scholarly journals Highly efficient synthesis of [60]fullerene oxides by plasma jet

2017 ◽  
Vol 4 (9) ◽  
pp. 170658 ◽  
Author(s):  
Sheng-Peng Jiang ◽  
Shengxia Duan ◽  
Kai-Qing Liu ◽  
Xiao-Yu Yang ◽  
Cheng Cheng ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Theoretical Calculations ◽  
Chemical Shifts ◽  
Plasma Jet ◽  
Nonequilibrium Plasma ◽  
Efficient Synthesis ◽  
Structural Assignment ◽  
High Yields ◽  
First Time ◽  
C Nmr

Atmospheric pressure nonequilibrium plasma jet has been applied to the synthesis of [60]fullerene oxides (C 60 O n ) for the first time. C 60 O and C 60 O 2 were produced and isolated in high yields up to 44% and 21%, respectively. The structural assignment of C 60 O was confirmed by comparison with the reported spectroscopic data. Theoretical calculations of 13 C NMR chemical shifts for eight isomers of C 60 O 2 were performed and compared with the experimental data to assign the most possible structure for the obtained C 60 O 2 dominantly as an e isomer.

Studying of Plasma- Polymerized Pyrrole at Variable Gas Flow Rates Via Plasma Jet

2021 ◽  
Vol 19 (48) ◽  
pp. 44-51
Author(s):  
Saba Jawad Kadhem
Keyword(s):  
Flow Rate ◽  
Atmospheric Pressure ◽  
Gas Flow ◽  
Flow Characteristics ◽  
Atmospheric Pressure Plasma ◽  
Optical Emission ◽  
Plasma Jet ◽  
Nonequilibrium Plasma ◽  
Nano Particles ◽  
Vis Spectroscopy

     In this manuscript has investigated the synthesis of plasma-polymerized pyrrole (C4H5N) nano-particles prepared by the proposed atmospheric pressure nonequilibrium plasma jet through the parametric studies, particularly gas flow rate (0.5, 1 and 1.5 L/min). The plasma jet which used operates with alternating voltage 7.5kv and frequency 28kHz. The plasma-flow characteristics were investigated based on optical emission spectroscopy (OES). UV-Vis spectroscopy was used to characterize the  oxidization  state for polypyrrole. The major absorption appears around 464.1, 449.7 and 435.3  nm at the three flow rate of argon gas. The chemical composition and structural properties of the contained samples which synthesized at 0.5 L/min as a argon flow rate were analyzed by scanning electron microscopy (SEM), Fourier transformation infrared spectroscopy (FTIR), Raman spectroscopy and X-ray diffraction (XRD). SEM point to a uniform distribution of polypyrrole (PPY) nanoparticles matrix. XRD technique showed a semicrystalline pattern for PPY)thin film. It is expected, that the high-quality plasma polymer grown by atmospheric pressure plasma jet method contributes to serving as conducting materials.

Neue Untersuchung über Inhaltsstoffe der Kreuzdornrinde, IV [1] Die Hauptanthraglykoside der Rinde von Rhamnus catharticus L.: Emodin-8-O-β-gentiobiosid, -glukosid und -primverosid / A New Investigation on the Com position of Rhamni cathartici Cortex, IV [1] The Main Anthraglycosides of the Stem Bark of Rhamnus catharticus L.: Emodin-8-0-/β-gentiobioside, -glucoside and -primveroside

1983 ◽  
Vol 38 (3-4) ◽  
pp. 170-178 ◽  
Author(s):  
Hans-W. Rauwald
Keyword(s):  
Nmr Spectroscopy ◽  
Plant Material ◽  
Chemical Shifts ◽  
Stem Bark ◽  
New Method ◽  
Countercurrent Chromatography ◽  
Anthraquinone Glycosides ◽  
Anthraquinone Derivatives ◽  
First Time ◽  
C Nmr

From the stem bark of Rhamnus catharticus L. (purging buckthorn) the three main anthraquinone glycosides have been isolated by the new method of droplet-countercurrent-chromatography. Their structures were spectroscopically identified as em odin-8-O-β-gentiobioside, -glucoside and -primveroside. From these the primveroside is a new substance, the gentiobioside has been found for the second time in plant material. The structures were confirmed by 13C NMR spectroscopy for the first time in O-glycosides of emodin type. Especially the differences in 13C chemical shifts of the free resp. acetylated aglycones and glycosides are useful parameters for determining the position of O-glycosylation in the 1,8-dihydroxy-anthraquinone derivatives

Conformation of ring A in triterpenoid ketones. Carbon-13 chemical shifts and spin-lattice relaxation times of lupane and 18α-oleanane derivatives

1989 ◽  
Vol 54 (7) ◽  
pp. 1928-1939 ◽  
Author(s):  
Miloš Buděšínský ◽  
Jiří Klinot
Keyword(s):  
Chemical Shifts ◽  
Relaxation Times ◽  
Lattice Relaxation ◽  
Chair Conformation ◽  
Spin Lattice Relaxation ◽  
Spin Lattice ◽  
Structural Assignment ◽  
Boat Form ◽  
The One ◽  
C Nmr

