scholarly journals The role of sulphur on the melting of Ca-poor sediment and on trace element transfer in subduction zones: an experimental investigation

2021 ◽  
Author(s):  
Anne-Aziliz Pelleter ◽  
Gaëlle Prouteau ◽  
Bruno Scaillet
Keyword(s):  
Trace Element ◽  
Partial Melting ◽  
Subduction Zones ◽  
Sediment Flux ◽  
Arc Magmas ◽  
Trace Element Contents ◽  
The Stability ◽  
Element Transfer ◽  
High Sediment

Abstract We performed phase equilibrium experiments on a natural Ca-poor pelite at 3 GPa, 750-1000 °C, under moderately oxidizing conditions, simulating the partial melting of such lithologies in subduction zones. Experiments investigated the effect of sulphur addition on phase equilibria and compositions, with S contents of up to ∼ 2.2 wt. %. Run products were characterized for their major and trace element contents, in order to shed light on the role of sulphur on the trace element patterns of melts produced by partial melting of oceanic Ca-poor sediments. Results show that sulphur addition leads to the replacement of phengite by biotite along with the progressive consumption of garnet, which is replaced by an orthopyroxene-kyanite assemblage at the highest sulphur content investigated. All Fe-Mg silicate phases produced with sulphur, including melt, have higher MgO/(MgO+FeO) ratios (relative to S-free/poor conditions), owing to Fe being primarily locked up by sulphide in the investigated redox range. Secular infiltration of the mantle wedge by such MgO and K2O-rich melts may have contributed to the Mg and K-rich character of the modern continental crust. Addition of sulphur does not affect significantly the stability of the main accessory phases controlling the behaviour of trace elements (monazite, rutile and zircon), although our results suggest that monazite solubility is sensitive to S content at the conditions investigated. The low temperature (∼ 800 °C) S-bearing and Ca-poor sediment sourced slab melts show Th and La abundances, Th/La systematics and HFSE signatures in agreement with the characteristics of sediment-rich arc magmas. Because high S contents diminish phengite and garnet stabilities, S-rich and Ca-poor sediment sourced slab melts have higher contents of Rb, B, Li (to a lesser extent), and HREE. The highest ratios of La/Yb are observed in sulphur-poor runs (with a high proportion of garnet, which retains HREE) and beyond the monazite out curve (which retains LREE). Sulphides appear to be relatively Pb-poor and impart high Pb/Ce ratio to coexisting melts, even at high S content. Overall, our results show that Phanerozoic arc magmas from high sediment flux margins owe their geochemical signature to the subduction of terrigenous, sometimes S-rich, sediments. In contrast, subduction of such lithologies during Archean appears unlikely or unrecorded.

scholarly journals The Fluid Mobilities of K and Zr in Subduction Zones: Thermodynamic Constraints

Minerals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 394
Author(s):  
Richen Zhong ◽  
Min Zhang ◽  
Chang Yu ◽  
Hao Cui
Keyword(s):  
Trace Element ◽  
Subduction Zones ◽  
Critical Role ◽  
High Field Strength ◽  
Trace Element Pattern ◽  
Arc Magmas ◽  
Thermodynamic Simulations ◽  
Element Pattern ◽  
Element Transfer ◽  
Complex Ion

A subduction zone plays a critical role in forging continental crust via formation of arc magmas, which are characteristically enriched in large ion lithophile elements (LILEs) and depleted in high field strength elements (HFSEs). This trace element pattern results from the different mobilities of LILEs and HFSEs during slab-to-wedge mass transfer, but the mechanisms of trace element transfer from subducting crusts are not fully understood. In this study, thermodynamic simulations are carried out to evaluate the mobilities of K and Zr, as representative cases of LILE and HFSE, respectively, in slab fluids. The fluids buffered by basaltic eclogite can dissolve > 0.1 molal of K at sub-arc depths (~3 to 5.5 GPa). However, only minor amounts of K can be liberated by direct devolatilization of altered oceanic basalt, because sub-arc dehydration mainly takes place at temperatures < 600 °C (talc-out), wherein the fluid solubility of K is very limited (<0.01 molal). Therefore, serpentinite-derived fluids are required to flush K from the eclogite. The solubility of K can be enhanced by the addition of NaCl to the fluid, because fluid Na+ can unlock phengite-bonded K via a complex ion exchange. Finally, it is further confirmed that Zr and other HFSEs are immobile in slab fluids.

