The effects of source mixing and fractional crystallization on the composition of Eocene granites in the Himalayan orogen

2021 ◽  
Author(s):  
Peng Gao ◽  
Yong-Fei Zheng ◽  
Chris Yakymchuk ◽  
Zi-Fu Zhao ◽  
Zi-Yue Meng
Keyword(s):  
Trace Element ◽  
Partial Melting ◽  
Fractional Crystallization ◽  
Melt Inclusions ◽  
Thermal Anomaly ◽  
Continental Collision ◽  
Plate Boundaries ◽  
Crustal Anatexis ◽  
Himalayan Orogen ◽  
Heavy Rare Earth Elements

Abstract Granites are generally the final products of crustal anatexis. The composition of the initial melts may be changed by fractional crystallization during magma evolution. Thus, it is crucial to retrieve the temperatures and pressures conditions of crustal anatexis on the basis of the composition of the initial melts rather than the evolved melts. Here we use a suite of ∼46–41 Ma granites from the Himalayan orogen to address this issue. These rocks can be divided into two groups in terms of their petrological and geochemical features. One group has high maficity (MgO + FeOt = 2–4 wt%) and mainly consists of two-mica granites, and is characterized by apparent adakite geochemical signatures, including high Sr concentrations, Sr/Y and La/Yb ratios; and low concentrations of HREE (heavy rare earth elements) and Y. The other group has low maficity (MgO + FeOt <1 wt%) and consists of subvolcanic porphyritic granites and garnet/tourmaline-bearing leucogranites. This group does not possess apparent adakite signatures. The low maficity group (LMG) has lower MgO + FeOt contents and the high maficity group (HMG) has higher Mg# compared with initial anatectic melts determined by experiment petrology and melt inclusions study. Petrological observations indicate that the HMG and the LMG can be explained as a crystal-rich cumulate and its fractionated melt, respectively, such that the initial anatectic melt is best represented by an intermediate composition. Such a cogenetic relationship is supported by the comparable Sr–Nd isotopic compositions of the two coeval groups. However, these compositions are also highly variable, pointing to a mixed source that was composed of amphibolite and metapelite with contrasting isotope compositions. We model the major and trace element compositions of anatectic melts generated by partial melting of the mixed source at four apparent thermobaric ratios of 600, 800, 1000 and 1200 °C/GPa. Modeling results indicate that melt produced at 1000 °C/GPa best matches the major and trace element compositions of the inferred initial melt compositions. In particular, a binary mixture generated from 10 vol% partial melting of amphibolite and 30 vol% melting of metapelite at 850 ± 50 °C and 8.5 ± 0.5 kbar gives the best match. Therefore, this study highlights that high thermobaric ratios and subsequent fractional crystallization are responsible for the generation of the apparent adakitic geochemical signatures, rather than melting at the base of the thickened crust as previously proposed. The thermal anomaly responsible for the Eocene magmatism in the Himalayan orogen was probably related to asthenosphere upwelling in response to rollback of the subducting Neo-Tethyan oceanic slab at the terminal stage of continental collision between India and Asia. As such, a transition in dynamic regime from compression to extension is necessary for the generation of high thermobaric ratios in the continental collision zone. Therefore, on the basis of evaluating the potential role of fractional crystallization in altering the composition of the initial melt, granite geochemistry coupled with thermodynamic modeling can better elucidate the petrogenesis of granites and the geodynamic mechanisms associated with anatexis at convergent plate boundaries.

