scholarly journals General forms of statistical mechanics with special reference to the requirements of the new quantum mechanics

1926 ◽  
Vol 113 (764) ◽  
pp. 432-449 ◽  
Keyword(s):  
Statistical Mechanics ◽  
Equations Of Motion ◽  
Ideal Gas ◽  
Absolute Temperature ◽  
Coupled Systems ◽  
Light Quantum ◽  
Classical Form ◽  
Special Cases ◽  
New Form ◽  
Temperature Radiation

It is well known that a new form of statistical mechanics has been recently developed by Einstein for an ideal gas of structureless mass-points. This starts from a discussion by Bose of the laws of temperature radiation based on the light quantum hypothesis, and has been further analysed by Schrödinger. Yet another new form has been proposed independently by Fermi and Dirac. The latter based his theory on a discussion of lightly coupled systems with the help of Schrödinger’s equation. Combined with Heisenberg’s work on the many-body problem, Dirac’s work forces us to conclude at least that the classical form of statistical mechanics must be changed. It indicates that the true form, which satisfies the laws of the new mechanics, is almost certainly that of Fermi and Dirac, which is the natural generalization of Pauli’s principle of exclusion for electronic orbits in an atom. The work of Heisenberg and Dirac already quoted has shown that Pauli’s principle and its extension are satisfied in the new mechanics by a complete self-consistent solution of the equations of motion. So far as I am aware, the discussions of the new forms have as yet dealt only with the statistics of a gas of structureless mass-points (and, of course, temperature radiation). There has, moreover, been as yet no attempt to define the entropy (and the absolute temperature) in strict analogy with rational thermodynamics by means of the equation d Q = T d S. If another definition is preferred, then this equation must be deduced from it. It has, therefore, seemed worth while to reopen the discussion by examining ab initio a quite general form of statistical mechanics of which the classical form and instein’s and Fermi-Dirac’s are special cases. This is rendered possible by using the powerful method of complex integration already applied to the classical form. The sequence of the argument is then to take the general form, which covers a very large range of ways of assigning possibilities and counting complexions, and construct on that basis exact integral expressions for the number of complexions possible to the assembly and for the average number of systems of the assembly in their various quantum states. We then derive from these the average energies and external reactions and so the form of d Q, deduce from d Q the existence of S and so define S and T. This can be done in the general form for assemblies of ideal systems just as general as can be handled in the classical way—ideal gases of molecules of any structure and crystals and radiation. Such assemblies are in all cases thermodynamical systems.

On a Scale-Invariant Model of Statistical Mechanics and the Laws of Thermodynamics

2016 ◽  
Vol 138 (3) ◽  
Author(s):  
Siavash H. Sohrab
Keyword(s):  
Statistical Mechanics ◽  
Thermal Energy ◽  
Thermodynamic System ◽  
Ideal Gas ◽  
Absolute Temperature ◽  
Scale Invariant ◽  
Invariant Model ◽  
Definition Of ◽  
Classical Thermodynamics ◽  
Total Thermal Energy

A scale-invariant model of statistical mechanics is applied to describe modified forms of zeroth, first, second, and third laws of classical thermodynamics. Following Helmholtz, the total thermal energy of the thermodynamic system is decomposed into free heat U and latent heat pV suggesting the modified form of the first law of thermodynamics Q = H = U + pV. Following Boltzmann, entropy of ideal gas is expressed in terms of the number of Heisenberg–Kramers virtual oscillators as S = 4 Nk. Through introduction of stochastic definition of Planck and Boltzmann constants, Kelvin absolute temperature scale T (degree K) is identified as a length scale T (m) that is related to de Broglie wavelength of particle thermal oscillations. It is argued that rather than relating to the surface area of its horizon suggested by Bekenstein (1973, “Black Holes and Entropy,” Phys. Rev. D, 7(8), pp. 2333–2346), entropy of black hole should be related to its total thermal energy, namely, its enthalpy leading to S = 4Nk in exact agreement with the prediction of Major and Setter (2001, “Gravitational Statistical Mechanics: A Model,” Classical Quantum Gravity, 18, pp. 5125–5142).