13C NMR spectra of sixteen lupane and 19β,28-epoxy-18α-oleanane triterpenoids I-XVI were measured and a complete structural assignment of chemical shifts was made. For most compounds also the carbon spin-lattice relaxation times T1 were obtained. Characteristic differences in chemical shifts of some carbon atom signals were found between 2α-methyl-3-oxo and 2α-methyl-1-oxo derivatives II, V and VIII with chair conformation of the ring A on the one hand and their 2β-isomers III, VI and IX (boat form) on the other. Using these 2-methyl ketones as models, the chair-boat population in allobetulone (I), 3-oxo-28-lupanenitrile (IV) and 1-oxo derivative VII was determined. The results agree well with the data obtained by other physical methods.

One-pot atom-efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis

2015 ◽  
Vol 51 (40) ◽  
pp. 8504-8507 ◽  
Author(s):  
Fan Jia ◽  
Xiaoyu Chen ◽  
Yan Zheng ◽  
Yusheng Qin ◽  
Youhua Tao ◽  
...  
Keyword(s):  
Tandem Reaction ◽  
Cyclic Carbonates ◽  
Tandem Catalysis ◽  
Efficient Synthesis ◽  
One Pot ◽  
One Pot Synthesis ◽  
Salen Complexes ◽  
High Yields ◽  
First Time

One-pot synthesis of well-defined bio-renewable polyesters and cyclic carbonates in high yields was successfully realized for the first time by way of a tandem reaction using metal salen complexes as catalysts.

An Atmospheric Pressure Nonequilibrium Plasma Jet Device

2008 ◽  
Vol 36 (4) ◽  
pp. 986-987 ◽  
Author(s):  
Qing Xiong ◽  
Xin Pei Lu ◽  
Zhong He Jiang ◽  
Zhi Yuan Tang ◽  
Jing Hu ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Plasma Jet ◽  
Nonequilibrium Plasma

scholarly journals Initiation of the plasma jet of the magneto-plasma compressor by the external plasma source

2021 ◽  
Vol 2100 (1) ◽  
pp. 012005
Author(s):  
V G Brovkin ◽  
A I Klimov ◽  
I Ch Mashek ◽  
A S Pashchina ◽  
N M Ryazansky ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Plasma Jet ◽  
Plasma Source ◽  
Liquid Mixtures ◽  
Plasma Jets ◽  
Front Velocity ◽  
Erosion Plasma ◽  
Gas Plasma ◽  
Preliminary Study ◽  
First Time

Abstract The results of a preliminary study of the interaction of supersonic gas-plasma flows created by a magneto-plasma compressor and a pulsed erosion plasma jet are presented. Stable initiation of the MPC discharge at atmospheric pressure was achieved for the first time. The advantage of using the coaxial arrangement of plasma jets sources for MPC discharge initiation is shown. A noticeable change in the shock wave front velocity and pressure (up to 20%), created during the MPC discharge and dispersed powders and liquid mixtures interaction, is discovered.

Microstructure and reactivity of small metal particles: The role of Ce additives

1992 ◽  
Vol 50 (1) ◽  
pp. 318-319
Author(s):  
L.D. Schmidt ◽  
K. R. Krause ◽  
J. M. Schwartz ◽  
X. Chu
Keyword(s):  
Atmospheric Pressure ◽  
Noble Metals ◽  
Mixed Oxides ◽  
Catalytic Properties ◽  
Chemical Shifts ◽  
Catalytic Converter ◽  
Structural Evolution ◽  
Single Particles ◽  
Small Metal Particles

The evolution of microstructures of 10- to 100-Å diameter particles of Rh and Pt on SiO2 and Al2O3 following treatment in reducing, oxidizing, and reacting conditions have been characterized by TEM. We are able to transfer particles repeatedly between microscope and a reactor furnace so that the structural evolution of single particles can be examined following treatments in gases at atmospheric pressure. We are especially interested in the role of Ce additives on noble metals such as Pt and Rh. These systems are crucial in the automotive catalytic converter, and rare earths can significantly modify catalytic properties in many reactions. In particular, we are concerned with the oxidation state of Ce and its role in formation of mixed oxides with metals or with the support. For this we employ EELS in TEM, a technique uniquely suited to detect chemical shifts with ∼30Å resolution.

Effect of Atmospheric-Pressure Helium Plasma Jet on Cell Culture Medium

2013 ◽  
Vol 133 (5) ◽  
pp. 278-285
Author(s):  
Norimitsu Takamura ◽  
Douyan Wang ◽  
Takao Satoh ◽  
Takao Namihira ◽  
Hisato Saitoh ◽  
...  
Keyword(s):  
Cell Culture ◽  
Atmospheric Pressure ◽  
Culture Medium ◽  
Plasma Jet ◽  
Helium Plasma ◽  
Cell Culture Medium
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