The granitic pegmatites of the Fregeneda area (Salamanca, Spain): characteristics and petrogenesis

1999 ◽  
Vol 63 (4) ◽  
pp. 535-558 ◽  
Author(s):  
E. Roda Robles ◽  
A. Pesquera Perez ◽  
F. Velasco Roldan ◽  
F. Fontan
Keyword(s):  
Trace Element ◽  
Partial Melting ◽  
Fractional Crystallization ◽  
Zonal Distribution ◽  
Granitic Pegmatites ◽  
Compositional Variations

AbstractPegmatites of the Fregeneda area, Salamanca, Spain, show a zonal distribution, from barren to enrichment in Li, Sn, Rb, Nb>Ta, B and P. They intrude pre-Ordovician metasediments which were metamorphosed to sillimanite-zone conditions near the Lumbrales granite. Field, mineralogical and petrographic data show the following zonal sequence from the granite outward: (1) barren pegmatites (pegmatites T1, T2, T3 and T4) with quartz, K-feldspar > albite, muscovite, tourmaline ± andalusite ± garnet; (2) intermediate pegmatites (types T5 and T6), characterized by the occurrence of beryl and Fe-Mn-Li phosphates; and (3) fertile pegmatites (dykes T7 and T8), with lepidolite, cassiterite, columbite, albite > K-feldspar, montebrasite and spodumene.Tourmaline from different pegmatites shows significant compositional variations. Trace element variations in mica and K-feldspar suggest that the origin of the different pegmatitic bodies may be explained by three different paths of fractional crystallization of melts generated by partial melting of quartzo-feldspathic rocks.

Crustal assimilation in the Burnt Lake metavolcanics, Grenville Province, southeastern Ontario, and its tectonic significance

1997 ◽  
Vol 34 (9) ◽  
pp. 1272-1285 ◽  
Author(s):  
T. E. Smith ◽  
P. E. Holm ◽  
N. M. Dennison ◽  
M. J. Harris
Keyword(s):  
Rare Earth ◽  
Trace Element ◽  
Partial Melting ◽  
Continental Crust ◽  
Fractional Crystallization ◽  
Volcanic Rocks ◽  
Lake Area ◽  
Depleted Mantle ◽  
Mafic Magmas ◽  
Back Arc

Three intimately interbedded suites of volcanic rocks are identified geochemically in the Burnt Lake area of the Belmont Domain in the Central Metasedimentary Belt, and their petrogenesis is evaluated. The Burnt Lake back-arc tholeiitic suite comprises basalts similar in trace element signature to tholeiitic basalts emplaced in back-arc basins formed in continental crust. The Burnt Lake continental tholeiitic suite comprises basalts and andésites similar in trace element composition to continental tholeiitic sequences. The Burnt Lake felsic pyroclastic suite comprises rhyolitic pyroclastics having major and trace element compositions that suggest that they were derived from crustal melts. Rare earth element models suggest that the Burnt Lake back-arc tholeiitic rocks were formed by fractional crystallization of mafic magmas derived by approximately 5% partial melting of an amphibole-bearing depleted mantle, enriched in light rare earth elements by a subduction component. The modelling also suggests that the Burnt Lake continental tholeiitic rocks were formed by contamination – fractional crystallization of mixtures of mafic magmas, derived by ~3% partial melting of the subduction-modified source, and rhyolitic crustal melts. These models are consistent with the suggestion that the Belmont Domain of the Central Metasedimentary Belt formed as a back-arc basin by attenuation of preexisting continental crust above a westerly dipping subduction zone.

Geochemistry of a Tertiary continental basalt suite, Red Sea coastal plain, Egypt: petrogenesis and characteristics of the mantle source region

2003 ◽  
Vol 140 (1) ◽  
pp. 11-24 ◽  
Author(s):  
ABDEL-KADER M. MOGHAZI
Keyword(s):  
Trace Element ◽  
Partial Melting ◽  
Red Sea ◽  
Fractional Crystallization ◽  
Coastal Plain ◽  
Mantle Source ◽  
Source Region ◽  
Rift System ◽  
Mantle Source Region ◽  
Continental Basalt

