-60 and longer mixing time do not have a significant effect on the properties of nano-ZnO and nano-SiO2 modified bitumen (the difference was less than 7%).

CERNE ◽  
2016 ◽  
Vol 22 (4) ◽  
pp. 465-474 ◽  
Author(s):  
Siroos Habibzade ◽  
Hamid R. Taghiyari ◽  
Asghar Omidvar ◽  
Hamid R. Roudi

ABSTRACT Nanoparticles have been vastly applied in wood polymer composites (WPCs) in the recent years to improve some of the drawbacks of solid wood species. In the present study, the effects of ZnO nanoparticles on fire retarding, physical, and mechanical properties of polymerized poplar wood were investigated. Poplar specimens were impregnated with styrene monomer, containing four different contents of nano-zinc oxide (ZnO) (0, 0.5, 1 and 1.5%, based on the dry weight of monomer). Results of the scanning electron microscopy (SEM) showed homogeneous dispersion of ZnO nanoparticles in the WPC matrix. Nano-zinc oxide improved physical properties such as dimensional stability and water absorption. Moreover, mechanical properties increased in comparison to the control specimens. The impregnation process also significantly improved some of the fire-retarding properties, including the ignition time; however, the flammability nature of styrene aggravated some others, such as carbonized area. It was concluded that, although most of the properties were improved, the final application of WPC should be taken in to consideration before making decision on whether or not to impregnate populus wood with styrene.


2021 ◽  
Vol 29 (1) ◽  
pp. 21-34
Author(s):  
Vera G. Matveeva ◽  
Mariam Yu. Khanova ◽  
Tatyana V. Glushkova ◽  
Larisa V. Antonova

Aim. To evaluate the potential utility of fibrin matrices containing 10, 20, and 25 mg/ml of fibrinogen (fibrin-10, fibrin-20, and fibrin-30, respectively) in vascular tissue engineering (VTE). Materials and Methods. Fibrinogen was isolated using the method of ethanol cryoprecipitation and polymerized using a solution of thrombin and CaCl2. The fibrin structure was studied in a scanning electron microscope, and the physical and mechanical properties of the material were tested on a Zwick/Roell test machine. The metabolic activity of endothelial cells (EC) on the fibrin surface was evaluated by the MTT assay, and the viability of fibroblasts in the thickness of fibrin and possibility for migration by in fluorescent and light microscopy. Percent of fibrin shrinkage was determined from the difference in the sample volumes before and after removal of moisture. Results. The fiber diameter did not differ among all fibrin samples, but the pore diameter in fibrin-30 was smaller than those in fibrin-10 and fibrin-20. A possibility for migration of fibroblasts into the depth of the fibrin matrix and preservation of 97-100% viability of cells at a depth 5 mm was confirmed. The metabolic activity of EC on the surface of fibrin-20 and fibrin-30 exceeded that on collagen, fibronectin, and fibrin-10. All fibrin samples shrank in volume to 95.5-99.5%, and the highest shrinkage was seen in fibrin-10. The physical and mechanical properties of fibrin were inferior to those of human A. mammaria by a factor of 10. Conclusion. Fibrin with fibrinogen concentrations of 20 and 30 mg/ml maintains a high metabolic and proliferative activity of EC on the surface and also a high viability of fibroblasts in the matrix. Its availability, ease of preparation, and a number of other favorable properties make fibrin a promising material for VTE. However, the problem of insufficient strength requires further investigations.


2021 ◽  
pp. 1-10
Author(s):  
Menglin Du ◽  
Feng Gao ◽  
Chengzheng Cai ◽  
Shanjie Su ◽  
Zekai Wang

Abstract Exploring the damage differences between different coal rank coal reservoirs subjected to liquid nitrogen (LN2) cooling is of great significance to the rational development and efficient utilization of coalbed methane. For this purpose, the mechanical properties, acoustic emission (AE) characteristics and energy evolution law of lignite and bituminous coal subjected to LN2 cooling were investigated based on the Brazilian splitting tests. Then, pore structure changes were analyzed to reveal the difference in the microscopic damage between lignite and bituminous coal after LN2 cooling. The results showed that compared with bituminous coal, the pore structure of lignite coal changed more obviously, which was manifested as follows: significant increases in porosity, pore diameters, and pore area; a larger transformation from micropores and transition pores to mesopores and macropores. After LN2 cooling, the thermal damage inside lignite and bituminous coal was 0.412 and 0.069, respectively. The thermal damage reduced the cohesive force between mineral particles, leading to the deterioration of the macroscopic physical and mechanical properties. Simultaneously, denser AE ringing counts and larger accumulated ringing counts were observed after LN2 cooling. Moreover, the random distribution of thermal damage enhanced the randomness of the macrocrack propagation direction, resulting in an increase in the crack path tortuosity. With more initial defects inside coal, a more obvious thermal damage degree and wider damage distribution will be induced by LN2 cooling, leading to more complicated crack formation paths and a higher fragmentation degree, such as that of lignite coal.


