scholarly journals Atmospheric Heavy Metal Input to Forest Soils in Rural Areas of Denmark

2007 ◽  
Vol 7 ◽  
pp. 192-197 ◽  
Author(s):  
M. F. Hovmand ◽  
Kaare Kemp
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Rural Areas ◽  
Forest Floor ◽  
Ambient Atmosphere ◽  
Chronological Order ◽  
Forest Sites ◽  
Yearly Average ◽  
Atmospheric Inputs

Atmospheric bulk deposition of heavy metals (HM) was measured from 1972/73 to the present time at five to ten forest sites in rural areas of Denmark. From 1979, HM in aerosols were measured at one to four forest sites. On the basis of these long-term continuous measurements, the atmospheric inputs to the forest floor have been calculated. Yearly HM emission estimates to the European atmosphere seems to correlate well with yearly average values of HM deposition, as well as with HM concentrations in the ambient atmosphere. HM emissions have been estimated since the 1950s. Using the correlation between emission and deposition, HM deposition values maybe extrapolated in reverse chronological order. The accumulated atmospheric HM deposition has been estimated in this way over a period of 50 years.

scholarly journals Transport and accumulation of heavy metals in undisturbed soil columns

2013 ◽  
Vol 9 (3) ◽  
pp. 187-194
Keyword(s):  
Heavy Metals ◽  
Kola Peninsula ◽  
Forest Floor ◽  
High Capacity ◽  
Soil Columns ◽  
Undisturbed Soil ◽  
Podzolic Soils ◽  
Floor Layer

The podzolic soils of the Kola Peninsula, Russia, have in localised areas been highly contaminated with copper and nickel from smelting activities. Migration and retention of these metals were investigated in undisturbed soil columns irrigated with simulated background and polluted precipitation in order to study the temporal processes of retention and release within the soil. The mineral layers were strongly acidified by the contaminated precipitation. Forest floor layers demonstrated a high capacity to retain input Ni and Cu under all conditions. Mineral layers accumulated some Cu, but released Ni. In general, Ni leached through the soil faster than Cu. Since metals are strongly retained in the forest floor layer, even after reduction or cessation of inputs there may be a significant long–term risk of their leaching to deeper soil and groundwater. This risk cannot be ameliorated without remediative intervention.

scholarly journals The rainfall effect onto solidification and stabilization of heavy metal-polluted sediments

2020 ◽  
Vol 7 (7) ◽  
pp. 192234
Author(s):  
Yan Sun ◽  
Daofang Zhang ◽  
Feipeng Li ◽  
Hong Tao ◽  
Moting Li ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Diffusion Coefficient ◽  
Simulated Acid Rain ◽  
Curing Process ◽  
Deterioration Rate ◽  
Before And After ◽  
Calculated Diffusion Coefficient ◽  
Leaching Procedure

Rainfall makes impacts on the process of solidification/stabilization (S/S) and the long-term safety of solidified matrix. In this study, the effect of rainfall on solidification/stabilization process was investigated by the rainfall test. The unconfined compressive strength (UCS) and toxicity characteristic leaching procedure (TCLP) were adopted to characterize the properties of S/S sediments before and after the rainfall test. The samples cured for 28 days were selected for semi-dynamic leaching tests with a simulated acidic leachant prepared at pH of 2.0, 4.0 and 7.0. The effectiveness of S/S treatment was evaluated by diffusion coefficient ( D e ) and leachability index (LX). The results indicated that UCS decreased at maximum deterioration rate of 34.23% after 7 days of curing, along with the minimum rate of 7.98% after 28 days by rainfall, with greater than 14 days referred. The rainfall had little effect on the leaching characteristics of heavy metals during the curing process. However, the simulated acid rain made significant impacts on the leaching behaviours of the heavy metals in the S/S materials. All the values of cumulative fraction of leached heavy metals were less than 2.0%, exhibition of good stabilization of cement. Furthermore, the calculated diffusion coefficient ( D e ) for Cu was 1.28 × 10 1 cm 2 s –1 , indicating its low mobility of heavy metal ions in S/S sediments. Furthermore, the calculated diffusion coefficients ( D i ) for Cd, Cu and Pb were 7.44 × 10 −11 , 8.18 × 10 −12 and 7.85 × 10 −12 cm 2 s –1 , respectively, indicating their relatively low mobility of heavy metal in S/S sediments.