Geochemistry and geochronology of OIB-type, Early Jurassic magmatism in the Zhangguangcai range, NE China, as a result of continental back-arc extension

2018 ◽  
Vol 158 (1) ◽  
pp. 143-157 ◽  
Author(s):  
Guangying Feng ◽  
Yildirim Dilek ◽  
Xiaolu Niu ◽  
Fei Liu ◽  
Jingsui Yang
Keyword(s):  
East Asia ◽  
Trace Element ◽  
Partial Melting ◽  
Early Jurassic ◽  
Ne China ◽  
Mafic Rocks ◽  
Asthenospheric Mantle ◽  
Trace Element Contents ◽  
Pacific Slab ◽  
Back Arc

AbstractThe Zhangguangcai Range in the Xing’an Mongolian Orogenic Belt, NE China, contains Early Jurassic (c. 188 Ma) Dabaizigou (DBZG) porphyritic dolerite. Compared with other island-arc mafic rocks, the DBZG dolerite is characterized by high trace-element contents, relatively weak Nb and Ta enrichments, and no Zr, Hf or Ti depletions, similar to OIB-type rocks. Analysed rocks have (87Sr/86Sr)i ratios of 0.7033–0.7044, relatively uniform positive ɛNd(t) values of 2.3–3.2 and positive ɛHf(t) values of 8.5–17.1. Trace-element and isotopic modelling indicates that the DBZG mafic rocks were generated by partial melting of asthenospheric mantle under garnet- to spinel-facies conditions. The occurrence of OIB-like mafic intrusion suggests significant upwelling of the asthenosphere in response to lithospheric attenuation caused by continental rifting. These processes occurred in an incipient continental back-arc environment in the upper plate of a palaeo-Pacific slab subducting W–NW beneath East Asia.

scholarly journals The role of the seagrass <i>Posidonia oceanica</i> in the cycling of trace elements

2012 ◽  
Vol 9 (3) ◽  
pp. 2623-2653 ◽  
Author(s):  
C. Sanz-Lázaro ◽  
P. Malea ◽  
E. T. Apostolaki ◽  
I. Kalantzi ◽  
A. Marín ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Posidonia Oceanica ◽  
Trophic Levels ◽  
Toxic Trace Elements ◽  
Relevant Role ◽  
Potentially Toxic Trace Elements ◽  
The Mediterranean ◽  
Element Transfer

Abstract. The aim of this work was to study the role of the seagrass Posidonia oceanica on the cycling of a wide set of trace elements (Ag, As, Ba, Bi, Cd, Co, Cr, Cs, Cu, Fe, Ga, Li, Mn, Ni, Pb, Rb, Sr, Tl, V and Zn). We measured the concentration of these trace elements in the different compartments of P. oceanica (leaves, rhizomes, roots and epibiota) in a non-polluted seagrass meadow representative of the Mediterranean and calculated the annual budget from a mass balance. We provide novel data on accumulation dynamics of many trace elements in P. oceanica compartments and demonstrate that trace element accumulation patterns are mainly determined by plant compartment rather than by temporal variability. Epibiota was the compartment which showed the greatest concentrations for most trace elements. Thus, they constitute a key compartment when estimating trace element transfer to higher trophic levels by P. oceanica. For most trace elements, translocation seemed to be low and acropetal. Zn, Cd, Sr and Rb were the trace elements that showed the highest release rate through decomposition of plant detritus, while Cs, Tl and Bi the lowest. P. oceanica acts as a sink of potentially toxic trace elements (Ni, Cr, As and Ag), which can be sequestered, decreasing their bioavailability. P. oceanica may have a relevant role in the cycling of trace elements in the Mediterranean.

scholarly journals The role of the seagrass <i>Posidonia oceanica</i> in the cycling of trace elements

2012 ◽  
Vol 9 (7) ◽  
pp. 2497-2507 ◽  
Author(s):  
C. Sanz-Lázaro ◽  
P. Malea ◽  
E. T. Apostolaki ◽  
I. Kalantzi ◽  
A. Marín ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Posidonia Oceanica ◽  
Trophic Levels ◽  
Toxic Trace Elements ◽  
Relevant Role ◽  
Potentially Toxic Trace Elements ◽  
The Mediterranean ◽  
Element Transfer

Abstract. The aim of this study was to investigate the role of the seagrass Posidonia oceanica on the cycling of a wide set of trace elements (Ag, As, Ba, Bi, Cd, Co, Cr, Cs, Cu, Fe, Ga, Li, Mn, Ni, Pb, Rb, Sr, Tl, V and Zn). We measured the concentration of these trace elements in different compartments of P. oceanica (leaves, rhizomes, roots and epiphytes) in a non-polluted seagrass meadow representative of the Mediterranean and calculated the annual budget from a mass balance. We provide novel data on accumulation dynamics of many trace elements in P. oceanica compartments and demonstrate that trace element accumulation patterns are mainly determined by plant compartment rather than by temporal variability. Epiphytes were the compartment, which showed the greatest concentrations for most trace elements. Thus, they constitute a key compartment when estimating trace element transfer to higher trophic levels by P. oceanica. Trace element translocation in P. oceanica seemed to be low and acropetal in most cases. Zn, Cd, Sr and Rb were the trace elements that showed the highest release rate through decomposition of plant detritus, while Cs, Tl and Bi showed the lowest. P. oceanica acts as a sink of potentially toxic trace elements (Ni, Cr, As and Ag), which can be sequestered, decreasing their bioavailability. P. oceanica may have a relevant role in the cycling of trace elements in the Mediterranean.

