Tris (hydroxymethyl) ethane (PG) as a phase change material, micro-porous xonotlite (CS) as matrix, PG/CS composite PCMs were prepared by melt-soaking method, and the effect of micro-porous structure of xonotlite on heat absorption capacity, bending strength and insulation performance of composites, and the exudation of PG was studied. Otherwise, for the work environment and characteristics of propulsive device of vehicle, this paper explored the feasibility that phase change materials (PCMs) worked as the insulation material in short-time insulation system of the vehicle. Experimental results show that, when the most probable pore diameters of xonotlite was not less than 63nm, the composites presented better and almost same absorption capacities of matrix (CS) to PCM (PG) in different composites; when up to 85nm, the composite exhibited the lowest leakage rate (less than 5%), the optimal mechanical property and thermal insulation performance. This Study proposed a new idea for the design of the insulation material in the thermal protection system of propulsive device of vehicle.