Major and trace element data on Tertiary continental basalt flows from the Shalatein area, Red Sea coastal plain of Egypt, have been presented and used to obtain more information about their source region and the processes involved in their generation. The rocks are mainly alkali olivine basalt with MgO and Mg no. in the range of 9.8–5 wt % and 65–46, respectively. They display wide variations in incompatible element concentrations, particularly LREE, Zr, Nb, K, Y, Ba and Sr. There is no evidence of significant crustal contamination or a lithospheric mantle signature in these rocks. Normalized trace element patterns and diagnostic elemental ratios are very similar to those of modern ocean-island basalts (OIB) a feature which suggests that the mantle source region was the asthenosphere. Comparison with the different types of OIB indicates that the basalts may be derived from a high U/Pb (HIMU) source with slightly elevated K and Ba contents. The basalts show general trends of increasing incompatible elements (K2O, Nb, Y, Sr and Yb), and decreasing contents of compatible elements (Cr, Ni, Sc and Ca) with decreasing Mg no. Furthermore, TiO2, P2O5, LREE and Th define maxima at about Mg no.=56, suggesting late fractionation of Fe–Ti oxides and apatite. Although these variations are consistent with fractional crystallization processes, the wide variations in LREE contents and the incompatible trace element ratios Ce/Y (1.2–3.8), Zr/Nb (2.3–7.1) and Nb/Y (0.6–4) in the least fractionated samples (Mg no. > 56) suggest that fractional crystallization involving the observed phenocryst assemblage (olivine and clinopyroxene) cannot fully explain such compositional variations. Modelling of the mafic rocks (Mg no. > 56) using REE suggests varying degrees of partial melting of an enriched mantle source region in the garnet stability field. Partial melting is attributed to plume-related mantle upwelling beneath the Red Sea rift system.

scholarly journals The role of sulphur on the melting of Ca-poor sediment and on trace element transfer in subduction zones: an experimental investigation

2021 ◽  
Author(s):  
Anne-Aziliz Pelleter ◽  
Gaëlle Prouteau ◽  
Bruno Scaillet
Keyword(s):  
Trace Element ◽  
Partial Melting ◽  
Subduction Zones ◽  
Sediment Flux ◽  
Arc Magmas ◽  
Trace Element Contents ◽  
The Stability ◽  
Element Transfer ◽  
High Sediment

Abstract We performed phase equilibrium experiments on a natural Ca-poor pelite at 3 GPa, 750-1000 °C, under moderately oxidizing conditions, simulating the partial melting of such lithologies in subduction zones. Experiments investigated the effect of sulphur addition on phase equilibria and compositions, with S contents of up to ∼ 2.2 wt. %. Run products were characterized for their major and trace element contents, in order to shed light on the role of sulphur on the trace element patterns of melts produced by partial melting of oceanic Ca-poor sediments. Results show that sulphur addition leads to the replacement of phengite by biotite along with the progressive consumption of garnet, which is replaced by an orthopyroxene-kyanite assemblage at the highest sulphur content investigated. All Fe-Mg silicate phases produced with sulphur, including melt, have higher MgO/(MgO+FeO) ratios (relative to S-free/poor conditions), owing to Fe being primarily locked up by sulphide in the investigated redox range. Secular infiltration of the mantle wedge by such MgO and K2O-rich melts may have contributed to the Mg and K-rich character of the modern continental crust. Addition of sulphur does not affect significantly the stability of the main accessory phases controlling the behaviour of trace elements (monazite, rutile and zircon), although our results suggest that monazite solubility is sensitive to S content at the conditions investigated. The low temperature (∼ 800 °C) S-bearing and Ca-poor sediment sourced slab melts show Th and La abundances, Th/La systematics and HFSE signatures in agreement with the characteristics of sediment-rich arc magmas. Because high S contents diminish phengite and garnet stabilities, S-rich and Ca-poor sediment sourced slab melts have higher contents of Rb, B, Li (to a lesser extent), and HREE. The highest ratios of La/Yb are observed in sulphur-poor runs (with a high proportion of garnet, which retains HREE) and beyond the monazite out curve (which retains LREE). Sulphides appear to be relatively Pb-poor and impart high Pb/Ce ratio to coexisting melts, even at high S content. Overall, our results show that Phanerozoic arc magmas from high sediment flux margins owe their geochemical signature to the subduction of terrigenous, sometimes S-rich, sediments. In contrast, subduction of such lithologies during Archean appears unlikely or unrecorded.