scholarly journals Evolution of Subduction Dynamics beneath West Avalonia in Middle to Late Ordovician Times

Lithosphere ◽  
2020 ◽  
Vol 2020 (1) ◽  
pp. 1-22
Author(s):  
Pierre Jutras ◽  
J. Brendan Murphy ◽  
Dennis Quick ◽  
Jaroslav Dostal
Keyword(s):  
Trace Element ◽  
Partial Melting ◽  
Volcanic Rocks ◽  
Upper Ordovician ◽  
The North ◽  
Trace Element Contents ◽  
Element Contents ◽  
Arc Setting ◽  
Back Arc ◽  
High Degree

Abstract Middle to Upper Ordovician volcanic rocks in the Arisaig area of Nova Scotia, Canada, constitute the only known record of volcanism in West Avalonia during that interval. Hence, they have been extensively studied to test paleocontinental reconstructions that consistently show Avalonia as a drifting microcontinent during that period. Identification of volcanic rocks with an intermediate composition (the new Seaspray Cove Formation) between upper Darriwilian bimodal volcanic rocks of the Dunn Point Formation and Sandbian felsic pyroclastic rocks of the McGillivray Brook Formation has led to a reevaluation of magmatic relationships in the Ordovician volcanic suite at Arisaig. Although part of the same volcanic construction, the three formations are separated by significant time-gaps and are shown to belong to three distinct magmatic subsystems. The tectonostratigraphic context and trace element contents of the Dunn Point Formation basalts suggest that they were produced by the high-degree partial melting of an E-MORB type source in a back-arc extensional setting, whereas trace element contents in intermediate rocks of the Seaspray Cove Formation suggest that they were produced by the low-degree partial melting of a subduction-enriched source in an arc setting. The two formations are separated by a long interval of volcanic quiescence and deep weathering, during which time the back-arc region evolved from extension to shortening and was eventually onlapped by arc volcanic rocks. Based on limited field constraints, paleomagnetic and paleontological data, this progradation of arc onto back-arc volcanic rocks occurred from the north, where an increasingly young Iapetan oceanic plate was being subducted at an increasingly shallow angle. Partial subduction of the Iapetan oceanic ridge is thought to have subsequently generated slab window magmatism, thus marking the last pulse of subduction-related volcanism in both East and West Avalonia.

Continental Crust formation in the Archean vs modern times

2020 ◽  
Author(s):  
Oliver Jagoutz ◽  
Benjamin Klein ◽  
Max W Schmidt ◽  
Nico Küter
Keyword(s):  
Continental Crust ◽  
Subduction Zones ◽  
Major Elements ◽  
Modern Times ◽  
Arc Magmas ◽  
Crucial Difference ◽  
Dry Conditions ◽  
Water Saturated ◽  
Liquid Line Of Descent

&lt;p&gt;When subduction initiated and contributed to formation of Continental crust is uncertain. A crucial difference between subduction zones magma and e.g. plume related magmatism is the role of H2O in the magma formed. Subduction zones magma are frequently wet and follow a liquid line of descent (LLD) that differs from dry plume related magmas. We developed a qualitative hygrometer based on major elements that allow to distinguish between LLD formed at water saturated condition from those that formed at dry conditions. While arc magmas can by dry at times, plume related magmas are generally dry. So wet LLD are a hall mark of subduction. In this talk we will compare the modern arc record with the Archean rock record to investigate if Archean rocks formed due to a wet or dry LLD.&amp;#160;&lt;/p&gt;

A Statistical Study of Process Variables to Optimize a High Speed Curtain Coater: Part I

TAPPI Journal ◽  
2009 ◽  
Vol 8 (1) ◽  
pp. 20-26 ◽  
Author(s):  
PEEYUSH TRIPATHI ◽  
MARGARET JOYCE ◽  
PAUL D. FLEMING ◽  
MASAHIRO SUGIHARA
Keyword(s):  
Boundary Layer ◽  
Experimental Design ◽  
High Speed ◽  
Statistical Study ◽  
Process Variables ◽  
High Speeds ◽  
The Stability ◽  
Air Removal ◽  
Removal System

Using an experimental design approach, researchers altered process parameters and material prop-erties to stabilize the curtain of a pilot curtain coater at high speeds. Part I of this paper identifies the four significant variables that influence curtain stability. The boundary layer air removal system was critical to the stability of the curtain and base sheet roughness was found to be very important. A shear thinning coating rheology and higher curtain heights improved the curtain stability at high speeds. The sizing of the base sheet affected coverage and cur-tain stability because of its effect on base sheet wettability. The role of surfactant was inconclusive. Part II of this paper will report on further optimization of curtain stability with these four variables using a D-optimal partial-facto-rial design.

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