scholarly journals Effect of Pig and Cattle Slurry Application on Heavy Metal Composition of Maize Grown on Different Soils

2018 ◽  
Vol 10 (8) ◽  
pp. 2684 ◽  
Author(s):  
Giorgio Provolo ◽  
Giulia Manuli ◽  
Alberto Finzi ◽  
Giorgio Lucchini ◽  
Elisabetta Riva ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Organic Fertilizer ◽  
Pig Manure ◽  
Soil Enrichment ◽  
Maize Cultivation ◽  
Time Required ◽  
Cu And Zn ◽  
Different Soils

Cattle and pig manure contain useful mineral nutrients (N, P, and K) and are therefore used as organic fertilizer. However, excessive applications of manure can cause environmental problems and threaten animal and human health because these materials also hold significant amounts of heavy metals, particularly Cu and Zn. To assess the potential risk due to the increased concentrations of heavy metals (Cu, Mn, Zn, and Cr) in a harvested crop, two maize hybrids were grown in pots on four different soils with three different fertilisers (urea, pig manure, and cattle manure). Both soil and manure characteristics influenced the heavy metal concentrations in the plant shoots. Organic fertilisation strongly interacted with the soils and, in general, reduced the shoot content of Cu, Mn, and Zn. A preliminary assessment of the heavy metal balance of the agricultural systems based on the intensive livestock production and maize cultivation showed that the potential soil enrichment of the long-term application of livestock manure arises mainly from the application of pig slurries that have a high content of Cu and Zn. The time required to apply an amount of metal that is equal to the initial soil content is 60–300 years for Zn and 240–450 years for Cu, depending on the soil type and the initial heavy metal content.

Long-term forest utilization can decrease forest floor microhabitat diversity: evidence from boreal Fennoscandia

2004 ◽  
Vol 34 (2) ◽  
pp. 303-309 ◽  
Author(s):  
Timo Kuuluvainen ◽  
Raija Laiho
Keyword(s):  
Forest Floor ◽  
Natural Forest ◽  
Decayed Wood ◽  
Natural Forests ◽  
Managed Forest ◽  
Vegetation Zone ◽  
Forest Sites ◽  
History Of ◽  
Forest Utilization

Forest floor microhabitat diversity was studied in old Pinus sylvestris L. dominated forest sites in two regions within the middle boreal vegetation zone in Fennoscandia: in 50 managed forest sites in the Häme region in southwestern Finland and in 45 natural or old selectively logged forest sites in the Kuhmo–Viena region in northeastern Finland and northwestern Russia. The forests in the Häme region are characterized by a long history of forest utilization, while the forests in the Kuhmo–Viena region can be regarded as natural or near natural. The managed forest sites in Häme had significantly lower forest floor microhabitat diversity compared with natural and near-natural forests. Microhabitats that were significantly more scarce in managed versus natural and near-natural forest sites included humps, depressions, decayed wood, and vicinity of decayed wood. On the other hand, even ground was significantly more abundant in managed forest compared with natural and near-natural forest. Microhabitat availability was also reflected in the occurrence of tree saplings growing in different microhabitats. The results suggest that long-term forest utilization has decreased forest floor microhabitat diversity. This has occurred because of a decreased amount of fallen deadwood and, possibly, lack of soil disturbances because of fewer uprootings caused by falling trees.

scholarly journals Evaluation of the effects of bio stabilised waste on soil in terms of heavy metal accumulation and leaching

2018 ◽  
Vol 13 (3) ◽  
pp. 1 ◽  
Author(s):  
Francesco Lombardi ◽  
Giulia Costa ◽  
Maria Chiara Di Lonardo ◽  
Alessio Lieto
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Accumulation ◽  
Organic Matter Content ◽  
Total Content ◽  
Heavy Metal Accumulation ◽  
Matter Content ◽  
Aerobic Biodegradation ◽  
Solid Matrix