Geochemistry and geochronology of OIB-type, Early Jurassic magmatism in the Zhangguangcai range, NE China, as a result of continental back-arc extension

2018 ◽  
Vol 158 (1) ◽  
pp. 143-157 ◽  
Author(s):  
Guangying Feng ◽  
Yildirim Dilek ◽  
Xiaolu Niu ◽  
Fei Liu ◽  
Jingsui Yang
Keyword(s):  
East Asia ◽  
Trace Element ◽  
Partial Melting ◽  
Early Jurassic ◽  
Ne China ◽  
Mafic Rocks ◽  
Asthenospheric Mantle ◽  
Trace Element Contents ◽  
Pacific Slab ◽  
Back Arc

AbstractThe Zhangguangcai Range in the Xing’an Mongolian Orogenic Belt, NE China, contains Early Jurassic (c. 188 Ma) Dabaizigou (DBZG) porphyritic dolerite. Compared with other island-arc mafic rocks, the DBZG dolerite is characterized by high trace-element contents, relatively weak Nb and Ta enrichments, and no Zr, Hf or Ti depletions, similar to OIB-type rocks. Analysed rocks have (87Sr/86Sr)i ratios of 0.7033–0.7044, relatively uniform positive ɛNd(t) values of 2.3–3.2 and positive ɛHf(t) values of 8.5–17.1. Trace-element and isotopic modelling indicates that the DBZG mafic rocks were generated by partial melting of asthenospheric mantle under garnet- to spinel-facies conditions. The occurrence of OIB-like mafic intrusion suggests significant upwelling of the asthenosphere in response to lithospheric attenuation caused by continental rifting. These processes occurred in an incipient continental back-arc environment in the upper plate of a palaeo-Pacific slab subducting W–NW beneath East Asia.

scholarly journals Origin of alkali-rich volcanic and alkali-poor intrusive carbonatites from a common parental magma

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ivan F. Chayka ◽  
Vadim S. Kamenetsky ◽  
Nikolay V. Vladykin ◽  
Alkiviadis Kontonikas-Charos ◽  
Ilya R. Prokopyev ◽  
...  
Keyword(s):  
Empirical Evidence ◽  
Fractional Crystallization ◽  
Melt Inclusions ◽  
Parental Magma ◽  
Progressive Increase ◽  
Topical Problem ◽  
Oldoinyo Lengai ◽  
Southern Siberia ◽  
Magmatic Stage ◽  
Common Parent

AbstractThe discrepancy between Na-rich compositions of modern carbonatitic lavas (Oldoinyo Lengai volcano) and alkali-poor ancient carbonatites remains a topical problem in petrology. Although both are supposedly considered to originate via fractional crystallization of a “common parent” alkali-bearing Ca-carbonatitic magma, there is a significant compositional gap between the Oldoinyo Lengai carbonatites and all other natural compositions reported (including melt inclusions in carbonatitic minerals). In an attempt to resolve this, we investigate the petrogenesis of Ca-carbonatites from two occurrences (Guli, Northern Siberia and Tagna, Southern Siberia), focusing on mineral textures and alkali-rich multiphase primary inclusions hosted within apatite and magnetite. Apatite-hosted inclusions are interpreted as trapped melts at an early magmatic stage, whereas inclusions in magnetite represent proxies for the intercumulus environment. Melts obtained by heating and quenching the inclusions, show a progressive increase in alkali concentrations transitioning from moderately alkaline Ca-carbonatites through to the “calcite CaCO3 + melt = nyerereite (Na,K)2Ca2(CO3)3” peritectic, and finally towards Oldoinyo Lengai lava compositions. These results give novel empirical evidence supporting the view that Na-carbonatitic melts, similar to those of the Oldoinyo Lengai, may form via fractionation of a moderately alkaline Ca-carbonatitic melt, and therefore provide the “missing piece” in the puzzle of the Na-carbonatite’s origin. In addition, we conclude that the compositions of the Guli and Tagna carbonatites had alkali-rich primary magmatic compositions, but were subsequently altered by replacement of alkaline assemblages by calcite and dolomite.

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