Improved Monomolecular Fat Film Method for Determination of Yolk in Egg Albumen

1980 ◽  
Vol 63 (4) ◽  
pp. 939-940
Author(s):  
Lawrence E Taber
Keyword(s):  
Acetic Acid Solution ◽  
Glass Plate ◽  
Third Order ◽  
Circular Pattern ◽  
Monomolecular Film ◽  
Oxidized Oil ◽  
Egg Albumen ◽  
Sample Aliquot ◽  
Film Method

Abstract The monomolecular film method can be simplified by an improved quantitation procedure. Following the extraction of the fat from the albumen and subsequent evaporation, the redissolved sample is applied to a round glass plate containing 1 in. pH 5 acetic acid solution topped by a film of oxidized oil sufficient to exhibit a color of third order green. The sample aliquot is dropped from a 100 μL Hamilton syringe directly at the center of the oil surface. A circular pattern results. The diameter of the pattern is measured in centimeters with a ruler placed under the glass plate. The area of the pattern is then calculated by the formula for the area of a circle.

Monomolecular Film Method for Determining Microquantities of Fat in Egg Albumen

1976 ◽  
Vol 59 (5) ◽  
pp. 1059-1060
Author(s):  
Lawrence E Taber
Keyword(s):  
Petroleum Ether ◽  
Alkaline Hydrolysis ◽  
Egg Yolk ◽  
Distilled Water ◽  
Chemical Test ◽  
Monomolecular Film ◽  
Oxidized Oil ◽  
Egg Albumen ◽  
Film Method

Abstract A very small amount of egg yolk (0.04–0.05%) in egg albumen interferes with the performance of the latter in the baking of angel food cakes. For many years no practical chemical test was available that would adequately determine these small amounts. In the proposed method, lipids are extracted from a sample of albumen, using a form of alkaline hydrolysis, and extracted again with petroleum ether. A known aliquot is expelled on a film of oxidized oil which has been suspended on the surface of distilled water. The resulting spot is measured by tracing its outline and measuring the area with a compensating planimeter.

HPLC-UV Method for Determination of Famotidine from Pharmaceutical Products

2018 ◽  
Vol 69 (2) ◽  
pp. 297-299
Author(s):  
Adriana Nita ◽  
Delia Mirela Tit ◽  
Lucian Copolovici ◽  
Carmen Elena Melinte (Frunzulica) ◽  
Dana Maria Copolovici ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Quantitative Analysis ◽  
Linear Response ◽  
Mobile Phase ◽  
Acetic Acid Solution ◽  
Pharmaceutical Products ◽  
Quantification Limit ◽  
Validation Parameters ◽  
Hplc Analyses

The aim of this study was to develop and validate a rapid, accurate, and exact method for the quantitative determination of famotidine in pharmaceutical products. The HPLC analyses were performed by using a mobile phase containing methanol:1% acetic acid solution=30:7 (v/v), at a flow rate of 0.4 mL/min.The total time of the method was 10 min, and the retention time of famotidine was 4.16 min. The detection was evaluated at l=267 nm. The method has been validated by using different validation parameters. The linear response of the detector for famotidine peak area was observed at concentrations ranging from 0.1 to 0.0001 mg mL-1 , resulting in a correlation coefficient of 0.99998. The values of the detection limit and of the quantification limit are 0.00048 mg mL-1 and 0.00148 mg mL-1, respectively. The method proposed allowed accurate (with a relative error of less than 2%) and precise (RSD values less than 2.0%) determination of famotidine content in pharmaceutical products and can be used for its rapid quantitative analysis.

A multitechnique investigation of the second order NLO response of a 10,20-diphenylporphyrinato nickel(II) complex carrying a phenylethynyl based push-pull system in the 5- and 15-positions

2004 ◽  
Vol 08 (11) ◽  
pp. 1311-1324 ◽  
Author(s):  
Maddalena Pizzotti ◽  
Elisabetta Annoni ◽  
Renato Ugo ◽  
Silvia Bruni ◽  
Silvio Quici ◽  
...  
Keyword(s):  
Ab Initio ◽  
Planar Structure ◽  
Third Order ◽  
Incident Wavelength ◽  
Pull System ◽  
Nlo Response ◽  
Self Consistent ◽  
Order Of Magnitude ◽  
Zero Frequency

A multitechnique investigation of the determination of the order of magnitude of the second and third order NLO response of [5-[(4-dimethylaminophenyl)ethynyl]-15-[(4-nitrophenyl)ethynyl]-10,20-diphenylporphyrinato]nickel(II) (1) is reported with the aim to produce self consistent evidence for a significant NLO response of this kind of push-pull porphyrin chromophore. The experimental multitechnique approach is based on the EFISH technique, working with a non-resonant incident wavelength of 1.907 μm, on the solvatochromic method and finally on a vibrational method, avoiding any fluorescence or resonance interference. A theoretical MNDO-TDHF evaluation of the zero-frequency quadratic and cubic hyperpolarizabilities of an ab initio optimized planar structure is also reported. The order of magnitude of the quadratic hyperpolarizability of (1) at zero frequency (β0), was found to be significantly lower than that reported for the corresponding Cu (II) or Zn (II) complexes with the same push-pull porphyrin chromophore.

