The Discovery of Nitrogen and the Disappearance of Alchemical Nitre: The Rise of Agricultural Chemistry in the Eighteenth and Nineteenth Centuries
So far, we have seen how sophisticated systems of agriculture had grown up in many different places and at various times in order to overcome problems associated with the decline of soil fertility arising from continuous exploitation. In Europe and elsewhere, it was clearly understood that manures and various materials such as potassium (or sodium) nitrate could rejuvenate the soil, and empirically probably little more could have been achieved in this direction. Nevertheless, the supply of the products capable of doing this was clearly limited. Only when the scientific basis of the action of fertilisers and manures had been fully understood could further advances be made, and this only happened with the scientific revolution, which began to flower in the sixteenth century and continues in bloom to this day. The empirical experience of centuries seems to have led to the supposition in Europe that the air was somehow involved in restoring the fertility of soils and in the facilitation of plant growth. However, the reason for this influence could not have been presented in modern terms. A lot of the discussion was centred about the mysterious substance nitre, which was then not simply the salt we recognise today. There are many instances of statements to the effect that nitre was absorbed from the air and even references in the older literature to aerial nitre. Solid nitre was, of course, very well-known in the form of saltpetre and was widely employed as a constituent of gunpowder. This kind of nitre could also be used as a fertiliser, though there was not enough of it around to “waste” by spreading it on the soil. Then, as is often true today, warfare was regarded as a more important use for such a resource. Nitre could be extracted from manures and from ashes, and, because it was a crystalline solid, it certainly was not the mysterious something that was present in the air. There was no understanding of the modern notions of elements and compounds. It would take a long time—two centuries—for a truly scientific approach to agricultural chemistry to be developed, but it is still worthwhile to enquire what exactly writers of treatises in the mid-seventeenth century really meant.