Animals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1482
Author(s):  
Ashraf Alkhtib ◽  
Dawn Scholey ◽  
Nicholas Carter ◽  
Gareth W.V. Cave ◽  
Belal I. Hanafy ◽  
...  

Recently, nanotechnology has been widely adopted in many fields. The goal of this study was to evaluate the potential for amino acid coated nano minerals as a supplement in broiler feed. Zinc was selected as a model mineral for this test and supplementation of nano zinc, both coated and uncoated was compared with organic and inorganic commercial forms of zinc. A total of 48 pens (8 birds each) were assigned to one of the following dietary treatments: Control, methionine-Zinc chelate (M-Zn), nano zinc oxide (Nano-ZnO), and methionine coated nano zinc oxide (M-Nano-ZnO). All experimental diets were formulated with the same total zinc, methionine, protein, and energy content with just the zinc source as a variable. Bird weight, feed intake and feed conversion ratios were recorded weekly, with three birds culled (sacrificed) at day 21 and day 35 for sampling measures. Ileal digestibility of zinc was determined at day 21 and day 35 using titanium dioxide as an inert marker. Blood serum, liver and spleen samples were collected at day 21 and day 35 and analysed for zinc content via inductively coupled plasma mass spectrometry (ICP-MS). Tibia strength and morphometrics were measured from both legs of three birds per pen at day 21 and day 35. The study was conducted at Nottingham Trent University Poultry Unit, UK. The novel method of producing nano minerals coated with amino acids was successfully tested with zinc and material produced to test in the feeding study. Methionine coated nano zinc oxide supplementation significantly improved bird weight gain and the increased feed intake of broilers compared to an inorganic zinc form. Ileal digestibility was also improved with this methionine-nano zinc. Moreover, this supplementation improved the tibia strength of broilers at the age of 21 days, though this was not observed at day 35. Therefore, M-Nano-ZnO could be used to supplement broilers to improve both performance and digestibility with a limited positive impact on bone strength. The results of the current study suggest that the amino acid coating of nano minerals can improve the digestibility of minerals which may have further implications for the field of mineral nutrition in animal feeds.


1986 ◽  
Vol 76 ◽  
Author(s):  
C. W. Wilkins ◽  
H. E. Bair ◽  
M. G. Chan ◽  
R. S. Hutton

ABSTRACTWe have studied some of the physical and mechanical properties of cyclized polybutadiene (CBR) dielectrics by dynamic mechanical analysis, thermal mechanical analysis, thermogravimetry, infrared analysis, and differential scanning calorimetry. Of interest is the difference in properties between thin (<30 μm) films which have been cured under vacuum and those which have been cured in air. Our results indicate that curing under vacuum prevents oxidation and reduces crosslinking. Vacuum cured films have 20% smaller moduli and 200 lower glass transition temperature than do films produced in air.


2011 ◽  
Vol 415-417 ◽  
pp. 35-38 ◽  
Author(s):  
Guang Qing Gai ◽  
Xiang Ting Dong ◽  
Xue Song Chen ◽  
Cheng Yan Zheng

The nano-particle modified epoxy resin adhesive was prepared by adding different types of nanoparticles to the epoxy resin adhesives.The influence of the kinds and amount of nanoparticles on the mechanical properties of epoxy resin adhesive was investigated.The investigation results indicated that the addition of three kinds of nanoparticles including nano-silica,nano-titanium dioxide,nano zinc oxide to epoxy resin adhesive has a significant influence on the mechanical properties of nano-composites.And tensile strength and breaking elongation of nano-composites reached the maximum when the amount of nanoparticle reached 4wt%.In addition,the toughening mechanisms of nano-particles modified epoxy resin adhesives was analysed.


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