scholarly journals Mixing indistinguishable systems leads to a quantum Gibbs paradox

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Benjamin Yadin ◽  
Benjamin Morris ◽  
Gerardo Adesso
Keyword(s):  
Statistical Mechanics ◽  
Thought Experiment ◽  
Entropy Change ◽  
Ideal Gas ◽  
Gibbs Paradox ◽  
Quantum Case ◽  
Entropy Increase ◽  
Level Of Knowledge ◽  
Different Gases ◽  
As If

AbstractThe classical Gibbs paradox concerns the entropy change upon mixing two gases. Whether an observer assigns an entropy increase to the process depends on their ability to distinguish the gases. A resolution is that an “ignorant” observer, who cannot distinguish the gases, has no way of extracting work by mixing them. Moving the thought experiment into the quantum realm, we reveal new and surprising behaviour: the ignorant observer can extract work from mixing different gases, even if the gases cannot be directly distinguished. Moreover, in the macroscopic limit, the quantum case diverges from the classical ideal gas: as much work can be extracted as if the gases were fully distinguishable. We show that the ignorant observer assigns more microstates to the system than found by naive counting in semiclassical statistical mechanics. This demonstrates the importance of accounting for the level of knowledge of an observer, and its implications for genuinely quantum modifications to thermodynamics.

scholarly journals Relativistic equations for elementary particles

1948 ◽  
Vol 192 (1029) ◽  
pp. 195-218 ◽  
Keyword(s):  
Elementary Particle ◽  
Wave Equation ◽  
Equations Of Motion ◽  
Rest Mass ◽  
Wave Form ◽  
Total Charge ◽  
Field Equations ◽  
Relativistic Approximation ◽  
Special Cases ◽  
Linear Differential

From the general principles of quantum mechanics it is deduced that the wave equation of a particle can always be written as a linear differential equation of the first order with matrix coefficients. The principle of relativity and the elementary nature of the particle then impose certain restrictions on these coefficient matrices. A general theory for an elementary particle is set up under certain assumptions regarding these matrices. Besides, two physical assumptions concerning the particle are made, namely, (i) that it satisfies the usual second-order wave equation with a fixed value of the rest mass, and (ii) either the total charge or the total energy for the particle-field is positive definite. It is shown that in consequence of (ii) the theory can be quantized in the interaction free case. On introducing electromagnetic interaction it is found that the particle exhibits a pure magnetic moment in the non-relativistic approximation. The well-known equations for the electron and the meson are included as special cases in the present scheme. As a further illustration of the theory the coefficient matrices corresponding to a new elementary particle are constructed. This particle is shown to have states of spin both 3/2 and 1/2. In a certain sense it exhibits an inner structure in addition to the spin. In the non-relativistic approximation the behaviour of this particle in an electromagnetic field is the same as that of the Dirac electron. Finally, the transition from the particle to the wave form of the equations of motion is effected and the field equations are given in terms of tensors and spinors.

scholarly journals Coupled Systems of Sequential Caputo and Hadamard Fractional Differential Equations with Coupled Separated Boundary Conditions

Symmetry ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 701 ◽  
Author(s):  
Suphawat Asawasamrit ◽  
Sotiris Ntouyas ◽  
Jessada Tariboon ◽  
Woraphak Nithiarayaphaks
Keyword(s):  
Differential Equations ◽  
Boundary Conditions ◽  
Fractional Differential Equations ◽  
Coupled Systems ◽  
Uniqueness Of Solutions ◽  
Krasnoselskii’S Fixed Point Theorem ◽  
Hadamard Fractional Differential Equations ◽  
Special Cases ◽  
Separated Boundary Conditions ◽  
Fractional Differential

This paper studies the existence and uniqueness of solutions for a new coupled system of nonlinear sequential Caputo and Hadamard fractional differential equations with coupled separated boundary conditions, which include as special cases the well-known symmetric boundary conditions. Banach’s contraction principle, Leray–Schauder’s alternative, and Krasnoselskii’s fixed-point theorem were used to derive the desired results, which are well-illustrated with examples.