This work evaluated and compared potential impacts related to the accumulation and/or release of heavy metals resulting from the application of different types of stabilized waste to soil. Namely, the following three types of flows were considered: waste produced by aerobic bio-stabilization of municipal solid waste at a Mechanical Biological Treatment (MBT) plant, and compost produced either from aerobic composting or from a combination of anaerobic and aerobic biodegradation processes. After a preliminary characterization of the materials (organic matter content, volatile solid, and heavy metals content), heavy metal accumulation in soil caused by possible long-term application of these organic materials was evaluated by implementing a discretized mass balance based on the total content of the heavy metals in each type of solid matrix investigated. In addition, results of percolation leaching tests performed on each type of material were presented and discussed. Results highlight that although the total content of heavy metals of the three types of materials differed considerably, with the MBT waste presenting the highest concentrations, the results of the leaching percolation tests were quite similar.

scholarly journals Heavy Metal Residues in Soil and Accumulation in Maize at Long-Term Wastewater Irrigation Area in Tongliao, China

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Yintao Lu ◽  
Hong Yao ◽  
Dan Shan ◽  
Yichen Jiang ◽  
Shichao Zhang ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Growth Cycle ◽  
Wastewater Irrigation ◽  
Pollution Level ◽  
Irrigated Area ◽  
Metal Contents ◽  
Maize Roots ◽  
Translocation Factors

Soil and plant samples were collected from Tongliao, China, during the maize growth cycle between May and October 2010. Heavy metals, such as Cr, Pb, Ni, and Zn, were analyzed. The concentrations of Cr, Pb, Ni, and Zn in the wastewater-irrigated area were higher than those in the topsoil from the groundwater-irrigated area. The concentrations of metals in the maize increased as follows: Pb < Ni < Zn < Cr. In addition, Cr, Pb, and Ni mainly accumulated in the maize roots, and Zn mainly accumulated in the maize fruit. The results of translocation factors (TF) and bioconcentration factors (BCF) of maize for heavy metals revealed that maize is an excluder plant and a potential accumulator plant and can serve as an ideal slope remediation plant. In addition, the increasing heavy metal contents in soils that have been polluted by wastewater irrigation must result in the accumulation of Cr, Pb, Ni, and Zn in maize. Thus, the pollution level can be decreased by harvesting and disposing of and recovering the plant material.

scholarly journals Biosolids and heavy metals in soils

2003 ◽  
Vol 60 (4) ◽  
pp. 793-806 ◽  
Author(s):  
Maria Lucia Azevedo Silveira ◽  
Luís Reynaldo Ferracciú Alleoni ◽  
Luiz Roberto Guimarães Guilherme
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Heavy Metal Concentration ◽  
Treatment Method ◽  
Soil Fertilization ◽  
Free Ions ◽  
Metal Contents ◽  
Agricultural Areas ◽  
Inorganic Ligands

The application of sewage sludge or biosolids on soils has been widespread in agricultural areas. However, depending on their characteristics, they may cause increase in heavy metal concentration of treated soils. In general, domestic biosolids have lower heavy metal contents than industrial ones. Origin and treatment method of biosolids may markedly influence their characteristics. The legislation that controls the levels of heavy metal contents in biosolids and the maximum concentrations in soils is still controversial. In the long-term, heavy metal behavior after the and of biosolid application is still unknown. In soils, heavy metals may be adsorbed via specific or non-specific adsorption reactions. Iron oxides and organic matter are the most important soil constituents retaining heavy metals. The pH, CEC and the presence of competing ions also affect heavy metal adsorption and speciation in soils. In solution, heavy metals can be present either as free-ions or complexed with organic and inorganic ligands. Generally, free-ions are more relevant in environmental pollution studies since they are readily bioavailable. Some computer models can estimate heavy metal activity in solution and their ionic speciation. Thermodynamic data (thermodynamic stability constant), total metal and ligand concentrations are used by the GEOCHEM-PC program. This program allows studying heavy metal behavior in solution and the effect of changes in the conditions, such as pH and ionic strength and the application of organic and inorganic ligands caused by soil fertilization.

scholarly journals DETEKSI FORMALIN DAN LOGAM BERAT PADA IKAN SEGAR DI PASAR TRADISIONAL KOTA KUPANG

Jurnal Kimia ◽  
2020 ◽  
pp. 147
Author(s):  
A. T. Lema ◽  
J. M. Jacob
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Content ◽  
Quantitative Detection ◽  
Fish Products ◽  
Fresh Fish ◽  
Fish Market ◽  
Qualitative Detection ◽  
Short And Long Term

