Quantum field theory of bound states IV. Relativistic theory of the excited states of hydrogen
When allowance is made for the instability of the excited states of hydrogen it is necessary to replace the equation of Salpeter & Bethe (1951) by a set of coupled integral equations for representatives of the state vector. These representatives correspond to an electron-proton bound state and also to the electron and proton with any number of photons present. The coupled equations can be reduced to a single integral equation, which gives the electronproton bound state as an eigenstate of a modified propagator. The modified propagator is related to the two-body propagator of Salpeter & Bethe. The difference between the first approximation to the modified propagator and the first approximation to the two-body compound propagator (Eden 1952, 1953) can be represented by a displacement of its singularity in total energy-momentum space. This displacement gives in a relativistic form all the relevant contributions to the Lamb shift to this order; these include the contribution from low-energy transverse photons crossing over an arbitrary number of longitudinal photons; previously this term has always been deduced by physical arguments and obtained by non-relativistic methods (Bethe 1947; Salpeter 1952). The displacement of the singularity also gives decay coefficients to this order in the charge. The method can readily be extended to higher approximations.