Statistical mechanics of one-dimensional solitary-wave-bearing scalar fields: Exact results and ideal-gas phenomenology

1980 ◽  
Vol 22 (2) ◽  
pp. 477-496 ◽  
Author(s):  
J. F. Currie ◽  
J. A. Krumhansl ◽  
A. R. Bishop ◽  
S. E. Trullinger
Keyword(s):  
Solitary Wave ◽  
Statistical Mechanics ◽  
Scalar Fields ◽  
Ideal Gas ◽  
Exact Results ◽  
One Dimensional

scholarly journals CONSTRUCTION OF EQUATIONS OF MOTION OF MULTIBODY SYSTEMS AND COMPUTER MODELING

2018 ◽  
pp. 74-81
Author(s):  
Darina Hroncová
Keyword(s):  
Mathematical Model ◽  
Computer Modeling ◽  
Computer Model ◽  
Equations Of Motion ◽  
Mechanical Systems ◽  
Ideal Gas ◽  
Material Point ◽  
Operating Conditions ◽  
Contact Friction ◽  
Knowledge Process

Urgency of the research. Computer models mean new quality in the knowledge process. Using a computer model, the properties of the subject under investigation can be tested under different operating conditions. By experimenting with a com-puter model, we learn about the modelled object. We can test different machine variants without having to produce and edit prototypes. Target setting. The development of computer technology has expanded the possibility of solving mathematical models and allowed to gradually automate the calculation of mathematical model equations. It is necessary to insert appropriate inputs of the mathematical model and monitor and evaluate the output results through the computer output device The target was to describe the mathematical apparatus required for mathematical modeling and subsequently to compile a model for computer modeling. Actual scientific researches and issues analysis. When formulating a mathematical model for a computer, the laws and the theory we use are always valid under more or less idealized conditions, and operate with fictitious concepts such as, material point, ideal gas, intangible spring, and the like. However, with these simplifications, we describe a realistic phenomenon where the initial assumptions are only met to a certain extent. In order for the results not to be different from the modeled reality, it is to be assumed that a good computer model arises gradually, by verifying and modifying it, which is one of the advantages of MSC Adams. Uninvestigated parts of general matters defining. The question of building a real manipulator model. Based on the above simulation, it is possible to build a real model. The research objective. Using MSC Adams to simulate multiple body systems and verify its suitability for simulating ma-nipulator and robot models. In various versions of the assembled model we can monitor its behavior under different operating conditions. The statement of basic materials. In computer simulation, MSC Adams-View is used to simulate mechanical systems. It has an interactive environment for automated dynamic analysis of parameterized mechanical systems with an arbitrary struc-ture of rigid and flexible bodies with geometric or force joints, in which act gravity, inertia, experimentally designed contact, friction, aerodynamic, hydrodynamic or electromechanical forces and have integrated control, hydraulic, pneumatic or elec-tromechanical circuits. Conclusions. Working with a mathematical model on a computer opens space for specific synthesis of empirical and ana-lytical method of scientific knowledge. Working with the computer model carries the characteristic features of classical experi-mentation. It represents a qualitatively new way of solving tasks that can not be experimented with on a real object. The result is the equivalence of the computer model and the object being investigated with the features and expressions chosen as essen-tial, with accuracy sufficient to the exact purpose.