Nowadays, the use of formalin as a preservative in fish is often found in society. Besides, the consumption of fresh fish products containing heavy metals will potentially cause various diseases both short and long-term. The aims of this study were to assess the knowledge of society about formalin, detect the presence of formalin, and analyze the heavy metal content of Pb, Cd, and Hg in Yellow striped fish, Tuna and Mackerel fish. The qualitative detection was done using Schiff reagents, while the quantitative detection was done by using the Spectrophotometry based on the reaction of formaldehyde and Nash reagents. The results showed that 50 percent of society did not know about the use of formaldehyde and its characteristics in fish. The Qualitative testing on 9 samples found that 2 samples contained positive formalin, while 7 samples were negative. The quantitative test showed that the highest formalin content was found in Tuna and Mackerel fish with concentration of 3.36 ppm, and 1.26 ppm, respectively. Also, mercury was found as the highest concentration in fish roughly 1 to 1.60 ppm for those samples from three different markets.                                                                                                                                                 Keywords: formalin, heavy metal, fresh fish, market, Kupang city

scholarly journals Estimation of the Seasonal Variability of the Content of Heavy Metal Compounds in the River Waters of the Foothill Zone of the Central

2020 ◽  
pp. 68-81
Author(s):  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
River Water ◽  
Seasonal Variability ◽  
Maximum Permissible Concentration ◽  
Metal Compounds ◽  
River Waters ◽  
Central Caucasus ◽  
Term Data

Based on long-term data, the seasonal variability of the content of heavy metal compounds in the water of the rivers of the foothills of the Central Caucasus – the Terek, Malka, Baksan, Ardon, Cherek, and Urukh – was estimated.Generalizing studies affecting the regional characteristics of the level of hazardous heavy metals in the river waters of the foothill zone of the Central Caucasus have not been carried out over many years. Therefore, the objective of the study was to assess the level of hazardous compounds of heavy metals (Cr, Ni, Mo, Mn, Zn, Pb) in the water of the Terek, Malka, Baksan, Ardon, Cherek and Urukh rivers at 6 observation points located in the foothill zone of the Central Caucasus, for the period from 2005 to 2018. In the analysis, the atomic absorption method using the MGA-915M electrothermal atomizer was used. The level of heavy metal compounds in river water was evaluated by such characteristics as the long-term average and median concentrations, the range of concentration fluctuations, and the frequency of exceeding the maximum permissible concentration. An analysis of long-term data for the period 2005-2018 on the study of the level of heavy metal compounds in the water of the Baksan, Malka, Urukh, Terek, Cherek and Ardon rivers in the foothill zone of the Central Caucasus shows that river water pollution to a greater extent occurs in summer rain flood . The revealed levels of heavy metal compounds in river water over the long-term period under study, as well as the frequency of exceeding the maximum permissible concentration, are illustrated by graphs. The results obtained may be relevant in the development of regional water quality indicators.

scholarly journals Determination of heavy metal deposition in the county of Obrenovac (Serbia) using mosses as bioindicators II: Cadmium (CD), cobalt (CO), and chromium (CR)

2006 ◽  
Vol 58 (2) ◽  
pp. 95-104 ◽  
Author(s):  
V. Vukojevic ◽  
M. Sabovljevic ◽  
Aneta Sabovljevic ◽  
Nevena Mihajlovic ◽  
Gordana Drazic ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Atmospheric Deposition ◽  
Metal Content ◽  
Short Term ◽  
Hypnum Cupressiforme ◽  
Bryum Argenteum ◽  
Heavy Metal Deposition

In the present study, the deposition of three heavy metals (Cd, Co and Cr) in the county of Obrenovac (Serbia) is determined using four moss taxa (Bryum argenteum, Bryum capillare, Brachythecium sp. and Hypnum cupressiforme) as bioindicators. Distribution of average heavy metal content in all mosses in the county of Obrenovac is presented in maps, while long term atmospheric deposition (in the mosses Bryum argenteum and B. capillare) and short term atmospheric deposition (in the mosses Brachythecium sp. and Hypnum cupressiforme) are discussed and in tables. Areas of the highest contaminations are highlighted.

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