scholarly journals DETERMINATION OF THE ENERGY GAP OF C60 MOLECULE USING THIRD-ORDER DERIVATIVE ABSORPTION SPECTROSCOPY

1998 ◽  
Vol 47 (2) ◽  
pp. 208
Author(s):  
ZHAO MING-SHAN ◽  
DAI ZUO-XIAO ◽  
LI YI ◽  
LI GUO-HUA ◽  
BU YU-XIANG ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Energy Gap ◽  
Order Derivative ◽  
Third Order

Determination of Chlorbenside Residues Including Its Sulfoxide and Sulfone Oxidation Products

1966 ◽  
Vol 49 (2) ◽  
pp. 407-412
Author(s):  
Harry Shuman ◽  
Ugo R Cieri
Keyword(s):  
Gas Chromatography ◽  
Acetic Acid ◽  
Acid Solution ◽  
Aluminum Oxide ◽  
Electron Capture ◽  
Acetic Acid Solution ◽  
Extraction Procedure ◽  
Oxidation Products ◽  
Aluminum Oxide Column

Abstract A method is presented for determining residues of chlorbenside including its sulfoxide and sulfone oxidation products. The method employs the Mills-Onley-Gaither extraction procedure. Chlorbenside and chlorbenside sulfoxide are converted to chlorbenside sulfone by a short oxidation with chromic-acetic acid solution. Chlorbenside sulfone is isolated from interfering pesticides and most oxidation products on an aluminum oxide column and determined by electron capture gas chromatography. Recoveries for mixtures of the three components added to apple samples at 0.3–5 ppm (calculated as chlorbenside) were between 92 and 110%.

scholarly journals A NEW VALIDATED THIRD ORDER DERIVATIVE SPECTROSCOPIC METHOD FOR SIMULTANEOUS ESTIMATION OF METOPROLOL SUCCINATE AND RAMIPRIL IN TABLET DOSAGE FORM

2020 ◽  
pp. 54-59
Author(s):  
ALEKHYA B. ◽  
M. SINDHUSHA ◽  
SORAJ K. RAUL ◽  
GOPAL K. PADHY
Keyword(s):  
Quantitative Analysis ◽  
Dosage Form ◽  
Spectroscopic Method ◽  
Simultaneous Estimation ◽  
Third Order ◽  
Metoprolol Succinate ◽  
Zero Crossing ◽  
Ich Guidelines ◽  
Tablet Dosage

Objective: The objective of the present work is to develop and validate a new UV derivative spectrophotometric method for simultaneous estimation of metoprolol succinate and ramipril in methanol: water (50:50v/v). Methods: “Zero crossing technique” was chosen for quantitative determination. The zero-crossing points (ZCP’s) were found to be 209 nm where metoprolol succinate was quantified and 211 nm where ramipril was quantified. This method was then subjected to accuracy, linearity, sensitivity and reproducibility according to ICH guidelines to ensure and confirm its validity. Results: The method was found to be obeying Beer’s law in the range of 10-50 µg/ml and 5-25 µg/ml for metoprolol succinate and ramipril, respectively. The % recoveries were observed between the range of 99.2-100.2 for metoprolol succinate and 99.57-99.86 for ramipril. The intra-day and inter-day results showed reproducibility. Conclusion: It can be concluded that the developed third-order UV derivative spectroscopic method for the simultaneous determination of metoprolol succinate and ramiprilcan be recommended for routine quantitative analysis.

Determination of Nonchaotic Behavior for Some Classes of Polynomial Jerk Equations

2020 ◽  
Vol 30 (08) ◽  
pp. 2050117
Author(s):  
Marcelo Messias ◽  
Rafael Paulino Silva
Keyword(s):  
Mathematical Model ◽  
Differential Equations ◽  
Ordinary Differential Equations ◽  
Simple Form ◽  
Chaotic Dynamics ◽  
Third Order ◽  
Algebraic Criterion

In this work, by using an algebraic criterion presented by us in an earlier paper, we determine the conditions on the parameters in order to guarantee the nonchaotic behavior for some classes of nonlinear third-order ordinary differential equations of the form [Formula: see text] called jerk equations, where [Formula: see text] is a polynomial of degree [Formula: see text]. This kind of equation is often used in literature to study chaotic dynamics, due to its simple form and because it appears as mathematical model in several applied problems. Hence, it is an important matter to determine when it is chaotic and also nonchaotic. The results stated here, which are proved using the mentioned algebraic criterion, corroborate and extend some results already presented in literature, providing simpler proofs for the nonchaotic behavior of certain jerk equations. The algebraic criterion proved by us is quite general and can be used to study nonchaotic behavior of other types of ordinary differential equations.

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