Modeling, Simulation, and Modal Analysis Hydraulic Valve Lifter With Oil Compressibility Effects

1989 ◽  
Author(s):  
T. Hatch ◽  
A. P. Pisano
Keyword(s):  
Differential Equations ◽  
Modal Analysis ◽  
Equations Of Motion ◽  
Check Valve ◽  
Linear Differential Equations ◽  
Third Order ◽  
Mode Behavior ◽  
Special Cases ◽  
Linear Differential ◽  
Hydraulic Valve

Abstract A two-degree-of-freedom (2-DOF), analytical model of a hydraulic valve lifter is derived. Special features of the model include the effects of bulk oil compressibility, multi-mode behavior due to plunger check valve modeling, and provision for the inclusion of third and fourth body displacements to aid In the use of the model in extended, multi-DOF systems. It is shown that motion of the lifter plunger and body must satisfy a coupled system of third-order, non-linear differential equations of motion. It is also shown that the special cases of zero oil compressibility and/or 1-DOF motion of lifter plunger can be obtained from the general third-order equations. For the case of zero oil compressibility, using Newtonian fluid assumptions, the equations of motion are shown to reduce to a system of second-order, linear differential equations. The differential equations are numerically integrated in five scenarios designed to test various aspects of the model. A modal analysis of the 2-DOF, compressible model with an external contact spring is performed and is shown to be in excellent agreement with simulation results.

Physics and Dynamics of the Atmosphere

2019 ◽  
pp. 71-90
Author(s):  
Han Dolman
Keyword(s):  
Equations Of Motion ◽  
Three Dimensional ◽  
Energy Difference ◽  
Cell System ◽  
Ideal Gas ◽  
Lapse Rate ◽  
Milankovitch Cycles ◽  
Physical Description ◽  
Geostrophic Balance ◽  
Basic Physics

This chapter describes the basic physics and thermodynamics of the atmosphere, starting from the ideal gas law and the hydrostatic equation, from which the lapse rate in the troposphere is derived. The effect of atmospheric moisture on the lapse rate is identified and the Clausius–Clapeyron equation giving the saturated humidity is derived. The effect of moisture on adiabatic vertical transport is shown. Then, the three-dimensional equations of motion are derived in vector form. From these, geostrophic balance and the thermal wind equations are derived. This, with the Coriolis force, gives the physical description of the atmospheric circulation. The driving force behind circulation is identified as the energy difference between the tropics and the extratropics. This is driven by radiation differences, including, at large geological scale, the Milankovitch cycles. Finally, circulation as a three-cell system per hemisphere, and the development of weather systems such as cyclones, are described.

Thermoelasticity

1997 ◽  
Author(s):  
Burak Erman ◽  
James E. Mark
Keyword(s):  
Equation Of State ◽  
Elastic Deformation ◽  
Additional Assumption ◽  
Polymer Network ◽  
Ideal Gas ◽  
Absolute Temperature ◽  
Constant Volume ◽  
Conformational Energy ◽  
Network Chain ◽  
Constant Deformation

The important postulate that intermolecular interactions are independent of extent of deformation leads directly to the conclusion that such interactions cannot contribute to an energy of elastic deformation ΔEel at constant volume. In the earliest theories of rubberlike elasticity, it was additionally assumed that, intramolecular contributions to ΔEel were likewise nil. In this idealization that the total ΔEel is zero, the elastic retractive force exhibited by a deformed polymer network would be entirely entropic in origin. At the molecular level, this would correspond, of course, to assuming all configurations of a network chain to be of exactly the same conformational energy and thus the average configuration to be independent of temperature. Under these circumstances, the dependence of stress on temperature is strikingly simple, as shown, for example, by the equation . . . f* = υkT/V (〈r2〉i/〈r2〉0)(α – α-2) . . . . . . (9.1) . . . that characterizes a polymer network in elongation where, it should be recalled, 〈r2〉i3/2 is proportional to the volume of the network. This additional assumption that 〈r2〉0 is independent of temperature would lead to the prediction that the elastic stress determined at constant volume and elongation α is directly proportional to the absolute temperature. Such network chains would be akin to the particles of an ideal gas, which would obey the equation of state p = nRT(1/V) and thus exhibit a pressure at constant deformation (1/V) likewise directly proportional to the temperature.

Statistical mechanics of an ideal gas

2009 ◽  
pp. 233-243
Author(s):  
Stephen J. Blundell ◽  
Katherine M. Blundell
Keyword(s):  
Statistical Mechanics ◽  
Ideal Gas
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